月桂醇乙基己酸酯 | 56078-38-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 月桂醇乙基己酸酯
• 英文名称: dodecyl 2-ethylhexanoate
• 英文别名: Lauryl 2-ethylhexanoate
• CAS: 56078-38-7
• 化学式: C₂₀H₄₀O₂
• 分子量: 312.536
• InChiKey: YLKDIPABJFXZRY-UHFFFAOYSA-N

物化性质

• 沸点：
  354.6±10.0 °C(Predicted)
• 密度：
  0.862±0.06 g/cm3(Predicted)
• LogP：
  8.781 (est)

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  22
• 可旋转键数：
  17
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-乙基-己酸稀土盐 、 十二烷醇 在 碘 、 三苯基膦 作用下， 以 乙腈 为溶剂， 反应 0.55h， 以90%的产率得到月桂醇乙基己酸酯
  参考文献：
  名称：

  微波辅助的高度实用的羧酸的化学选择性酯化和酰胺化†

  摘要：

  酯和酰胺官能团无处不在，使它们的偶联反应成为最受欢迎的有机转化之一。在此，我们已经描述了酯和酰胺的有效微波辅助合成。可溶性三苯基膦与分子碘结合，可得到所需的产物，而无需碱/催化剂。另外，为所述转化引入了固相合成路线，其与溶液相路线相比具有更多的优点，例如低湿度敏感性，易于处理，通过简单过滤分离产物和可重复使用性。简而言之，我们的方法本质上是简单，温和，绿色和高度化学选择性的。

  DOI：

  10.1039/c6ra22558f

文献信息

• [EN] NOVEL ANTIMICROBIAL PEPTIDES AND THEIR APPLICATION<br/>[FR] NOUVEAUX PEPTIDES ANTIMICROBIENS ET LEUR APPLICATION
  申请人：INFINITEC ACTIVOS S L

  公开号：WO2015135896A1

  公开（公告）日：2015-09-17

  The present invention relates to a compound of formula (I) and to compositions comprising said compound, as well as the use of said compound and/or said compositions to prevent fungal and/or bacterial growth.

  本发明涉及式(I)的化合物，以及包含该化合物的组合物，以及使用该化合物和/或所述组合物来防止真菌和/或细菌生长。
• UV ABSORBER FORMULATIONS
  申请人：Acker Stephanie

  公开号：US20100111884A1

  公开（公告）日：2010-05-06

  Disclosed is a UV filter composition comprising (a) an organic UV absorber of formula (1), wherein R 1 and R 2 , independently of one another, are C 3 -C 18 alkyl; C 2 -C 18 alkenyl; a radical of the formula —CH 2 —CH(OH)—CH 2 —O-T 1 ; or R 1 and R 2 are a radical of the formula (4a); R 7 is a direct bond; a straight-chain or branched C 1 -C 4 alkylene radical or a radical of the formula (I) or (II); R 8 , R 9 and R 10 , independently of one another, are C 1 -C 18 alkyl; C 1 -C 18 alkoxy or a radical of the formula (III); R 11 is C 1 -C 5 alkyl; m 1 is a number from 1 to 4; p 1 is 0; or a number from 1 to 5; A 1 is a radical of the formula (1b), (1c) or (1d); R 3 is hydrogen; C 1 -C 10 alkyl; —(CH 2 CHR 5 —O)n 1 -T 2 ; or —CH 2 —CH(—OH)—CH 2 —O-T 2 ; R 4 is hydrogen; M; C 1 -C 5 alkyl; or —(CH 2 )m 2 —O-T 3 ; R 5 is hydrogen; or methyl; T 1 , T 2 and T 3 independently from each other are hydrogen; or C 1 -C 18 alkyl; Q 1 is C 1 -C 18 alkyl, M is a metal cation; m 2 is 1 to 4; and n 1 is 1-16, (b) dimethyl capramide, (c) a cosmetically acceptable carrier; and water.

  本发明公开了一种紫外线过滤组合物，包括（a）式（1）的有机紫外线吸收剂，其中R1和R2独立地是C3-C18烷基；C2-C18烯基；式—CH2—CH（OH）— —O-T1的基团；或者R1和R2是式（4a）的基团；R7是直链或支链C1-C4烷基、式（I）或（II）的基团；R8、R9和R10独立地是C1-C18烷基、C1-C18烷氧基或式（III）的基团；R11是C1-C5烷基；m1是1至4的数字；p1是0或1至5的数字；A1是式（1b）、（1c）或（1d）的基团；R3是氢、C1-C10烷基、式—（ CHR5—O）n1-T2或式— —CH（—OH）— —O-T2；R4是氢、M、C1-C5烷基或式—（ ）m2—O-T3；R5是氢或甲基；T1、T2和T3互相独立地是氢或C1-C18烷基；Q1是C1-C18烷基，M是金属阳离子；m2是1至4的数字；n1是1-16，（b）二甲基辛酰胺，（c）化妆品可接受载体；和水。
• LUBRICATING OIL FOR REFRIGERATOR, HYDRAULIC FLUID COMPOSITION FOR REFRIGERATOR AND METHOD FOR LUBRICATION OF REFRIGERATOR
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP1225213A1

