(4-乙烯基苯基)甲基N,N-二乙基氨基二硫代甲酸酯 | 99798-43-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: (4-乙烯基苯基)甲基N,N-二乙基氨基二硫代甲酸酯
• 英文名称: N,N-(diethylamino)dithiocarbamoylmethylstyrene
• 英文别名: 4-[(N,N-diethyldithiocarbamyl)methyl]styrene；4-vinylbenzyl N,N-diethyldithiocarbamate；Carbamodithioic acid, diethyl-, (4-ethenylphenyl)methyl ester；(4-ethenylphenyl)methyl N,N-diethylcarbamodithioate
• CAS: 99798-43-3
• 化学式: C₁₄H₁₉NS₂
• 分子量: 265.444
• InChiKey: YMQKPVAQCHGDGY-UHFFFAOYSA-N

物化性质

• 沸点：
  371.7±45.0 °C(Predicted)
• 密度：
  1.103±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  60.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-氯甲基苯乙烯 、 sodium N,N-diethyldithiocarbamate 以 丙酮 为溶剂， 反应 1.0h， 以97%的产率得到(4-乙烯基苯基)甲基N,N-二乙基氨基二硫代甲酸酯
  参考文献：
  名称：

  由超支化聚合物和银离子自组装的水纳米球：分子包裹体和光还原特性

  摘要：

  具有（N，N-二乙氨基）二硫代氨基甲酰基（DC）单元作为外围基团（HBP-DC）在硝酸银水溶液中自发形成纳米球。尽管HBP-DC本身不溶于水，但Ag（I）离子与表面DC单元的配位会产生阳离子电荷，从而使Ag（I）/ HBP-DC复合物可分散在水中并驱动其自组装成纳米球。这些Ag（I）/ HBP-DC络合物在自组装过程中显示出疏水客体分子的结合。当将四苯基卟啉（TPP）和HBP-DC的THF混合物添加到硝酸银水溶液中时，观察到TPP的荧光很强。由于TPP分子注入水中时会形成不发光的聚集体，因此在水性Ag（I）/ HBP-DC纳米球中观察到的发光表明TPP分子被限制在水性纳米球的疏水内部。同时，Ag（I）/ HBP-DC纳米球的表面用作产生银纳米晶体的支架。在Ag（I）/ HBP-DC纳米球表面上形成的Ag（I）-DC络合物经过光还原，产生小的银纳米晶体均匀分布在纳米球上。取决于反应条件，银纳

  DOI：

  10.1021/ma1017956

文献信息

• POLYMERIC COATINGS AND METHODS FOR FORMING THEM
  申请人：Meagher Laurence

  公开号：US20080045686A1

  公开（公告）日：2008-02-21

  The present invention relates to a controllable polymeric surface coating including a macromolecule, which is covalently bound to the surface of a substrate, the macromolecule including a plurality of polymerisation initiators and a plurality of surface binding groups; and pendant polymers grafted from at least some of the polymerisation initiators.

  本发明涉及一种可控的聚合物表面涂层，包括一种大分子，该大分子与基底表面共价结合，该大分子包括多个聚合引发剂和多个表面结合基团；并且从至少一些聚合引发剂上生长的悬挂聚合物。
• METHOD FOR PRODUCING HYPERBRANCHED POLYMER
  申请人：Nissan Chemical Industries, Ltd.

  公开号：EP2202248A1

  公开（公告）日：2010-06-30

  There is provided a method for producing a hyperbranched polymer. A method for producing a hyperbranched polymer comprising polymerizing a dithiocarbamate compound of Formula (1): wherein R1 is H or CH3; R2 and R3 are individually a C1-5 alkyl group, etc., A1 is Formula (2) and/or Formula (3): wherein A2 is a linear, branched or cyclic C1-30 alkylene group that optionally contains an ether bond or an ester bond and X1, X2, X3 and X4 are each independently H, a C1-20 alkyl group, etc., by heating at 50 to 250°C.

  本发明提供了一种生产超支化聚合物的方法。生产超支化聚合物的方法包括聚合式（1）的二硫代氨基甲酸酯化合物： 其中 R1 是 H 或 CH3；R2 和 R3 分别是 C1-5 烷基等，A1 是式 (2) 和/或式 (3)： 其中 A2 是线性、支链或环状 C1-30 亚烷基，可选择含有醚键或酯键，X1、X2、X3 和 X4 各自独立地为 H、C1-20 烷基等。
• CURABLE MATERIAL CONTAINING PHOTOPOLYMERIZABLE POLYMER AND CURED OBJECT
  申请人：Yasui Kei

  公开号：US20100144957A1

  公开（公告）日：2010-06-10

  There is provided a curable material capable of manufacturing a cured object by ultraviolet irradiation without using a photopolymerization initiator or additive and a cured object obtained therefrom, and, in particular, provided a film-forming material capable of manufacturing a cured film and the cured film obtained therefrom. The curable material comprises a branched and/or linear photopolymerizable polymer having an N,N-dialkyldithiocarbamate group as a functional group at a molecular end. The film-forming material is composed of the curable material, and the cured object is obtained by photopolymerization of the curable material to effect inter-bonding and the cured film is obtained by photopolymerization of the film-forming material to effect inter-bonding and form a film.
• HYPERBRANCHED POLYMER HAVING NITROXYL GROUP
  申请人：Koga Noboru

  公开号：US20100249350A1

  公开（公告）日：2010-09-30

  There is provided a hyperbranched polymer having a nitroxyl group. A hyperbranched polymer comprising at least one organic radical structure (nitroxyl group) of Formula (1), Formula (2) or Formula (3): and having a weight average molecular weight measured by gel permeation chromatography in a converted molecular weight as polystyrene of 500 to 5,000,000.
• ORGANIC SWITCHING ELEMENT AND METHOD FOR PRODUCING THE SAME
  申请人：Fujita Katsuhiko

  公开号：US20100289012A1

  公开（公告）日：2010-11-18

  There is provided a switching element including two electrodes and an organic bistable material sandwiched between the electrodes, which is expected to be applied to an organic memory element or the like. A switching element which includes: two electrodes; and an organic thin film containing a metal fine particle and interposed between the electrodes, and which exhibits such a current bistability that the switching element has two stable resistance values in response to a voltage applied, the switching element characterized in that the metal fine particle is dispersed in the organic thin film with a metal fine particle-dispersing agent containing a polymer having a dithiocarbamate group and having a weight average molecular weight of 500 to 5,000,000.