1,2,3,4,5,6,7,8,9,10-十氟芘 | 1493-68-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 中文名称: 1,2,3,4,5,6,7,8,9,10-十氟芘
• 英文名称: Decafluorpyren
• 英文别名: Perfluorpyren；Pyrene, decafluoro-；1,2,3,4,5,6,7,8,9,10-decafluoropyrene
• CAS: 1493-68-1
• 化学式: C₁₆F₁₀
• 分子量: 382.16
• InChiKey: ZRQXDCFMDRAOSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  1,2,3,4,5,6,7,8,9,10-十氟芘 在 硝酸 作用下， 生成 1,2,3,6,7,8-Hexafluorpyren-4,5,9,10-chinon
  参考文献：
  名称：

  Yakobson,G.G. et al., Doklady Chemistry, 1966, vol. 169, p. 762 - 764

  摘要：

  DOI：
• 作为产物：
  描述：

  十氯芘 在 potassium fluoride 作用下， 生成 1,2,3,4,5,6,7,8,9,10-十氟芘
  参考文献：
  名称：

  Yakobson,G.G. et al., Doklady Chemistry, 1966, vol. 169, p. 762 - 764

  摘要：

  DOI：

文献信息

• Polycyclic fluoroaromatic compounds—III
  作者：D. Harrison、M. Stacey、R. Stephens、J.C. Tatlow

  DOI：10.1016/0040-4020(63)85004-8

  日期：1963.1

  -pyrene have been prepared, by fluorination of the aromatic hydrocarbons with cobaltic fluoride. When defluorinated in the vapour phase over heated metal gauze perfluoro-indane, -acenaphthylene, -acenaphthene, -anthracene and -pyrene were obtained.

  通过用氟化钴对芳族烃进行氟化，已经制备了全氟过氢茚满，-芴，-,、-菲，-蒽和-ne。当在加热的金属丝网上在气相中脱氟时，得到全氟茚满，-ac烯，-ac烯，-蒽和-py。
• fluorinations with potassium tetrafluorocobaltate(III)—V
  作者：J. Burdon、J.R. Knights、I.W. Parsons、J.C. Tatlow

  DOI：10.1016/s0040-4020(01)97532-5

  日期：1974.1

  Anthracene, phenanthrene, decafluorophenanthrene, pyrene, biphenyl and decafluorobiphenyl have been fluorinated over potassium tetrafluorocobaltate(III) and some of them over caesium tetrafluorocobaltate(III). All the product mixtures except those from pyrene and decafluorobiphenyl consisted mainly of perfluoro-olefins and -aromatics; the pyrene product was largely a perfluoroper-hydropyrene, and that

  蒽，菲，十氟菲、,、联苯和十氟联苯已在四氟钴酸钾（III）上进行了氟化，其中一些在四氟钴酸铯（III）上进行了氟化。除pyr和十氟联苯以外的所有产物混合物主要由全氟烯烃和-芳族化合物组成。product产物主要是全氟过氢py，十氟联苯的主要是全氟双环己基。仅在联苯的情况下，才分离出任何含氢产物。尝试对这些观察结果进行机械解释。相关粗氟化混合物的脱氟为全氟to和-菲的合成提供了一条很好的途径。如果是蒽的氟化产物，则脱氟在中间阶段大都停止了，
• Fluorinated pentacene derivative and method of producing same
  申请人：Kobayashi Masafumi

  公开号：US20070083067A1

  公开（公告）日：2007-04-12

  Fluorinated pentacene derivatives, for example, the novel compounds tetradecafluoropentacene, 5,6,7,12,13,14-hexafluoropentacene, 5,7,12,14-tetrafluoropentacene, and 6,13-difluoropentacene, and intermediates therefor are provided. And a method of producing fluorinated pentacene derivatives and intermediates therefor is also provided. Pentacene derivatives fluorinated at desired positions of the pentacene skeleton are obtained by introducing the oxo group, hydroxyl group, or alkoxyl group into the pentacene skeleton followed by fluorination with sulfur tetrafluoride and partial defluorination using a reducing agent.

