异硬脂基缩水甘油醚 | 59068-00-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 中文名称: 异硬脂基缩水甘油醚
• 英文名称: isostearyl glycidyl ether
• 英文别名: 2-(16-methylheptadecoxymethyl)oxirane
• CAS: 59068-00-7
• 化学式: C₂₁H₄₂O₂
• 分子量: 326.563
• InChiKey: BFMNHBIWNXFWJI-UHFFFAOYSA-N

物化性质

• 沸点：
  409.5±18.0 °C(Predicted)
• 密度：
  0.884±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  23
• 可旋转键数：
  18
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  21.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  异硬脂基缩水甘油醚 在 sodium acetate 作用下， 生成 pentaerythritol monoisostearyl glyceryl ether monoacetate
  参考文献：
  名称：

  Fatty acid ester of etherified polyhydric alcohol

  摘要：

  本发明涉及以下一般式（1）所表示的醚化多羟醇的脂肪酸酯、其生产方法、包含该化合物的化妆品组合物以及通过酯化制备醚化多羟醇的生产方法。G(A).sub.x (B).sub.y (1)（其中，G：由至少具有三个羟基的多羟醇的所有羟基的氢原子去除而形成的残基，A：--CH.sub.2 CH(OH)R或--CHRCH.sub.2 OH，R.sup.1：R.sup.1a或--CH.sub.2 OR.sup.1a（R.sup.1a：C.sub.1 -C.sub.36烷基或烯基），B：H或C.sub.1 -C.sub.11酰基，x+y：G的羟基数，x≥1，y≥1，并且至少有一个y个B基团：烷酰基）。该化合物（1）不仅可作为制备醚化多羟醇的中间体，而且在化妆品基料、乳化剂、润滑剂、油性成分等方面本身也具有优异性能。

  公开号：

  US05932755A1
• 作为产物：
  描述：

  sodium hydroxide 、 异硬脂醇 、 、 环氧氯丙烷 在 十八烷基三甲基氯化铵 水 作用下， 以 正己烷 为溶剂， 反应 9.5h， 生成 异硬脂基缩水甘油醚
  参考文献：
  名称：

  Process for the production of glyceryl ethers

  摘要：

  该规范描述了一种生产4-烷氧甲基-1,3-二氧兰的方法，该方法通过在酸催化剂存在下将烷基环氧乙烷与羰基化合物反应，以高产率、高纯度和简单的方式生产。4-烷氧甲基-1,3-二氧兰可用作通过水解生产α-单烷基甘油醚的中间体。

  公开号：

  US04465869A1

文献信息

• Skin pore minimizers and skin elasticity improvers
  申请人：——

  公开号：US20040009140A1

  公开（公告）日：2004-01-15

  This invention relates to skin pore tighteners each of which comprises, as an active ingredient, a compound represented by the following formula: R 1 -OG   (1) wherein R 1 represents an alkyl or alkenyl group having 8 to 32 carbon atoms, and OG represents a residual group obtained by removing a hydrogen atom from a hydroxyl group of a polyhydric alcohol, monosaccharide or oligosaccharide at least one hydroxyl group of which has been sulfated or phosphatized, or a salt thereof, and also to skin elasticity improvers each of which comprises, as an active ingredient, a glyceryl ether derivative represented by the following formula: 1 wherein R 1 represents the same group as defined above, and X 1 and X 2 each independently represents a hydrogen atom, —SO 3 OH or —PO(OH) 2 with the proviso that X 1 and X 2 are not hydrogen atoms at the same time, or a salt thereof. The skin pore tighteners according to the present invention have excellent effect in tightening skin pores and rendering them less conspicuous, while the skin elasticity improvers and skin tighteners according to the present invention have superb effect in preventing and lessening skin wrinkles and sagging. Accordingly, they are useful as ordinary cosmetic preparations, as cosmetic preparations after depilating treatment, and also as cosmetic preparations after removal of keratotic plugs.

  本发明涉及皮肤毛孔收敛剂，每种皮肤毛孔收敛剂包括以下式表示的化合物作为活性成分：R1-OG (1)，其中R1代表具有8至32个碳原子的烷基或烯基基团，OG代表通过从多羟醇、单糖或寡糖的羟基中去除氢原子而获得的残基，其中至少一个羟基已磺酸化或磷酸化，或其盐，以及皮肤弹性改善剂，每种皮肤弹性改善剂包括以下式表示的甘油醚衍生物作为活性成分：1，其中R1代表如上定义的相同基团，X1和X2分别独立表示氢原子，-SO3OH或-PO(OH)2，条件是X1和X2不能同时为氢原子，或其盐。根据本发明的皮肤毛孔收敛剂在收紧皮肤毛孔和使其变得不那么明显方面具有出色的效果，而根据本发明的皮肤弹性改善剂和紧致剂在预防和减轻皮肤皱纹和下垂方面具有出色的效果。因此，它们可用作普通化妆品制剂，脱毛后的化妆品制剂，以及去除角化栓后的化妆品制剂。
• POLYGLYCERIN DIALKYL OR ALKENYL ETHER, AND COSMETIC COMPOSITION CONTAINING SAME
  申请人：Daicel Corporation

