1,2,3-丙三基三[氧代(1-甲基-2,1-乙二基)]三丙烯酰酸酯 | 94160-26-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1,2,3-丙三基三[氧代(1-甲基-2,1-乙二基)]三丙烯酰酸酯
• 英文名称: glyceroltriacrylate propoxylated
• 英文别名: propoxylated (3) glyceryl triacrylate；1,1a(2),1a(2)a(2)-[1,2,3-Propanetriyltris[oxy(1-methyl-2,1-ethanediyl)]] tri-2-propenoate；1-[2,3-bis(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate
• CAS: 94160-26-6
• 化学式: C₂₁H₃₂O₉
• 分子量: 428.48
• InChiKey: UTPIIYCVYBQOBI-UHFFFAOYSA-N

物化性质

• 保留指数：
  2412

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  30
• 可旋转键数：
  20
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  107
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  1,2,3-丙三基三[氧代(1-甲基-2,1-乙二基)]三丙烯酰酸酯 、 4-[3-(methylamino)propoxy]benzophenone 在 2,6-二叔丁基-4-甲基苯酚 作用下， 以 乙酸乙酯 为溶剂， 反应 48.0h， 生成 1-[2,3-Bis[2-[3-[3-(4-benzoylphenoxy)propyl-methylamino]propanoyloxy]propoxy]propoxy]propan-2-yl 3-[3-(4-benzoylphenoxy)propyl-methylamino]propanoate
  参考文献：
  名称：

  Multifunctional Type II photoinitiators and curable compositions

  摘要：

  根据公式(I)，一种多功能的二类光引发剂，其中X代表根据公式(II)的结构基团，其中：A代表Norrish Type II引发基团；L代表二价连接基团，定位Norrish Type II引发基团A和CR2R3基团在1-5到1-9位置，其中位置1被定义为A的芳香环或脂环中与L共价结合的第一个原子，位置5到9被定义为CR2R3基团的碳原子，L与之共价结合，但L不含胺基。还公开了包括这种多功能二类光引发剂的辐射固化组合物和油墨。

  公开号：

  EP2130818A1

文献信息

• MULTIFUNCTIONAL TYPE II PHOTOINITIATORS AND CURABLE COMPOSITIONS
  申请人：Loccufier Johan

  公开号：US20110069130A1

  公开（公告）日：2011-03-24

  A multifunctional Type II photoinitiator according to Formula (I): wherein X represents a structural moiety according to Formula (II): wherein: A represents a Norrish Type II initiating group; and L represents a divalent linking group positioning the Norrish Type II initiating group A and the CR2R3-group in a 1-5 to a 1-9 position wherein position 1 is defined as the first atom in the aromatic or alicyclic ring of A to which L is covalently bonded and the position 5 to 9 is defined as the carbon atom of the CR2R3-group to which L is covalently bonded, with the proviso that L does not contain an amine. Radiation curable compositions and inks include the multifunctional Type II photoinitiator.

  一种多功能的二型光引发剂，其化学式为(I)：其中X代表化学式(II)的结构基团：其中：A代表Norrish二型引发基团；L代表二价连结基团，将Norrish二型引发基团A和CR2R3基团定位于1-5到1-9的位置，其中位置1定义为A芳香环或脂环中与L共价结合的第一个原子，位置5到9定义为CR2R3基团中与L共价结合的碳原子，但L不包含胺基。辐射可固化组合物和油墨包括该多功能二型光引发剂。
• ULTRAVIOLET-CURABLE RESIN MATERIAL FOR PATTERN TRANSFER AND MAGNETIC RECORDING MEDIUM MANUFACTURING METHOD USING THE SAME
  申请人：MORITA Kazuyo

  公开号：US20110049089A1

  公开（公告）日：2011-03-03

  According to one embodiment, an ultraviolet curing curable resin material for pattern transfer is provided. The resin contains isobornyl acrylate, an acrylate having a fluorene skeleton, a polyfunctional acrylate, and a polymerization initiator.

  根据一种实施例，提供了一种用于图案转移的紫外光固化可固化树脂材料。该树脂含有异丙基丙烯酸酯、含有芴骨架的丙烯酸酯、多官能团丙烯酸酯和聚合引发剂。
• SYNERGISTS
  申请人：Davidson Robert Stephen

  公开号：US20130012611A1

  公开（公告）日：2013-01-10

  Compounds of formula (I): wherein Ar represents an, optionally substituted, aryl or heteroaryl group, R represents an, optionally substituted, aryl or heteroaryl group, an optionally substituted straight or branched chain C 1.10 -alkyl, R 1 is H or methyl, X is an extender group, n is 0 or an integer between 1 and 12 inclusive, A is a polyol residue wherein the unsubstituted polyol from which the residue is derived has at least y OH groups, and y is an integer>1, can easily be prepared, and are useful as synergists in radiation curing.

  式(I)的化合物：其中Ar代表一个可选择取代的芳基或杂芳基基团，R代表一个可选择取代的芳基或杂芳基基团，一个可选择取代的直链或支链C1-10烷基，R1为H或甲基，X为延伸基团，n为0或介于1至12之间的整数，A为多元醇残基，其中未取代的多元醇至少具有y个OH基团，y为大于1的整数。这些化合物可以轻松制备，并且在辐射固化中作为协同剂非常有用。
• UV curable inkjet inks for printing on glass
  申请人：AGFA NV

  公开号：US11352513B2

  公开（公告）日：2022-06-07

  A UV curable inkjet ink contains at least one free radical photoinitiator and at least 30 wt % of a mixture including 0 to 45 wt % of a polymerizable oligomer, at least 5 wt % of a polyfunctional propoxylated acrylate and at least 20 wt % of a monofunctional ethoxylated methacrylate according to Formula (I): with n representing an integer of 1 to 4 and R representing an alkyl group; the weight ratio of the polyfunctional propoxylated acrylate over the monofunctional ethoxylated methacrylate is less than 1.60; and all the weight percentages wt % are based on the total weight of the UV curable inkjet ink.

  一种紫外线固化喷墨墨水含有至少一种自由基光引发剂和至少 30 wt % 的混合物，其中包括 0 至 45 wt % 的可聚合低聚物、至少 5 wt % 的多官能团丙氧基化丙烯酸酯和至少 20 wt % 的单官能团乙氧基化甲基丙烯酸酯： 其中 n 代表 1 至 4 的整数，R 代表烷基；多官能团丙氧基化丙烯酸酯与单官能团乙氧基化甲基丙烯酸酯的重量比小于 1.60；所有重量百分比 wt % 均基于 UV 固化喷墨墨水的总重量。
• PHOTOCURABLE COATING COMPOSITION, AND OVERPRINT AND PROCESS FOR PRODUCING SAME
  申请人：KAKINO Ryuki

  公开号：US20090081422A1

  公开（公告）日：2009-03-26

  A photocurable coating composition is provided that includes an ethylenically unsaturated compound having an alicyclic hydrocarbon group and a photopolymerization initiator. There are also provided a process for producing an overprint, the process including a step of obtaining a printed material by printing on a printing substrate, a step of coating the printed material with the photocurable coating composition, and a step of photocuring the photocurable coating composition, an overprint produced by the process, use of the photocurable coating composition for producing an overprint, and use of the photocurable coating composition for producing an overprint for an electrophotographically printed material.