1,2,3-三氯-4,5,6-三甲基苯 | 19219-81-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 1,2,3-三氯-4,5,6-三甲基苯
• 英文名称: 1,2,3-Trichlor-4,5,6-trimethyl-benzol
• 英文别名: 1,2,3-Trichloro-4,5,6-trimethylbenzene
• CAS: 19219-81-9
• 化学式: C₉H₉Cl₃
• 分子量: 223.529
• InChiKey: QCTIBRJBUAXXEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2903999090

反应信息

• 作为反应物：
  描述：

  1,2,3-三氯-4,5,6-三甲基苯 在 硝酸 作用下， 生成 2,6-Dichlor-4-hydroxy-3,4,5-trimethyl-cyclohexa-2,5-dienon
  参考文献：
  名称：

  Products Obtained by the Reaction of Trichlorotrimethylbenzenes with Fuming Nitric Acid. Side-chain NitrooxylationversusOxidation to Unsaturated Cyclic Ketones

  摘要：

  研究了三氯三甲基苯与发烟硝酸的反应。三氯伪二苯经过侧链硝氧基化和核氧化反应，生成了 2,5,6- 三氯-3,4-二甲基苄基硝酸盐、3,5,6-三氯-2,4-二甲基苄基硝酸盐和 3,6- 二氯-4-硝基-2,4,5-三甲基环己-2,5-二烯酮。三氯甲基产生了几种羰基化合物的混合物，其中有 3,5-二氯-4-羟基-2,4,6-三甲基环己-2,5-二烯酮和两个硝基酮，暂定为 2,4,6-三氯-5-羟基-2,4,6-三甲基环己-2,5-二烯酮、通过色谱法和分馏萃取法获得了结晶产品--6-三氯-5-羟基-6-硝基-2,3,5-三甲基环己-3-烯酮和 3,5-二氯-2-羟基-6,6-二硝基-2,4,5-三甲基环己-3-烯酮。三氯亚甲基对硝化剂的作用类似，主要产物为 2,6-二氯-4-羟基-3,4,5-三甲基环己-2,5-二烯酮。侧链硝酰氧基化和环酮形成的竞争模式已被描述。

  DOI：

  10.1246/bcsj.47.876
• 作为产物：
  描述：

  1,5-dichloro-2,3,4-trimethyl-benzene 在 氯仿 、 氯 、 铁粉 作用下， 生成 1,2,3-三氯-4,5,6-三甲基苯
  参考文献：
  名称：

  Crossley; Hills, Journal of the Chemical Society, 1906, vol. 89, p. 880

  摘要：

  DOI：

文献信息

• COMPOSITIONS CONTAINING A POLYAMINE, A NONIONIC SURFACTANT, AND AN ANIONIC SILICONE FOR LIFTING COLOR AND/OR IMPARTING SHINE ONTO KERATINOUS SUBSTRATES
  申请人：TAN Siliu

  公开号：US20120325249A1

  公开（公告）日：2012-12-27

  The present invention is drawn to a composition and method for lifting color and/or imparting shine onto keratinous substrates, the composition containing: (a) at least one polyamine compound; (b) at least one nonionic surfactant; (c) at least one anionic silicone; and (d) at least one oxidizing agent. The compositions of the present invention may optionally contain at least one thickening agent, at least one alkaline agent, at least one fatty substance other than a fatty acid, and at least one salt.

  本发明涉及一种用于提升角蛋白基质的颜色和/或赋予光泽的组合物和方法，该组合物包含：(a)至少一种多胺化合物；(b)至少一种非离子表面活性剂；(c)至少一种阴离子硅油；以及(d)至少一种氧化剂。本发明的组合物可以选择性地包含至少一种增稠剂、至少一种碱性剂、至少一种脂肪物质而不是脂肪酸以及至少一种盐。
• COMPOSITIONS CONTAINING A FATTY MONOAMINE, A NONIONIC SURFACTANT, AND AN ANIONIC SILICONE FOR LIFTING COLOR AND/OR IMPARTING SHINE ONTO KERATINOUS SUBSTRATES
  申请人：TAN Siliu

  公开号：US20120325252A1

  公开（公告）日：2012-12-27

  The present invention is drawn to a composition and method for lifting color and/or imparting shine onto keratinous substrates, the composition containing: (a) at least one fatty monoamine compound; (b) at least one nonionic surfactant; (c) at least one anionic silicone; and (d) at least one oxidizing agent. The compositions of the present invention may optionally contain at least one thickening agent, at least one alkaline agent, at least one fatty substance other than a fatty acid, and at least one salt.

