(Z)-4-十三碳烯-1-醇乙酸酯 | 65954-19-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: (Z)-4-十三碳烯-1-醇乙酸酯
• 英文名称: (Z)-4-Tridecen-1-yl acetate
• 英文别名: [(Z)-tridec-4-enyl] acetate
• CAS: 65954-19-0
• 化学式: C₁₅H₂₈O₂
• 分子量: 240.38
• InChiKey: DUCVQKMNGSZPAV-KHPPLWFESA-N

物化性质

• 沸点：
  282.5±9.0℃ (760 Torr)
• 密度：
  0.879±0.06 g/cm3 (20 ºC 760 Torr)
• 闪点：
  74.8±17.1℃
• LogP：
  5.884 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

ADMET

毒理性

• 毒性数据

大鼠 LC50 > 2500 mg/m³

LC50 (rat) > 2,500 mg/m3

来源:Haz-Map, Information on Hazardous Chemicals and Occupational Diseases

文献信息

• Polyamide-polyether block copolymer
  申请人：Arizona Chemical Company

  公开号：US20040186263A1

  公开（公告）日：2004-09-23

  Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy) diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.25; and c) the reaction mixture contains either no co-diacid, or comprises a small amount of co-diacid, wherein, if the reaction mixture comprises a small amount of co-diacid, then acid equivalents from co-diacid contribute less than 25% of the total acid equivalents present in the reaction mixture.

  具有链接内部聚醚块和内部聚酰胺块的共聚物具有优越的物理性能和溶剂凝胶能力。该共聚物可以从含有1,4-环己二甲酸（CHDA）和聚（烷氧基）二胺（PAODA）的反应混合物中制备。可选地，反应混合物不含有与胺或羧酸基团中任何一种反应的单官能化合物，但是某些单官能化合物可能存在。二聚胺和/或二聚酸可以存在于反应混合物中。共聚物也可以从含有二聚酸和至少两种二胺化合物（包括PAODA和具有2-6个碳的短链脂肪二胺（SDA））的反应混合物中制备，其中：a）反应混合物包含x克PAODA和y克SDA，且x/（x+y）为0.8-0.98; b）反应混合物重z克，且x/z至少为0.25; c）反应混合物不含共二酸，或含有少量共二酸，其中，如果反应混合物含有少量共二酸，则共二酸的酸当量贡献少于反应混合物中总酸当量的25％。
• POLYAMIDE-POLYETHER BLOCK COPOLYMER
  申请人：Pavlin S. Mark

  公开号：US20070244294A1

  公开（公告）日：2007-10-18

  Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy) diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.25; and c) the reaction mixture contains either no co-diacid, or comprises a small amount of co-diacid, wherein, if the reaction mixture comprises a small amount of co-diacid, then acid equivalents from co-diacid contribute less than 25% of the total acid equivalents present in the reaction mixture.

  具有连接的内部聚醚块和内部聚酰胺块的共聚物具有优越的物理性能和溶剂凝胶能力。该共聚物可以从含有1,4-环己烷二羧酸（CHDA）和聚（烷氧基）二胺（PAODA）的反应混合物中制备。可选地，反应混合物不含与胺基或羧酸基反应的单官能化合物，但其中一些单官能化合物可能存在。二聚胺和/或二聚酸可以存在于反应混合物中。共聚物也可以从含有二聚酸和至少两种二胺化合物（包括PAODA和具有2-6个碳的短链脂肪族二胺（SDA））的反应混合物中制备，其中：a）反应混合物包含x克PAODA和y克SDA，且x/（x+y）为0.8-0.98；b）反应混合物重z克，且x/z至少为0.25；c）反应混合物不含共二酸，或包含少量共二酸，其中，如果反应混合物包含少量共二酸，则共二酸的酸当量贡献的总酸当量不超过反应混合物中总酸当量的25％。
• Polyamide-Polyether Block Copolymer
  申请人：Pavlin Mark S.

  公开号：US20090082460A1

  公开（公告）日：2009-03-26

  Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy)diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.25; and c) the reaction mixture contains either no co-diacid, or comprises a small amount of co-diacid, wherein, if the reaction mixture comprises a small amount of co-diacid, then acid equivalents from co-diacid contribute less than 25% of the total acid equivalents present in the reaction mixture.

