1,2,3,4,5-五溴-6-碘苯 | 57137-98-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,2,3,4,5-五溴-6-碘苯
• 英文名称: Pentabrom-iodbenzol
• 英文别名: pentabromoiodobenzene；Pentabrom-jod-benzol；1,2,3,4,5-Pentabromo-6-iodobenzene
• CAS: 57137-98-1
• 化学式: C₆Br₅I
• 分子量: 598.49
• InChiKey: UVPBFFIODIHJKD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2,3,4,5-五溴-6-碘苯 在 sodium methylate 作用下， 以 甲醇 、 二甲基亚砜 为溶剂， 生成 1,2,3,4,5-五溴苯
  参考文献：
  名称：

  Bolton, Roger; Moore, Clive; Sandall, John P.B., Journal of the Chemical Society. Perkin transactions II, 1982, p. 1593 - 1598

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2,3,4,5-五溴苯 在 potassium iodate 、 硫酸 、 碘 作用下， 反应 168.0h， 以98%的产率得到1,2,3,4,5-五溴-6-碘苯
  参考文献：
  名称：

  Cross coupling of polybromoiodobenzenes with some terminal alkynes

  摘要：

  Sonogashira reactions of pentabromoiodobenzene and tetrabromo-1,4-diiodobenzene with various terminal alkynes at 20C in benzene resulted in selective replacement of the iodine atoms with formation of the corresponding alk-1-yn-1-yl-substituted polybromobenzenes.

  DOI：

  10.1134/s1070428008090121

文献信息

• Brominated flame-retardant tetrazines
  申请人：International Business Machines Corporation

  公开号：US11198818B2

  公开（公告）日：2021-12-14

  A flame-retardant compound, a process for forming a flame-retardant compound, and an article of manufacture. The flame-retardant compound includes a tetrazine moiety and at least one ligand comprising a brominated moiety. The process includes providing starting materials, which include a nitrile compound, a bromine source, and hydrazine. The process also includes reacting the starting materials to form a tetrazine flame retardant. The article of manufacture includes a polymer and a flame-retardant compound having a tetrazine moiety and at least one ligand comprising a brominated moiety.

  一种阻燃化合物、制造阻燃化合物的工艺以及制造物。所述阻燃化合物包括四嗪基团和至少一个包含溴化基团的配体。所述工艺包括提供起始材料，所述起始材料包括腈类化合物、溴源和水合肼。所述工艺还包括使所述起始材料反应以形成四嗪类阻燃剂。所述制造物包括聚合物和一种阻燃化合物，所述阻燃化合物具有四嗪基团和至少一个包含溴化基团的配体。
• The Polybromination of Alkylbenzenes¹
  作者：G. F. Hennion、James G. Anderson

  DOI：10.1021/ja01207a023

  日期：1946.3
• Deacon,G.B. et al., Australian Journal of Chemistry, 1977, vol. 30, p. 1013 - 1023
  作者：Deacon,G.B. et al.

  DOI：——

  日期：——
• BROMINATED FLAME-RETARDANT TETRAZINES
  申请人：International Business Machines Corporation

  公开号：US20200399540A1

  公开（公告）日：2020-12-24

  A flame-retardant compound, a process for forming a flame-retardant compound, and an article of manufacture. The flame-retardant compound includes a tetrazine moiety and at least one ligand comprising a brominated moiety. The process includes providing starting materials, which include a nitrile compound, a bromine source, and hydrazine. The process also includes reacting the starting materials to form a tetrazine flame retardant. The article of manufacture includes a polymer and a flame-retardant compound having a tetrazine moiety and at least one ligand comprising a brominated moiety.