(2-甲基戊基)苯 | 39916-61-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (2-甲基戊基)苯
• 英文名称: 2-Benzyl-pentan
• 英文别名: (2-Methylpentyl)benzene；2-methylpentylbenzene
• CAS: 39916-61-5
• 化学式: C₁₂H₁₈
• mdl: MFCD00049126
• 分子量: 162.275
• InChiKey: LFBQYMCKHGBSJY-UHFFFAOYSA-N

物化性质

• 保留指数：
  1191;1191;1196;1205.2

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2902909090

反应信息

• 作为反应物：
  描述：

  (2-甲基戊基)苯 在 chlorosulphuric acid 作用下， 生成 4-(2-methyl-pentyl)-benzenesulfonic acid amide
  参考文献：
  名称：

  死Strukturformel DES第三人以elektrochemische Reduktion冯甲基苄基acetessigester gewonnenen KohlenwasserstoffsÇ 12 ħ 18（塔菲尔“血清胆碱酯酶Umlagerung III）

  摘要：

  DOI：

  10.1002/hlca.193702001119
• 作为产物：
  描述：

  2-甲基-1-苯基-1-戊醇 在 磷化氢 、 氢碘酸 作用下， 生成 (2-甲基戊基)苯
  参考文献：
  名称：

  死Strukturformel DES第三人以elektrochemische Reduktion冯甲基苄基acetessigester gewonnenen KohlenwasserstoffsÇ 12 ħ 18（塔菲尔“血清胆碱酯酶Umlagerung III）

  摘要：

  DOI：

  10.1002/hlca.193702001119

文献信息

• Chemistry of bivalent carbon intermediates—IV
  作者：C.D. Gutsche、G.L. Bachman、R.S. Coffey

  DOI：10.1016/s0040-4020(01)92713-9

  日期：1962.1

  By means of competition experiments phenylcarbene, generated from phenyldiazomethane, has been shown to be approximately equally reactive to the benzene ring (to form phenylcycloheptatriene) and to aliphatic CH2 bonds, to be approximately six times more reactive to aliphatic CH2 bonds than to aliphatic CH2 bonds, and to be very unreactive toward aromatic CH bonds. These data have been used as aids

  通过竞争实验苯基碳烯，从phenyldiazomethane生成的手段，已经被证明是近似相等反应性的苯环（以形成phenylcycloheptatriene）和脂族CH 2个键的，为大约六倍以上反应性脂族CH 2个键比脂族CH 2键，并且对芳族CH键非常不活泼。这些数据已被用来帮助解释两个先前报道的结果1 b，1 c分子内对应物；它们还用于解释2-正丁基苯基重氮甲烷的分解，该分解生成比例大约为6：5：1的三种环状产物2-乙基茚满，2-甲基四氢萘和苯并双氢呋喃，以及第四种烃产物1- （邻甲苯基）-丁烯-2，代表卡宾反应的新模式。研究了温度和光源对2-正丁基苯基重氮甲烷分解产物比例的影响。
• Factors Affecting Heavy-Duty Diesel Vehicle Emissions
  作者：Nigel N. Clark、Justin M. Kern、Christopher M. Atkinson、Ralph D. Nine

  DOI：10.1080/10473289.2002.10470755

  日期：2002.1

  Societal and governmental pressures to reduce diesel exhaust emissions are reflected in the existing and projected future heavy-duty certification standards of these emissions. Various factors affect the amount of emissions produced by a heterogeneous charge diesel engine in any given situation, but these are poorly quantified in the existing literature. The parameters that most heavily affect the emissions from compression ignition engine-powered vehicles include vehicle class and weight, driving cycle, vehicle vocation, fuel type, engine exhaust aftertreatment, vehicle age, and the terrain traveled. In addition, engine control effects (such as injection timing strategies) on measured emissions can be significant. Knowing the effect of each aspect of engine and vehicle operation on the emissions from diesel engines is useful in determining methods for reducing these emissions and in assessing the need for improvement in inventory models. The effects of each of these aspects have been quantified in this paper to provide an estimate of the impact each one has on the emissions of diesel engines.
• High Pressure Thermal Alkylation of Monoalkylbenzenes by Simple Olefins¹
  作者：Herman Pines、Joseph T. Arrigo

  DOI：10.1021/ja01575a036

  日期：1957.9
• Enantioselective Carbometalation of Cinnamyl Derivatives: New Access to Chiral Disubstituted Cyclopropanes— Configurational Stability of Benzylic Organozinc Halides
  作者：Stephanie Norsikian、Ilan Marek、Sophie Klein、Jean F. Poisson、Jean F. Normant

  DOI：10.1002/(sici)1521-3765(19990702)5:7<2055::aid-chem2055>3.0.co;2-9

  日期：1999.7.2
• Alkylation-reduction of carbonyl systems. IV. Convenient and selective synthesis of simple and complex aromatic hydrocarbons by phenylation-reduction of aldehydes and ketones
  作者：Stan S. Hall、Frank J. McEnroe

  DOI：10.1021/jo00891a001

  日期：1975.2

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