  公开号：EP2813483A1

  公开（公告）日：2014-12-17

  Provided are: a novel polyglycerol di-(alkyl/alkenyl) ether that is useful as a highly hydrophilic gemini surfactant; and a cosmetic composition containing the polyglycerol di-(alkyl/alkenyl) ether. The polyglycerol di-(alkyl/alkenyl) ether is represented by Formula (1), where R1 and R2 are identical or different and are independently a straight- or branched-chain alkyl group or a straight- or branched-chain alkenyl group, where the alkyl group may have one or more hydroxyl groups; and n indicates a number of glycerol units and is an integer of 2 or more. Formula (1) is expressed as follows:

  提供了一种新型聚甘油二-(烷基/烯基)醚，可用作高度亲水的双子表面活性剂；以及含有该聚甘油二-(烷基/烯基)醚的化妆品组合物。聚甘油二-(烷基/烯基)醚由化学式(1)表示，其中R1和R2相同或不同，独立地表示直链或支链烷基或直链或支链烯基，其中烷基可能具有一个或多个羟基；n表示甘油单元的数量，是大于等于2的整数。化学式(1)表达如下：
• EMULSIFIER FOR EMULSION POLYMERIZATION AND EMULSION POLYMERIZATION METHOD USING SAME
  申请人：Dai-Ichi Kogyo Seiyaku Co., Ltd.

  公开号：US20150038654A1

  公开（公告）日：2015-02-05

  An emulsifier for emulsion polymerization includes a compound represented by the following general: X=H, —(CH 2 ) a —SO 3 M, —(CH 2 ) b —COOM, —PO 3 M 2 , —P(B)O 2 M, or —CO—CH 2 —CH(SO 3 M)-COOM Y= Z=

  乳液聚合的乳化剂包括以下一般代表的化合物：X=H，—（CH2）a—SO3M，—（CH2）b—COOM，—PO3M2，—P（B）O2M或—CO—CH2—CH（SO3M）-COOM；Y=Z=。
• Alpha-mono(methyl-branched alkyl) glyceryl ether and a skin care cosmetic composition containing the same
  申请人：Kao Corporation

  公开号：EP0025302A1

  公开（公告）日：1981-03-18

  α-mono(methyl-branched alkyl) glyceryl ethers represented by the formula where m is an integer of 2 to 14, n is an integer of 3 to 11, and the total of m + n is 1 1 to 17, are disclosed along with skin care compositions containing the same as emulsifiers.

  α-单(甲基支链烷基)甘油醚由式 其中 m 为 2 至 14 的整数，n 为 3 至 11 的整数，m+n 的总和为 1 1 至 17。
• 2,3-Dialkoxypropyl glyceryl ether and its preparation process as well as cosmetic composition containing same
  申请人：KAO SOAP COMPANY, LTD.

  公开号：EP0071019A1

  公开（公告）日：1983-02-09

  Disclosed herein is a novel 2,3-dialkoxypropyl glyceryl ether and the preparation process for it. The above diglycerin dialkyl ether is readily prepared with high yield and purity by reacting its corresponding glycidyl ether with a protected glycerin to form a 1,3-dioxolan compound, followed by etherifying the thus formed 1,3-dioxolan compound into a dialkyl ether dioxolan compound, and then hydrolyzing the resultant dialkyl ether dioxolan compound. This diglycerin dialkyl ether is useful as an emulsifier, cleaner etc., and is preferably used as a component of cosmetic compositions. A cosmetic composition comprising the above 2,3- dialkoxypropyl glyceryl ether is also disclosed.

  本文公开了一种新型 2,3-二烷氧基丙基甘油醚及其制备工艺。上述二甘油二烷基醚很容易制备，产量和纯度都很高，制备方法是将相应的缩水甘油醚与受保护的甘油反应生成 1，3-二氧戊环化合物，然后将生成的 1，3-二氧戊环化合物醚化成二烷基醚二氧戊环化合物，再将生成的二烷基醚二氧戊环化合物水解。这种二甘油二烷基醚可用作乳化剂、清洁剂等，最好用作化妆品组合物的成分。此外，还公开了一种包含上述 2,3-二烷氧基丙基甘油醚的化妆品组合物。