,'-二(4-联苯基)-,'-二苯基联苯胺 | 134008-76-7

• 物质功能分类: 化学试剂 - 有机试剂 - 多环化合物
• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: ,'-二(4-联苯基)-,'-二苯基联苯胺
• 中文别名: '-二(4-联苯基)-,'-二苯基联苯胺；N,N'-二(4-联苯基)-N,N'-二苯基联苯胺；TPD10
• 英文名称: N,N’-bis(biphenyl-4-yl)-N,N’-diphenylbenzidine
• 英文别名: 4,4'-bis[1,1'-biphenyl-4-yl(phenyl)amino]-1,1'-biphenyl；N,N'-Diphenyl-N,N'-di-p-biphenylyl-benzidin；N,N'-bis-biphenyl-4-yl-N,N'-diphenyl-benzidine；N,N'-Bis-biphenyl-4-yl-N,N'-diphenyl-benzidin；4,4'-bis{(biphenyl-4-yl)-phenylamino}biphenyl；N.N'-Diphenyl-N.N'-bis-p-diphenylyl-benzidin；Diphenyl-dibiphenyl-benzidin；N,N'-Di(4-biphenylyl)-N,N'-diphenylbenzidine；N,4-diphenyl-N-[4-[4-(N-(4-phenylphenyl)anilino)phenyl]phenyl]aniline
• CAS: 134008-76-7
• 化学式: C₄₈H₃₆N₂
• 分子量: 640.827
• InChiKey: SDVOZSYGHFDAKX-UHFFFAOYSA-N

物化性质

• 熔点：
  211.0 to 215.0 °C

计算性质

• 辛醇/水分配系数(LogP)：
  13.3
• 重原子数：
  50
• 可旋转键数：
  9
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  二苯胺 在 sodium dichromate 、 铜 、 potassium carbonate 、 溶剂黄146 、 硝基苯 作用下， 生成 ,'-二(4-联苯基)-,'-二苯基联苯胺
  参考文献：
  名称：

  Piccard; de Montmollin, Helvetica Chimica Acta, 1923, vol. 6, p. 1017,1019

  摘要：

  DOI：

文献信息

• Metal-Free Oxidative C–C Coupling of Arylamines Using a Quinone-Based Organic Oxidant
  作者：Sudhakar Maddala、Sudesh Mallick、Parthasarathy Venkatakrishnan

  DOI：10.1021/acs.joc.7b01377

  日期：2017.9.1

  A variety of arylamines are shown to undergo oxidative C–C bond formation using quinone-based chloranil/H+ reagent as the recyclable organic (metal-free) oxidant system to afford benzidines/naphthidines. Arylamines (3°/2°) designed with various substituents were employed to understand the steric as well as electronic preferences of oxidative dimerization, and a mechanism involving amine radical cation

  使用基于醌的氯腈/ H +试剂作为可循环使用的有机（无金属）氧化剂体系，可以显示出多种芳基胺进行氧化C-C键形成，以提供联苯胺/萘啶。设计了具有各种取代基的芳胺（3°/ 2°）用于理解氧化二聚作用的空间和电子偏好，并提出了涉及胺自由基阳离子的机理。通过氧化CC偶联获得的四苯基联苯胺衍生物已通过简单的化学转化进一步转化为发射蓝色光的空穴传输材料。这项研究强调了以简单，经济和有效的方式准备新型HTM。
• DELAYED FLUORESCENCE COMPOUND FOR ORGANIC EL DEVICE AND USING THE SAME
  申请人：YEN FENG-WEN

  公开号：US20180159049A1

  公开（公告）日：2018-06-07

  The present invention discloses a delayed fluorescence compound and the organic EL device employing the delayed fluorescence compound as light emitting host of emitting lay and/or an electron transporting layer, and/or a hole blocking layer, and/or a delayed fluorescence material of emitting layer for organic EL device in the present invention display good performance.