  含有链接的内部聚醚块和内部聚酰胺块的共聚物具有优越的物理性能和溶剂凝胶能力。该共聚物可以从反应混合物中制备而成，该反应混合物包含1,4-环己烷二甲酸（CHDA）和聚（烷氧基）二胺（PAODA）。可选地，反应混合物不含与胺或羧酸基反应的单官能化合物，但此类单官能化合物中的一些可能存在。二聚胺和/或二聚酸可以存在于反应混合物中。共聚物也可以从反应混合物中制备而成，该反应混合物包含二聚酸和至少两种二胺化合物，包括PAODA和具有2-6个碳的短链脂肪族二胺（SDA），其中：a）反应混合物包含x克PAODA和y克SDA，且x/（x+y）为0.8-0.98；b）反应混合物重量为z克，且x/z至少为0.25；c）反应混合物不含共二酸，或包含少量共二酸，其中，如果反应混合物包含少量共二酸，则共二酸的酸当量贡献的总酸当量不超过反应混合物中的总酸当量的25％。
• SUSTAINED RELEASE PHEROMONE PREPARATION AND METHOD FOR CONTROLLING INSECT PEST USING THE SAME
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3888460A1

  公开（公告）日：2021-10-06

  There is provided a sustained release pheromone preparation including a mixture containing a first unsaturated aliphatic acetate compound having one carbon-carbon double bond and a second unsaturated aliphatic acetate compound having two carbon-carbon double bonds in a mass ratio of 0.5:99.5 to 99.5:0.5, each compound having the same total number of carbon atoms; and a container containing the mixture therein and including, as a part or whole of the container, a membrane of a linear aliphatic polyester containing one or more selected from the following repeating unit (I); wherein the preparation targets at at least one type of insect pest whose sex pheromone substances contains both of the first and second compounds, or targets at at least one type of insect pest whose sex pheromone substance contains one of them and at least one type of insect pest sex pheromone substance or substances contains the other or both of them.

  本发明提供了一种缓释信息素制剂，包括一种混合物，其中含有具有一个碳碳双键的第一种不饱和脂肪族醋酸酯化合物和具有两个碳碳双键的第二种不饱和脂肪族醋酸酯化合物，其质量比为 0.5:99.5 至 99.5:0.5。5，每种化合物具有相同的碳原子总数；以及 一个容器，其中装有混合物，作为容器的一部分或整体，包括一层线性脂肪族聚酯膜，该膜含有选自以下重复单元 (I) 的一个或多个；其中制剂针对至少一种昆虫害虫，其性信息素物质含有第一和第二种化合物，或针对至少一种昆虫害虫，其性信息素物质含有其中一种，而至少一种昆虫害虫性信息素物质含有另一种或两种化合物。
• Use of spray adjuvant to enhance the movement of pesticides through plant canopies to the target
  申请人：Penner Donald

  公开号：US20060088563A1

  公开（公告）日：2006-04-27

  Pesticide compositions and methods of using the compositions for killing, inhibiting or repelling pests are disclosed. The pesticide compositions are admixtures of at least one pesticide and a repellent adjuvant. The retention of the pesticide compositions on the foliage of plants is reduced, so that the composition facilitates the penetration of the foliage onto the underlying target site. Preferably the composition is applied as a spray to provide spherically shaped particles which bounce off the foliage. The pesticide composition can be used to penetrate natural foliage such as tree canopies and underbrush, or to penetrate through cultivated foliage such as turfgrass and crops.

  本发明公开了杀虫剂组合物和使用组合物杀灭、抑制或驱除害虫的方法。杀虫剂组合物是至少一种杀虫剂和一种驱虫佐剂的混合物。农药组合物在植物叶片上的滞留减少，因此组合物有利于从叶片渗透到下层目标部位。组合物最好以喷雾形式施用，以提供从叶片上反弹的球形颗粒。杀虫组合物可用于穿透天然叶片，如树冠和灌木丛，或穿透栽培叶片，如草皮和农作物。