(9CI)-4-乙基-2,5,6-三甲基嘧啶 | 120537-58-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 中文名称: (9CI)-4-乙基-2,5,6-三甲基嘧啶
• 英文名称: 2,5,6-trimethyl-4-ethylpyrimidine
• 英文别名: 4-Ethyl-2,5,6-trimethylpyrimidine
• CAS: 120537-58-8
• 化学式: C₉H₁₄N₂
• 分子量: 150.224
• InChiKey: NYGKPQOGORUBSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  3-戊酮 、 乙腈 在 三氟甲磺酸酐 作用下， 生成 (9CI)-4-乙基-2,5,6-三甲基嘧啶
  参考文献：
  名称：

  二维超快TOCSY NMR光谱法实时监测有机反应

  摘要：

  快速浏览所有内容：提出了一次扫描的二维超快TOCSY实验，并用于研究由脂肪族酮，腈和Tf 2 O合成嘧啶的方法。记录了525个二维TOCSY实验，可以监测反应物，中间体和产物（参见图片；蓝色=产物；灰色，绿色和粉红色=中间体）。

  DOI：

  10.1002/anie.200902387

文献信息

• Fibre-Reactive Dyes, Their Preparation and Their Use
  申请人：Huntsman International LLC

  公开号：US20150096131A1

  公开（公告）日：2015-04-09

  Reactive dyes of formula (1) wherein Q 1 and Q 2 are each independently of the other hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, A is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore, X is halogen, 3- or 4-carboxypyridin-1-yl, or 3- or 4-carbamoylpyridin-1-yl, Y is vinyl or a radical —CH 2 —CH 2 —U and U is a group removable under alkaline conditions, and q is the number 1 or 2, are suitable for dyeing and printing cellulosic or amide-group-containing fibre materials.

  式子（1）中的反应性染料，其中Q1和Q2各自独立地是氢原子或未取代或取代的C1-C4烷基，A是单偶氮，多偶氮，金属络合偶氮，蒽醌，酞菁，福马赞或二氧杂芥子嗪色团的基团，X是卤素，3-或4-羧基吡啶-1-基，或3-或4-氨基甲酰基吡啶-1-基，Y是乙烯或基团-CH2-CH2-U，U是在碱性条件下可去除的基团，q是数字1或2，适用于染色和印刷纤维素或含酰胺基团的纤维材料。
• Martinez, A. Garcia; Herrera, A.; Martinez, R., Journal of Heterocyclic Chemistry, 1988, vol. 25, p. 1237 - 1241
  作者：Martinez, A. Garcia、Herrera, A.、Martinez, R.、Teso, E.、Garcia, A.、et al.

  DOI：——

  日期：——
• On the mechanism of the reaction between ketones and trifluoromethanesulfonic anhydride. An improved and convenient method for the preparation of pyrimidines and condensed pyrimidines
  作者：A. Garcia Martinez、A. Herrera Fernandez、F. Moreno Jimenez、A. Garcia Fraile、L. R. Subramanian、M. Hanack

  DOI：10.1021/jo00031a062

  日期：1992.2
• Fibre-Reactive Dyes, Their Preparation And Their Use
  申请人：Tzikas Athanassios

  公开号：US20080250575A1

  公开（公告）日：2008-10-16

  Reactive dyes of formula wherein Q 1 and Q 2 are each independently of the other hydrogen or unsubstituted or substituted C 1 -C 4 alkyl, D 1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D 2 has the same definition as D 1 or is a radical of formula wherein (Q 3 ) 0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C 1 -C 4 alkyl, C 1 -C 4 alkoxy, carboxy and sulfo and Z 1 is a radical of formula —SO 2 —Y ,   (3a) —NH—CO—(CH 2 ) m —SO 2 —Y ,   (3b) —CONH—(CH 2 ) n —SO 2 —Y ,   (3c) —NH—CO—CH(Hal)-CH 2 -Hal or   (3d) —NH—CO—C(Hal)=CH 2 ,   (3e) Y is vinyl or a —CH 2 —CH 2 —U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
• Functionalized particles
  申请人：Kulke Torsten

  公开号：US20110077375A1

  公开（公告）日：2011-03-31

  Functionalized particles having fully formed shells and cores comprising a polyurethane or polyurea matrix obtained by interfacial addition polymerisation of (i) at least one polyisocyanate derivative selected from the group of partially blocked polyisocyanates and polyisocyanates partially modified with fiber reactive groups and (ii) at least one polyamine or polyhydric alcohol, said functionalized particles being capable to chemically or physically bind to a substrate.