(6ci,9ci)-1-环己烯-1,3-二羧酸 | 109940-58-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: (6ci,9ci)-1-环己烯-1,3-二羧酸
• 英文名称: Δ²-tetrahydroisophthalic acid
• 英文别名: cyclohex-1-ene-1,3-dicarboxylic acid；Cyclohex-1-en-1,3-dicarbonsaeure；cyclohexene-1,3-dicarboxylic acid
• CAS: 109940-58-1
• 化学式: C₈H₁₀O₄
• 分子量: 170.165
• InChiKey: FCTPXMGHGVCNMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  12
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  盐酸 、 (6ci,9ci)-1-环己烯-1,3-二羧酸 生成 Δ³-tetrahydroisophthalic acid
  参考文献：
  名称：

  386.谷氨酸和酯的结构。第八部分谷氨酸和柠康酸系列的一些环状化合物

  摘要：

  DOI：

  10.1039/jr9330001628
• 作为产物：
  描述：

  1-环己烯羧酸乙酯 在 氢氧化钾 、 sodium ethanolate 作用下， 生成 (6ci,9ci)-1-环己烯-1,3-二羧酸
  参考文献：
  名称：

  386.谷氨酸和酯的结构。第八部分谷氨酸和柠康酸系列的一些环状化合物

  摘要：

  DOI：

  10.1039/jr9330001628

文献信息

• Reactive polymer-supporting porous film for battery seperator and use thereof
  申请人：Uetani Yoshihiro

  公开号：US20060257727A1

  公开（公告）日：2006-11-16

  The invention provides a reactive polymer-supporting porous film for use as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film, the partially crosslinked reactive polymer being obtained by the reaction of a crosslinkable polymer having at least one reactive group selected from the group consisting of 3-oxetanyl group and epoxy group in the molecule with a polycarboxylic acid. The reactive polymer-supporting porous film for use as a battery separator has a separator and electrodes sufficiently bonded to each other and low inner resistance so that it is suitably used for production of battery excellent in high rate performance. Further, the invention provides a method of producing a battery which comprises placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container thereby bonding the porous film and the electrodes together.

  本发明提供一种反应性聚合物支持多孔膜，用于作为电池隔膜，包括多孔基底膜和部分交联的反应性聚合物支持在多孔基底膜上，所述部分交联的反应性聚合物是通过交联性聚合物与多羧酸反应而得到的，所述交联性聚合物在分子中至少具有3-氧杂环基团和环氧基团中的一种反应性基团。作为电池隔膜使用的反应性聚合物支持多孔膜，具有足够紧密结合的隔膜和电极以及低内阻，因此适用于生产高速性能优异的电池。此外，本发明还提供一种电池的制造方法，其中包括将电极/反应性聚合物支持多孔膜层状体放置在电池容器中；向电池容器中引入含有阳离子聚合催化剂的电解液，从而将多孔膜和电极粘合在一起。
• REACTIVE POLYMER-SUPPORTING POROUS FILM FOR BATTERY SEPARATOR AND USE THEREOF
  申请人：Uetani Yoshihiro

  公开号：US20110232081A1

  公开（公告）日：2011-09-29

  A reactive polymer-supporting porous film is provided as a battery separator which comprises a porous substrate film and a partially crosslinked reactive polymer supported on the porous substrate film. The partially crosslinked reactive polymer is obtained by the reaction of a crosslinkable polymer having at least one group selected from the 3-oxetanyl group and epoxy group reactive with a polycarboxylic acid. The reactive polymer-supporting porous film has a separator and electrodes sufficiently bonded to each other and with low inner resistance suitably used for production of battery excellent in high rate performance. Further, provided is a method of producing a battery which comprises placing the electrode/reactive polymer-supporting porous film layered body in a battery container; introducing an electrolytic solution containing a cationic polymerization catalyst into the battery container thereby bonding the porous film and electrodes together.

  提供一种反应性聚合物支撑多孔膜作为电池隔膜，包括一个多孔基底膜和部分交联的反应性聚合物支撑在多孔基底膜上。部分交联的反应性聚合物是通过交联聚合物与至少具有3-氧杂环基团和环氧基团之一的可反应羧酸反应而得到的。反应性聚合物支撑多孔膜具有足够粘结的隔膜和电极，内阻低，适用于生产高速性能优异的电池。此外，还提供了一种制造电池的方法，包括将电极/反应性聚合物支撑多孔膜层状体放置在电池容器中；向电池容器中引入含有阳离子聚合催化剂的电解质溶液，从而将多孔膜和电极粘结在一起。
• Aromatic polycarbonate resin composition
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0905184A2

  公开（公告）日：1999-03-31

  An aromatic polycarbonate resin composition having hydroxyl groups as end groups is thermally stable and also offers excellent resistance to hydrolysis. The polycarbonate resin composition incorporates (A) an aromatic polycarbonate resin containing hydroxyl groups in the proportion of 5% or more of the total end groups and a metal impurity and (B) a deactivating agent selected from the group consisting of phosphorous acid, a thioether compound, a phosphite diester and a nitrogen-containing organic compound. The amount deactivating agent is based on the amount of metal impurity in (A) and the type of deactivating agent.

