(2E,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯 | 83168-67-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 中文名称: (2E,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯
• 英文名称: trans,trans-Perfluoro-2,4-hexadiene
• 英文别名: (E,E)-Perfluoro-2,4-hexadiene；(2E,4E)-1,1,1,2,3,4,5,6,6,6-decafluorohexa-2,4-diene
• CAS: 83168-67-6
• 化学式: C₆F₁₀
• 分子量: 262.05
• InChiKey: ITEBVUXKIREBFG-ZPUQHVIOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  10

安全信息

• 海关编码：
  2903399090

反应信息

• 作为反应物：
  描述：

  (2E,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯 生成 Cyclobutene, 1,2,3,4-tetrafluoro-3,4-bis(trifluoromethyl)-, trans-
  参考文献：
  名称：

  全氟二烯和环丁烯热电环相互转化的动力学和热力学研究

  摘要：

  Les dienes (Z,Z) ou (Z) presentent un avantage cinetique important sur les diene (E,L) ou (E) dans leur processus de cyclisation

  DOI：

  10.1021/ja00235a032
• 作为产物：
  描述：

  Cyclobutene, 1,2,3,4-tetrafluoro-3,4-bis(trifluoromethyl)-, trans- 生成 (2E,4E)-1,1,1,2,3,4,5,6,6,6-十氟己-2,4-二烯
  参考文献：
  名称：

  全氟二烯和环丁烯热电环相互转化的动力学和热力学研究

  摘要：

  Les dienes (Z,Z) ou (Z) presentent un avantage cinetique important sur les diene (E,L) ou (E) dans leur processus de cyclisation

  DOI：

  10.1021/ja00235a032

文献信息

• Remarkable, contrasteric, electrocyclic ring opening of a cyclobutene
  作者：William R. Dolbier、Henryk Koroniak、Donald J. Burton、A. R. Bailey、G. S. Shaw、S. W. Hansen

  DOI：10.1021/ja00318a071

  日期：1984.3

  Etude thermodynamique et cinetique de la decyclisation des cis et trans bis-trifluoromethyl-3,4 tetrafluoro-1,2,3,4 cyclobutenes

  顺式和反式双三氟甲基-3,4 四氟-1,2,3,4 环丁烯去环化练习曲
• METHOD OF DRY ETCHING, DRY ETCHING GAS AND PROCESS FOR PRODUCING PERFLUORO-2-PENTYNE
  申请人：Zeon Corporation

  公开号：EP1542268A1

  公开（公告）日：2005-06-15

  A dry etching method wherein a resist film is irradiated with radiation having a wavelength of not more than 195 nm to form a resist pattern having a minimum line width of not more than 200 nm, and the substrate having the resist pattern formed thereon is subjected to dry etching using a fluorine-containing compound having 4 to 6 carbon atoms and at least one unsaturated bond as an etching gas. As the fluorine-containing compound, perfuloro-2-pentyne, perfuloro-2-butyne, nonafluoro-2-pentene and perfluoro-2-pentene are preferably used. Perfuloro-2-pentyne is produced by a process wherein a 1,1,1-trihalo-2,2,2-trifluoroethane is allowed to react with pentafluoropropionaldehyde to give a 2-halo-1,1,1,4,4,5,5,5-octafluoro-2-pentene, and the thus-produced halo-octafluoro-2-pentene is dehydrohalogenated.

  一种干法蚀刻方法，其中用波长不超过 195 纳米的辐射照射抗蚀剂薄膜，以形成最小线宽不超过 200 纳米的抗蚀剂图案，并使用具有 4 至 6 个碳原子和至少一个不饱和键的含氟化合物作为蚀刻气体，对在其上形成了抗蚀剂图案的基板进行干法蚀刻。作为含氟化合物，最好使用全氟-2-戊炔、全氟-2-丁炔、非全氟-2-戊烯和全氟-2-戊烯。全氟-2-戊炔的生产工艺是：1,1,1-三卤-2,2,2-三氟乙烷与五氟丙醛反应生成 2-卤-1,1,1,4,4,5,5,5-八氟-2-戊烯，然后将生成的卤代八氟-2-戊烯进行脱氢卤化。
• MULTILAYER BODY, LIGHT-EMITTING DEVICE AND USE THEREOF
  申请人：ZEON CORPORATION