  提供了氟代五环芴衍生物，例如新型化合物四氟代五环芴、5,6,7,12,13,14-六氟代五环芴、5,7,12,14-四氟代五环芴和6,13-二氟代五环芴及其中间体。同时还提供了一种制备氟代五环芴衍生物和中间体的方法。通过在五环芴骨架中引入羟基、氧代基或烷氧基，然后使用四氟化硫进行氟化并使用还原剂进行部分脱氟，从而获得在所需位置氟代的五环芴衍生物。
• Fluorine-containing resin composition
  申请人：Asahi Glass Company Ltd.

  公开号：EP0905179A1

  公开（公告）日：1999-03-31

  A fluorine-containing resin composition comprising at least one fluorine-containing polycyclic compound (A) selected from the group consisting of the following compounds (A1), (A2) and (A3), and a polymer (B) having a fluorine-containing alicyclic structure: (A1) a fluorine-containing non-condensed polycyclic compound having at least two fluorine-containing rings bonded by a bond containing at least one member selected from the group consisting of a triazine ring, an oxygen atom, a sulfur atom, a phosphorus atom and a metal atom, each of said fluorine-containing rings being a carbon ring or a heterocyclic ring, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group; (A2) a fluorine-containing non-condensed polycyclic compound having at least three fluorine-containing rings bonded directly or by a bond containing a carbon atom, each of said fluorine-containing rings being a carbon ring or a heterocyclic ring, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group; (A3) a fluorine-containing condensed polycyclic compound which is a condensed polycyclic compound composed of at least three carbon rings or heterocyclic rings, of which some or all of hydrogen atoms are substituted by a fluorine atom or a fluorine-containing group.

  一种含氟树脂组合物，包含至少一种从以下化合物（A1）、（A2）和（A3）组成的组中选出的含氟多环化合物（A），以及一种具有含氟脂环结构的聚合物（B）： (A1) 具有至少两个含氟环的含氟非缩合多环化合物，这两个含氟环通过含有至少一个选 自三嗪环、氧原子、硫原子、磷原子和金属原子组成的组的键结合，每个所述含氟环是 碳环或杂环，其中部分或全部氢原子被氟原子或含氟基团取代； (A2) 含氟非缩合多环化合物，至少有三个含氟环直接或通过含有碳原子的键结合在一起，每个含氟环是碳环或杂环，其中部分或全部氢原子被氟原子或含氟基团取代； (A3) 含氟缩合多环化合物，它是由至少三个碳环或杂环组成的缩合多环 化合物，其中部分或全部氢原子被氟原子或含氟基团取代。
• THERMOPLASTIC ACRYLIC RESIN AND METHOD FOR PRODUCING SAME, AND RESIN COMPOSITION
  申请人：Kaneka Corporation

  公开号：EP3778679A1

  公开（公告）日：2021-02-17

  One or more embodiments of the present invention relate to a thermoplastic acrylic resin that is a graft copolymer in which a stem polymer is an acrylic resin containing acrylonitrile and another ethylenically unsaturated monomer, and a branch polymer is a polymer composed of an ethylenically unsaturated monomer, wherein acrylonitrile is contained in an amount of 35 mass% or more and 84.5 mass% or less, the other ethylenically unsaturated monomer is contained in an amount of 15 mass% or more and 64.5 mass% or less, and the polymer composed of an ethylenically unsaturated monomer is contained in an amount of 0.5 mass% or more and 40 mass% or less. Thus, provided are a thermoplastic acrylic resin having improved melt-processability without compromising heat resistance, a method for producing the thermoplastic acrylic resin, a thermoplastic acrylic resin composition, a molded body, an acrylic fiber, and a method for producing the acrylic fiber.

  本发明的一个或多个实施例涉及一种热塑性丙烯酸树脂，它是一种接枝共聚物，其中干聚合物是含有丙烯腈和另一种乙烯基不饱和单体的丙烯酸树脂，支聚合物是由乙烯基不饱和单体组成的聚合物，其中丙烯腈的含量为 35 质量％或以上，84.5 质量％或更少，另一种乙烯基不饱和单体的含量为 15 质量％或更多和 64.5 质量％或更少，由乙烯基不饱和单体组成的聚合物的含量为 0.5 质量％或更多和 40 质量％或更少。因此，本发明提供了一种在不影响耐热性的前提下提高熔融加工性的热塑性丙烯酸树脂、一种生产该热塑性丙烯酸树脂的方法、一种热塑性丙烯酸树脂组合物、一种模塑体、一种丙烯酸纤维以及一种生产该丙烯酸纤维的方法。