  一种以羟基为端基的芳香族聚碳酸酯树脂组合物具有热稳定性，并具有优异的耐水解性。这种聚碳酸酯树脂组合物包括：(A) 含羟基的芳香族聚碳酸酯树脂（占端基总量的 5%或以上）和金属杂质；(B) 选自磷酸、硫醚化合物、亚磷酸二酯和含氮有机化合物的失活剂。失活剂的用量取决于（A）中金属杂质的用量和失活剂的种类。
• COMPOSITE FORMED BODY AND METHOD FOR PRODUCING SAME, AND RESIN FOR BONDING
  申请人：Daicel-Degussa Ltd.

  公开号：EP1671785A1

  公开（公告）日：2006-06-21

  In a molded composite article, a resin member comprising a non-urethane-series thermoplastic resin and a resin member comprising a thermoplastic polyurethane-series resin are directly joined with each other; and the non-urethane-series thermoplastic resin is a non-urethane-series thermoplastic resin (Ib) or (IIb), and the non-urethane-series thermoplastic resin and the thermoplastic polyurethane-series resin fulfill a following requirement (Ia) or (IIa), (Ia): the non-urethane-series thermoplastic resin (Ib) comprises at least one member selected from the group consisting of a polyamide component having an alicyclic ring, and an amino group-containing compound, or (IIa): each of the non-urethane-series thermoplastic resin (IIb) and the thermoplastic polyurethane-series resin has a polyether segment. The resin composition (Ib) may be a resin composition (Ib-2) containing a non-urethane-series thermoplastic resin and the amino group-containing compound. The molded composite article can be produced by heating at least one selected from the non-urethane-series thermoplastic resin and thermoplastic polyurethane-series resin to join the other. Even if the base resin is a non-urethane-series thermoplastic resin, the present invention achieves a direct and firm bonding between the non-urethane-series thermoplastic resin member and the thermoplastic polyurethane-series resin member which were different in properties from each other by a simple process.

  在模塑复合材料制品中，由非聚氨酯系列热塑性树脂组成的树脂构件和由热塑性聚氨酯系列树脂组成的树脂构件彼此直接连接；并且非聚氨酯系列热塑性树脂是非聚氨酯系列热塑性树脂（Ib）或（IIb），并且非聚氨酯系列热塑性树脂和热塑性聚氨酯系列树脂满足以下要求（Ia）或（IIa），（Ia）：非氨甲酸酯系列热塑性树脂（Ib）包含至少一种选自具有脂环的聚酰胺组分和含氨基化合物的成员，或 (IIa)：非氨甲酸酯系列热塑性树脂（IIb）和热塑性聚氨酯系列树脂中的每一种都具有聚醚段。树脂组合物（Ib）可以是含有非聚氨酯系列热塑性树脂和含氨基化合物的树脂组合物（Ib-2）。模塑复合材料制品可通过加热从非聚氨酯系列热塑性树脂和热塑性聚氨酯系列树脂中选出的至少一种树脂，使其与另一种树脂接合而制成。即使基体树脂是非氨甲酸乙酯系列热塑性树脂，本发明也能通过简单的工艺，使性质不同的非氨甲酸乙酯系列热塑性树脂构件和热塑性聚氨脂系列树脂构件直接牢固地结合在一起。
• PLASTICIZER FOR VINYL CHLORIDE RESIN CONTAINING NON-PHTHALATE ESTER AND VINYL CHLORIDE RESIN COMPOSITION CONTAINING SUCH PLASTICIZER
  申请人：New Japan Chemical Co., Ltd.

  公开号：EP3124540A1

  公开（公告）日：2017-02-01

  An object of the present invention is to provide a plasticizer for vinyl chloride-based resin superior in cold resistance and volatility resistance, and desirable in flexibility, fogging resistance, heat discoloration resistance, and weather resistance, and to also provide a vinyl chloride-based resin composition comprising the plasticizer. An ester obtained by reacting a specific carboxylic acid or a derivative thereof with a C9 saturated aliphatic alcohol at a specific proportion is superior in cold resistance and volatility resistance, and desirable in flexibility, fogging resistance, heat discoloration resistance, and weather resistance. Therefore, it becomes possible to obtain a vinyl chloride-based resin composition applicable to automobile parts, medical materials, or the like, as well as a molded article of the vinyl chloride-based resin composition.

  本发明的目的是提供一种用于氯乙烯基树脂的增塑剂，该增塑剂具有优异的耐寒性和耐挥发性，以及理想的柔韧性、耐雾性、耐热变色性和耐候性，同时还提供一种含有该增塑剂的氯乙烯基树脂组合物。 由特定比例的特定羧酸或其衍生物与 C9 饱和脂肪醇反应而得的酯类具有优异的耐寒性和耐挥发性，并具有理想的柔韧性、耐雾性、耐热变色性和耐候性。因此，可以获得适用于汽车零件、医疗材料等的氯乙烯基树脂组合物，以及氯乙烯基树脂组合物的成型品。