1,6-六亚甲基二胺癸二酸 | 6422-99-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 1,6-六亚甲基二胺癸二酸
• 英文名称: 1,6-hexamethylenediamine sebacic acid
• 英文别名: hexanediyldiamine; sebacate；Hexandiyldiamin; Sebacinat；sebacic acid, compound with hexane-1,6-diamine (1:1)；Nylon-610-Salz；hexamethylenediammonium sebacate；6-Azaniumylhexylazanium;decanedioate
• CAS: 6422-99-7
• 化学式: C₆H₁₆N₂*C₁₀H₁₈O₄
• 分子量: 318.457
• InChiKey: YWJUZWOHLHBWQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.74
• 重原子数：
  22
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  127
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1,6-己二胺 、 癸二酸 以 乙醇 为溶剂， 反应 2.0h， 以93%的产率得到1,6-六亚甲基二胺癸二酸
  参考文献：
  名称：

  基于异戊二烯-2,5-二亚甲基胺作为具有增强反应性的绿色刚性构建基的聚酰胺的研究

  摘要：

  从一种新的基于碳水化合物的二胺，即异南糖苷-2,5-二亚甲基胺（IIDMA）合成了新型的半结晶聚酰胺和共聚酰胺。与1,6-六亚甲基二胺（1,6-HDA）以及生物基癸二酸（SA）或芸苔酸（BrA）结合使用，可通过尼龙盐的熔融聚合反应，然后将其固相化，获得所需的共聚酰胺。状态缩聚（SSPC）过程。取决于化学组成，聚酰胺的数均分子量（M n）在4000-49000 g / mol的范围内。随着合成共聚酰胺中IIDMA含量的增加，其相应的玻璃化转变温度（T g）从50°C升高至约60–67°C，而熔融温度（Tm）从220降至160°C。通过NMR和FT-IR光谱分析聚酰胺的化学结构。差示扫描量热法（DSC）和广角X射线衍射（WAXD）分析都揭示了这些新型共聚酰胺的半结晶特性。可变温度（VT）13 C { 1 H}交叉极化/魔角旋转（CP / MAS）NMR和FT-IR技术用于研究晶体结构以及IID

  DOI：

  10.1021/ma302126b

文献信息

• NEAR-INFRARED ABSORBENT DISPERSION, AQUEOUS INK FOR INK JET RECORDING, AND AQUEOUS INK SET FOR INK JET RECORDING
  申请人：FUJI XEROX CO., LTD.

  公开号：US20180112092A1

  公开（公告）日：2018-04-26

  A near-infrared absorbent dispersion includes water, a near-infrared absorbent, and a resin dispersant, wherein a weight ratio of the near-infrared absorbent to the total weight of the near-infrared absorbent and the resin dispersant is more than 0.01 and less than 0.33.

  一种近红外吸收分散液包括水、近红外吸收剂和树脂分散剂，其中近红外吸收剂与近红外吸收剂和树脂分散剂总重量的重量比大于0.01且小于0.33。
• Process for making polyamide textile articles bearing designs in different colors
  申请人：Eroshov Michael

  公开号：US20070000065A1

  公开（公告）日：2007-01-04

  Process for manufacturing a fabric having distinctive and sharp differentially colored patterns or designs, which process comprises the steps of: (a) producing a first and a second polyamide, said polyamides having different concentrations of amine groups; (b) producing a first and a second polyamides having different concentrations of carboxyl end-groups and sulfonate groups; (c) producing a first yarn from said first polyamide and a second yarn from said second polyamide; (d) making a fabric having first surface areas defined by said first yarn and second surface areas defined by said second yarn; and (e) chemically dyeing said fabric in a dyeing bath comprising at least one anionic (acid) dyestuff and at least one cationic (basic) dyestuff, whereby said first yarn and therefore said first surface areas are dyed predominantly by said anionic dyestuff and said second yarn and therefore said second surface areas are dyed predominantly by said cationic dyestuff.