  本发明涉及一种用于提升角蛋白质基质颜色和/或赋予光泽的组合物和方法，该组合物包含：（a）至少一种脂肪单胺化合物；（b）至少一种非离子表面活性剂；（c）至少一种阴离子硅油；以及（d）至少一种氧化剂。本发明的组合物可以选择性地包含至少一种增稠剂，至少一种碱性剂，除脂肪酸以外的至少一种脂肪物质，以及至少一种盐。
• EMULSION DYEING COMPOSITION CONTAINING AT LEAST ONE PHOSPHOLIPID, AT LEAST ONE NONIONIC SURFACTANT AND AT LEAST ONE SILICONE, AND METHOD OF USING SAME
  申请人：Hashimoto Sawa

  公开号：US20120325244A1

  公开（公告）日：2012-12-27

  The present invention is drawn to a composition and method for dyeing keratinous substrates containing: (a) at least one phospholipid; (b) at least one nonionic surfactant; (c) at least anionic silicone; (d) at least one dye chosen from oxidation dye precursors and direct dyes. The compositions of the present invention may optionally contain at least one thickening agent, at least one alkaline agent, at least one fatty substance other than a fatty acid, at least one salt, and at least one oxidizing agent.

  本发明涉及一种含有以下成分的染色角质基质的组合物和方法：（a）至少一种磷脂；（b）至少一种非离子表面活性剂；（c）至少一种阴离子硅油；（d）至少一种氧化染料前体和直接染料中选择的染料。本发明的组合物可以选择性地包含至少一种增稠剂，至少一种碱性剂，除脂肪酸以外的至少一种脂肪物质，至少一种盐和至少一种氧化剂。
• EMULSION DYEING COMPOSITION CONTAINING AT LEAST ONE FATTY QUATERNARY AMINE, AT LEAST ONE NONIONIC SURFACTANT AND AT LEAST ONE SILICONE, AND METHOD OF USING SAME
  申请人：HASHIMOTO Sawa

  公开号：US20120325246A1

  公开（公告）日：2012-12-27

  The present invention is drawn to a composition and method for coloring keratinous substrates containing: (a) at least one fatty quaternary amine; (b) at least one nonionic surfactant; (c) at least anionic silicone; (d) at least one dye chosen from oxidation dye precursors and direct dyes; (e) optionally, at least one thickening agent; (f) optionally, at least one alkaline agent; (g) optionally, at least one fatty substance other than a fatty acid; (h) optionally, at least one salt; and (i) optionally, at least one oxidizing agent.

  本发明涉及一种用于着色角质蛋白基质的组合物和方法，其包含：(a)至少一种脂肪基季铵盐；(b)至少一种非离子表面活性剂；(c)至少一种阴离子硅油；(d)至少一种从氧化染料前体和直接染料中选择的染料；(e)可选地，至少一种增稠剂；(f)可选地，至少一种碱性剂；(g)可选地，至少一种除脂肪酸外的脂肪物质；(h)可选地，至少一种盐；和(i)可选地，至少一种氧化剂。
• COMPOSITIONS CONTAINING A PHOSPHOLIPID, A NONIONIC SURFACTANT, AND AN ANIONIC SILICONE FOR LIFTING COLOR AND/OR IMPARTING SHINE ONTO KERATINOUS SUBSTRATES
  申请人：TAN Siliu

  公开号：US20120325253A1

  公开（公告）日：2012-12-27

  The present invention is drawn to a composition and method for lifting color and/or imparting shine onto keratinous substrates, the composition containing: (a) at least one phospholipid; (b) at least one nonionic surfactant; (c) at least one anionic silicone; and (d) at least one oxidizing agent. The compositions of the present invention may optionally contain at least one thickening agent, at least one alkaline agent, at least one fatty substance other than a fatty acid, and at least one salt.

  本发明涉及一种用于提升角蛋白质基质上的颜色和/或赋予光泽的组合物和方法，该组合物包含：(a) 至少一种磷脂；(b) 至少一种非离子表面活性剂；(c) 至少一种阴离子硅油；和(d) 至少一种氧化剂。本发明的组合物可以选择性地含有至少一种增稠剂、至少一种碱性剂、至少一种脂肪物质，除了脂肪酸，以及至少一种盐。