1,3,5-三(7-氮杂吲哚-1-基)苯 | 319430-91-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 中文名称: 1,3,5-三(7-氮杂吲哚-1-基)苯
• 英文名称: 1,3,5-Tris(7-azaindol-1-yl)benzene
• 英文别名: 1,3,5-tris(7'-azaindolyl)benzene；1,3,5-Tris(n-7-azaindolyl)benzene；1-[3,5-bis(pyrrolo[2,3-b]pyridin-1-yl)phenyl]pyrrolo[2,3-b]pyridine
• CAS: 319430-91-6
• 化学式: C₂₇H₁₈N₆
• 分子量: 426.48
• InChiKey: CFRAJQWGJXMEOT-UHFFFAOYSA-N

物化性质

• 沸点：
  696.0±55.0 °C(Predicted)
• 密度：
  1.35±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  33
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  53.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  十羰基二铼 、 1,3,5-三(7-氮杂吲哚-1-基)苯 以 二乙二醇二甲醚 为溶剂， 以93%的产率得到tricarbonyl(2,4,6-tris(7'-azaindolyl)phenyl)rhenium(I)
  参考文献：
  名称：

  重新合成（I）配合物的轴承三齿2,6-双（7 ' -azaindolyl）苯基配体与绿色发射性质

  摘要：

  了Re（I）配合轴承2,6-双（7 ' -azaindolyl）苯基配体为三齿配体是通过用再合成2（CO）10。配合物的结构通过X射线晶体学确认。Re（I）配合物的两个7-氮杂吲哚基配体均以蝴蝶形式存在。Re-C ipso键通过苯基部分和Re原子之间的π反向供电显示出部分双键特征。在室温下的THF溶液，这些配合物显示出绿色发射（λ EM = 510纳米），这被认为是归因于MLCT（DZ 2（Re）的→π *（7 ' -azaindolyl基团））的含过渡π→π *（7 ' -azaindolyl组）过渡。

  DOI：

  10.1016/j.jorganchem.2004.02.023
• 作为产物：
  描述：

  7-氮杂吲哚 、 1,3,5-三溴苯 在 potassium carbonate 、 copper(II) sulfate 作用下， 反应 9.0h， 以54%的产率得到1,3,5-三(7-氮杂吲哚-1-基)苯
  参考文献：
  名称：

  A Blue Luminescent Starburst Molecule and Its Orange Luminescent Trinuclear PdII Complex: 1,3,5-tris(7-azaindol-1-yl)benzene (tabH) and [PdII3(tab)2Cl4]

  摘要：

  DOI：

  10.1002/1521-3773(20001103)39:21<3933::aid-anie3933>3.0.co;2-w

文献信息

• Organoboron luminescent compounds and methods of making and using same
  申请人：Wang Suning

  公开号：US20060036114A1

  公开（公告）日：2006-02-16

  The invention provides three-coordinated organoboron compounds that are useful for photoluminescence and electroluminescence. Compounds of the invention include light emitters, preferably emitting intense blue light, electron transporters, hole transporters and hole injectors. A particularly preferred such compound is p-(1-naphthylphenylamino)-4,4′-biphenyldimesitylborane (BNPB), which demonstrates all of these properties. The invention further provides methods of synthesizing such three-coordinated boron compounds, methods of producing photoluminescence and electroluminescence, methods for charge transports, methods for hole injection, methods of applying the compounds in thin films, and uses of the compounds of the invention in luminescent probes, and electroluminescent displays.

  这项发明提供了对于光致发光和电致发光有用的三配位有机硼化合物。该发明的化合物包括发光剂，最好是发射强烈蓝光的发光剂，电子传输剂，空穴传输剂和空穴注入剂。一种特别优选的化合物是对-(1-萘基苯基氨基)-4,4′-联苯二甲苯基硼烷（BNPB），它展示了所有这些性质。该发明还提供了合成这种三配位硼化合物的方法，生产光致发光和电致发光的方法，电荷传输的方法，空穴注入的方法，将这些化合物应用于薄膜的方法，以及在荧光探针和电致发光显示器中使用该发明的化合物的用途。
• Organic luminescent compounds and methods of making and using same
  申请人：——

  公开号：US20040265628A1

  公开（公告）日：2004-12-30

  The invention provides organic compounds of the general structure (1) 1 (1) that are photoluminescent and electroluminescent, emitting intense blue light. The invention further provides methods of synthesizing such compounds, methods of producing photoluminescence and electroluminescence, methods of applying the compounds in thin films, and uses of the compounds of the invention in luminescent probes, electroluminescent displays and as pH probes and metal ion detectors.

  本发明提供了一般结构式（1）1（1）的有机化合物，该化合物具有光致发光和电致发光性质，能够发出强烈的蓝色光。本发明还提供了合成这种化合物的方法，产生光致发光和电致发光的方法，将该化合物应用于薄膜的方法，以及将该化合物用作发光探针、电致发光显示器、pH探针和金属离子探测器的用途。
• COMPOSITION, FILM, ORGANIC LIGHT EMITTING ELEMENT, METHOD FOR PROVIDING LIGHT EMITTING COMPOSITION, AND PROGRAM
  申请人：Kyulux, Inc.

  公开号：EP4102587A1

  公开（公告）日：2022-12-14

  An organic light emitting element produced by using a light emitting composition that contains both a first compound having a PBHT value more than 0.730 and a second compound having Esi lower than that of the first compound and ΔEST less than 0.20 eV is excellent in durability. Esi is the lowest excited singlet energy level, ΔEST is the difference between the lowest excited singlet energy level and the lowest excited triplet energy level.

  使用同时含有 PBHT 值大于 0.730 的第一种化合物和 Esi 低于第一种化合物且 ΔEST 小于 0.20 eV 的第二种化合物的发光组合物生产的有机发光元件具有优异的耐久性。Esi 是最低激发单电子能级，ΔEST 是最低激发单电子能级与最低激发三电子能级之差。
• Organic electroluminescent device
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US10862047B2

  公开（公告）日：2020-12-08

  An organic electroluminescent device having an anode, a cathode, and a light emitting layer between the anode and the cathode, in which the light emitting layer contains a first organic compound, a second organic compound, and a third organic compound that satisfy the following expression (A), the second organic compound is a delayed fluorescent material, and the third organic compound is a light emitting material, is capable of enhancing the light emission efficiency. ES1(A), ES1(B) and ES1(C) represent a lowest singlet excitation energy level of the first, second and third organic compound, respectively. ES1(A)>ES1(B)>ES1(C)  (A)

  一种有机电致发光器件具有阳极、阴极以及位于阳极和阴极之间的发光层，其中发光层包含满足以下表达式（A）的第一种有机化合物、第二种有机化合物和第三种有机化合物，第二种有机化合物是一种延迟荧光材料，第三种有机化合物是一种发光材料，该器件能够提高发光效率。ES1(A)、ES1(B) 和 ES1(C) 分别代表第一、第二和第三种有机化合物的最低单激发能级。 ES1(A)>ES1(B)>ES1(C) (A)
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION

  公开号：US20160190478A1

  公开（公告）日：2016-06-30

  An organic electroluminescent device having an anode, a cathode, and a light emitting layer between the anode and the cathode, in which the light emitting layer contains a first organic compound, a second organic compound, and a third organic compound that satisfy the following expression (A), the second organic compound is a delayed fluorescent material, and the third organic compound is a light emitting material, is capable of enhancing the light emission efficiency. E S1 (A), E S1 (B) and E S1 (C) represent a lowest singlet excitation energy level of the first, second and third organic compound, respectively. E S1 (A)>E S1 (B)>E S1 (C)  (A)