  制造具有独特和明显不同颜色图案或设计的织物的过程，该过程包括以下步骤：(a)生产第一种和第二种聚酰胺，所述聚酰胺具有不同浓度的胺基；(b)生产具有不同浓度的羧基末端和磺酸基的第一种和第二种聚酰胺；(c)从所述第一种聚酰胺和第二种聚酰胺中制造第一股纱和第二股纱；(d)制造具有由所述第一股纱定义的第一表面区域和由所述第二股纱定义的第二表面区域的织物；以及(e)在染色浴中化学染色所述织物，该染色浴包括至少一种阴离子(酸性)染料和至少一种阳离子(碱性)染料，因此所述第一股纱和因此所述第一表面区域主要由所述阴离子染料染色，而所述第二股纱和因此所述第二表面区域主要由所述阳离子染料染色。
• Heat-curable, elastomer-forming composition crosslinked with 1,3-diamino propane and method for preparing the composition
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0010789A1

  公开（公告）日：1980-05-14

  Halopolymers, such as chlorinated polyethylene, are uniquely vulcanized by heating a curable mixture including the halopolymer and a 1,3-diaminopropane or salt thereof. A preferred mixture further includes an acid acceptor, such as calcium oxide or calcium hydroxide, and sulfur or a sulfur-containing compound. The scorch safety and shelf life of such compositions are further improved by adding a minor amount of a mixture of N-(cyclohexylthio)phthalimide and N-nitrosodiphenylamine.

  卤聚合物（如氯化聚乙烯）可通过加热包括卤聚合物和 1,3-二氨基丙烷或其盐的可固化混合物进行独特的硫化。 优选的混合物还包括酸接受体（如氧化钙或氢氧化钙）和硫或含硫化合物。 通过添加少量 N-（环己基硫基）邻苯二甲酰亚胺和 N-亚硝基二苯胺的混合物，可进一步提高此类组合物的防焦安全性和保质期。
• Resin composition comprising water-soluble polyamide and vinyl alcohol-based polymer
  申请人：UNITIKA LTD.

  公开号：EP0039226A2

  公开（公告）日：1981-11-04

  A resin composition is described consisting essentially of from 0.5 to 100 parts by weight of a water-soluble polyamide and from 0.5 to 100 parts by weight of a vinyl alcohol-based polymer. The resin composition has excellent transparency and can be used, for example, to form light-sensitive resin compositions and adhesives.

  所述树脂组合物主要由 0.5 至 100 重量份的水溶性聚酰胺和 0.5 至 100 重量份的乙烯醇基聚合物组成。 该树脂组合物具有极佳的透明度，可用于制造光敏树脂组合物和粘合剂等。
• Copolyamide, process for producing thereof and copolyamide molding composition comprising thereof
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0073557A1

  公开（公告）日：1983-03-09

  A copolyamide comprising undecamethylenehexahydroterephthalamide unit and hexamethylenehexahydroterephthalamide unit and having 57 to 83 percent of trans isomer ratio of hexahydroterephthalic acid residues, is suitable for injection and extrusion moldings. The copolyamide is prepared by a process comprising heating of equimolar salt of undecamethylenediamine and hexahydroterephtha- lie acid and equimolar salt of hexamethylenediamine and hexahydroterephthalic acid at maximum temperature of about 280 to 360 °C, whereby the copolyamide is stably metl-polymerized. The copolyamide molding composition comprising the copolyamide and inorganic reinforcing agent, can be formed into various molded articles having excellent properties.

  一种由十一亚甲基六氢对苯二甲酰胺单元和六亚甲基六氢对苯二甲酰胺单元组成的共聚酰胺，其六氢对苯二甲酸残留物的反式异构体比率为 57%至 83%，适用于注射和挤压成型。 该共聚酰胺的制备过程包括在最高温度约 280 至 360 °C 下加热十一亚甲基二胺和六氢对苯二甲酸的等摩尔盐以及六亚甲基二胺和六氢对苯二甲酸的等摩尔盐，从而使共聚酰胺稳定地发生偏聚。 由该共聚酰胺和无机增强剂组成的共聚酰胺成型组合物可制成各种具有优异性能的成型制品。