  本发明公开了一种延迟荧光化合物以及采用该延迟荧光化合物作为发光主体的有机EL器件，所述器件发射层和/或电子传输层和/或阻挡孔层和/或延迟荧光材料的发射层在本发明中显示出良好的性能。
• METHOD OF PRODUCING AROMATIC AMINO COMPOUNDS
  申请人：Yokoyama Norimasa

  公开号：US20110257404A1

  公开（公告）日：2011-10-20

  [Problem] To provide a method of producing an aromatic amino compound by using a primary or secondary amine compound and a halogenated aromatic compound as starting materials, and relying upon the Ullmann reaction, the method being capable of obtaining the highly pure aromatic amino compound in high yields and inexpensively. [Means for Solution] A method of producing an aromatic amino compound by using a primary or secondary amine compound having an aromatic ring group and a halogenated aromatic compound as starting materials, reacting the amine compound with the halogenated aromatic compound in the presence of a copper catalyst and a base so as to produce the aromatic amino compound having a structure in which an aromatic ring group derived from the halogenated aromatic compound is coupled to the amino group of the amine compound, wherein the amine compound and the halogenated aromatic compound are reacted together under a condition where an aromatic oxycarboxylic acid having a hydroxyl group and a hydroxycarbonyl group that are bonded to neighboring carbon atoms, is made present together with the copper catalyst and the base.

  提供一种通过使用一种主要或次要胺化合物和一种卤代芳香化合物作为起始原料，依靠乌尔曼反应来生产芳香氨基化合物的方法，该方法能够以高产率和低成本获得高纯度的芳香氨基化合物。 通过使用具有芳香环基团的主要或次要胺化合物和一种卤代芳香化合物作为起始原料，在铜催化剂和碱的存在下将胺化合物与卤代芳香化合物反应，从而产生具有芳香环基团从卤代芳香化合物衍生的结构的芳香氨基化合物，其中胺化合物和卤代芳香化合物在存在具有羟基和羟基羰基团结合到相邻碳原子的芳香氧羧酸的条件下与铜催化剂和碱一起反应。
• Compound, organic electric element using the same, and an electronic device thereof
  申请人：DUK SAN NEOLUX CO., LTD.

  公开号：US10026905B2

  公开（公告）日：2018-07-17

  A compound represented by Formula 1. An organic electric element includes a first electrode, a second electrode, and an organic material layer including the compound of Formula 1. The organic material layer include a light emitting layer, a hole transport layer including a compound represented by Formula 2, and an emission-auxiliary layer including the compound represented by Formula 1. When the organic electric element includes the compound in the organic material layer, luminous efficiency, color purity, and life span can be improved.

  由公式1表示的化合物。一种有机电元件包括第一电极、第二电极和包括公式1所表示的化合物的有机材料层。有机材料层包括发光层、包括公式2所表示的化合物的空穴传输层，以及包括公式1所表示的化合物的发射辅助层。当有机电元件包括有机材料层中的该化合物时，可以改善发光效率、色彩纯度和寿命。
• Stilbene derivative, light emitting element material, light emitting element, light emitting device and electronic appliance
  申请人：Egawa Masakazu

  公开号：US20070100180A1

  公开（公告）日：2007-05-03

  An object of the present invention to provide a novel stilbene derivative having a large energy gap. In addition, it is another object of the present invention to provide a novel light emitting element material having a large energy gap which is suitable for a host material in a light emitting layer. Further in addition, it is another object of the present invention to provide a novel light emitting element material having a large energy gap and an electron transporting property. The present invention provides a stilbene derivative represented by a following general formula (3) and a light emitting element material including the stilbene derivative represented thereby: wherein, n is an integer of 0 or more and 2 or less and m is an integer of 1 or more and 2 or less.

  本发明的一个目的是提供一种具有较大能隙的新型蒽醌衍生物。此外，本发明的另一个目的是提供一种适用于光发射层中宿主材料的具有较大能隙的新型发光元件材料。此外，本发明的另一个目的是提供一种具有较大能隙和电子传输性能的新型发光元件材料。本发明提供了一个由下述一般公式（3）表示的蒽醌衍生物和包括所述蒽醌衍生物的发光元件材料：其中，n是0或更多且2或更少的整数，m是1或更多且2或更少的整数。