1,4-bis{2-[2-(2-(1-pyrenylmethoxy)ethoxy)ethoxy]ethoxy}benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1,4-bis{2-[2-(2-(1-pyrenylmethoxy)ethoxy)ethoxy]ethoxy}benzene
• 英文别名: 1-[2-[2-[2-[4-[2-[2-[2-(Pyren-1-ylmethoxy)ethoxy]ethoxy]ethoxy]phenoxy]ethoxy]ethoxy]ethoxymethyl]pyrene；1-[2-[2-[2-[4-[2-[2-[2-(pyren-1-ylmethoxy)ethoxy]ethoxy]ethoxy]phenoxy]ethoxy]ethoxy]ethoxymethyl]pyrene
• 化学式: C₅₂H₅₀O₈
• 分子量: 802.964
• InChiKey: ZHXDBJPTZZGIMR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  60
• 可旋转键数：
  24
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  73.8
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2-氯乙氧基-2-乙氧基二乙醇 在 sodium hydride 、 potassium carbonate 、 potassium iodide 作用下， 以 四氢呋喃 、 丙酮 为溶剂， 生成 1,4-bis{2-[2-(2-(1-pyrenylmethoxy)ethoxy)ethoxy]ethoxy}benzene
  参考文献：
  名称：

  Cu²⁺-Induced Blue Shift of the Pyrene Excimer Emission:  A New Signal Transduction Mode of Pyrene Probes

  摘要：

  [GRAPHICS]A pentiptycene-bispyrenyl system (1) has been synthesized and investigated as a fluorescent chemosensor for metal ions, A novel blue shift along with an intensity enhancement of the pyrene excimer emission is observed for 1 in the presence of Cu2+. Such a new signal transduction mode of pyrene probes results from the formation of a static pyrene excimer that has very different characteristics from its dynamic counterpart.

  DOI：

  10.1021/ol015524y

文献信息

• Cu²⁺-Induced Blue Shift of the Pyrene Excimer Emission:  A New Signal Transduction Mode of Pyrene Probes
  作者：Jye-Shane Yang、Che-Sheng Lin、Chung-Yu Hwang

  DOI：10.1021/ol015524y

  日期：2001.3.1

  [GRAPHICS]A pentiptycene-bispyrenyl system (1) has been synthesized and investigated as a fluorescent chemosensor for metal ions, A novel blue shift along with an intensity enhancement of the pyrene excimer emission is observed for 1 in the presence of Cu2+. Such a new signal transduction mode of pyrene probes results from the formation of a static pyrene excimer that has very different characteristics from its dynamic counterpart.