  公开号：EP1745922A1

  公开（公告）日：2007-01-24

  A layered product comprising: sealing film comprising a laminate of at least one organic film and at least one inorganic film, and transparent resin substrate; in which the organic film is made from fluorine compound or alicyclic structure containing polymer and metallic simple substance or metallic compound as raw material, and in which the inorganic film is made from metallic simple substance or metallic compound as raw material. A luminescence device comprising: substrate, and lower electrode layer, luminescent-material layer, upper electrode layer and sealing film which are laminated in turn on the substrate; in which the substrate and the sealing layer comprises the layered product.

  一种分层产品，包括：由至少一种有机薄膜和至少一种无机薄膜层压而成的密封膜，以及透明树脂基板；其中有机薄膜由含氟化合物或脂环结构聚合物和金属单质或金属化合物为原料制成，无机薄膜由金属单质或金属化合物为原料制成。一种发光装置，包括：基板、依次层叠在基板上的下电极层、发光材料层、上电极层和密封膜；其中基板和密封层为分层产品。
• Method of dry etching, dry etching gas and process for producing perfluoro-2-pentyne
  申请人：Yamada Toshiro

  公开号：US20050247670A1

  公开（公告）日：2005-11-10

  A dry etching method wherein a resist film is irradiated with radiation having a wavelength of not more than 195 nm to form a resist pattern having a minimum line width of not more than 200 nm, and the substrate having the resist pattern formed thereon is subjected to dry etching using a fluorine-containing compound having 4 to 6 carbon atoms and at least one unsaturated bond as an etching gas. As the fluorine-containing compound, perfuloro-2-pentyne, perfuloro-2-butyne, nonafluoro-2-pentene and perfluoro-2-pentene are preferably used. Perfuloro-2-pentyne is produced by a process wherein a 1,1,1-trihalo-2,2,2-trifluoroethane is allowed to react with pentafluoropropionaldehyde to give a 2-halo-1,1,1,4,4,5,5,5-octafluoro-2-pentene, and the thus-produced halo-octafluoro-2-pentene is dehydrohalogenated.

  一种干法蚀刻方法，其中用波长不超过 195 纳米的辐射照射抗蚀剂薄膜，以形成最小线宽不超过 200 纳米的抗蚀剂图案，并使用具有 4 至 6 个碳原子和至少一个不饱和键的含氟化合物作为蚀刻气体，对在其上形成了抗蚀剂图案的基板进行干法蚀刻。作为含氟化合物，最好使用全氟-2-戊炔、全氟-2-丁炔、非全氟-2-戊烯和全氟-2-戊烯。全氟-2-戊炔的生产工艺是：1,1,1-三卤-2,2,2-三氟乙烷与五氟丙醛反应生成 2-卤-1,1,1,4,4,5,5,5-八氟-2-戊烯，然后将生成的卤代八氟-2-戊烯进行脱氢卤化。
• Transformations of <i>F</i>-Alkyl Iodides and Bromides Induced by Nickel(0) Carbonyl
  作者：Carl G. Krespan、David A. Dixon

  DOI：10.1021/jo970805y

  日期：1998.1.1

  Adducts of primary F-alkyl iodides with nickel carbonyl are formed readily in donor solvents and pyrolyze at 100-150 degrees C to give olefinic coupling products in high yield. The mechanism proposed to account for the observed chemistry involves preferential alpha-elimination of fluorine with formation of a carbenoid species complex coordinated to nickel. Differences in reaction paths among several types of substrate halides are rationalized on the basis of polarization of the Ni-C bond in the adducts, Support for these proposals is provided by state-of-the-art calculations.