  公开（公告）日：2002-07-24

  The invention provides a lubricating oil for refrigerators, comprising (a) at least one ester represented by the formula (1) wherein R1 is C1 to C18 straight-chain alkyl or C3 to C18 branched-chain alkyl; R2 is H, C1 to C18 straight-chain alkyl or C3 to C18 branched-chain alkyl; with the poviso that the total number of carbons contained in the alkyls represented by R1 and R2 is 2 to 18 and that when R2 is H, R1 is branched-chain alkyl; and R3 is C1 to C20 straight-chain alkyl, C3 to C20 branched-chain alkyl or C3 to C10 cycloalkyl, optionally in combination with (b) at least one member selected from the group consisting of fatty acid polyol esters, phthalic acid esters, alicyclic dicarboxylic acid esters, polyvinyl ethers, hydrocarbon oils and polyalkylene glycols; as well as a method for lubricating a refrigerator using such a lubricating oil, and a working fluid composition for refrigerators comprising (I) component (a) or components (a) and (b) and (II) a refrigerant.

  本发明提供了一种用于冰箱的润滑油，包括 (a) 至少一种由式 (1) 代表的酯类 其中 R1 是 C1 至 C18 直链烷基或 C3 至 C18 支链烷基；R2 是 H、C1 至 C18 直链烷基或 C3 至 C18 支链烷基；前提是 R1 和 R2 所代表的烷基所含的碳总数为 2 至 18，且当 R2 为 H 时，R1 为支链烷基；和 R3 是 C1 至 C20 直链烷基、C3 至 C20 支链烷基或 C3 至 C10 环烷基，可选择与 (b) 至少一种选自脂肪酸多元醇酯、邻苯二甲酸酯、脂环二羧酸酯、聚乙烯醚、烃油和聚烷基二 醇组成的组的成员结合使用；以及一种使用这种润滑油润滑冰箱的方法，和一种用于冰箱的工作液组合物，该组合物包括 (I) 成分 (a) 或成分 (a) 和 (b) 以及 (II) 制冷剂。
• COMPOSITION FOR COSMETICS, COSMETIC, METHOD FOR PRODUCING OIL-IN-WATER EMULSION COSMETIC, AND TWO SEPARATE LAYER-TYPE COSMETIC
  申请人：The Nisshin Oillio Group, Ltd.

  公开号：EP2494952A1

  公开（公告）日：2012-09-05

  The present invention relates to a composition for cosmetics including a polyglycerol fatty acid ester, which is an ester of polyglycerol having an average degree of polymerization of 4 to 100 with a fatty acid having 2 to 18 carbon atoms, has a hydroxyl value equal to or less than 15 mgKOH/g, and has a specific gravity at 20°C of 0.96 to 1.15; a cosmetic which includes the composition for cosmetics; a method for producing an oil-in-water emulsion cosmetic which includes mixing the composition for cosmetics with a hydrophilic solvent and emulsifying; and a two-separate-layer-type cosmetic, which comprises the composition for cosmetics with water, packaged in a transparent or translucent container. The present invention relates to the composition for cosmetics which can be appropriately used in producing a cosmetic giving a highly excellent feel in using and having a very good texture, a cosmetic showing a very high stability over time as an emulsion even though having a low viscosity, and a two-separate-layer-type cosmetic which can be easily dispersed uniformly by lightly shaking before using and, after using, easily separated into the original two layers, including an oily layer and an aqueous layer, and remain stable.

  本发明涉及一种化妆品组合物，包括聚甘油脂肪酸酯，它是平均聚合度为 4 至 100 的聚甘油与具有 2 至 18 个碳原子的脂肪酸的酯，羟值等于或小于 15 mgKOH/g，在 20°C 时比重为 0.96 至 1.15 ；一种化妆品，其中包括化妆品用组合物；一种生产水包油型乳液化妆品的方法，其中包括将化妆品用组合物与亲水性溶剂混合并乳化；以及一种双层分离型化妆品，其中包括化妆品用组合物和水，包装在透明或半透明容器中。本发明涉及一种化妆品组合物，该组合物可适当地用于生产一种使用感极佳、质地极好的化妆品，一种即使粘度较低，但作为乳液长期使用也能显示出极高稳定性的化妆品，以及一种两层分离型化妆品，该化妆品在使用前轻轻摇晃即可轻松分散均匀，使用后可轻松分离成原来的两层，包括油性层和水性层，并保持稳定。
• VASELINE-LIKE COMPOSITION, AND COSMETIC PREPARATION
  申请人：The Nisshin Oillio Group, Ltd.

  公开号：EP2550954A1

  公开（公告）日：2013-01-30

  The present invention relates to a vaseline-like composition, comprising one type or two or more types of components selected from the following components (C), (D) and (E) at 5% by weight to 20% by weight, the following component (A) at 40% by weight to 90% by weight, and the following component (B) at 5% by weight to 50% by weight, and to a cosmetic containing the vaseline-like composition: component (A) : one or more types of ester compounds selected from diisostearyl malate and diglyceryl triisostearate; component (B): a hydrocarbon wax having a melting point of 70°C to 130°C; component (C): a poly(12-hydroxystearic acid) having an average degree of polymerization of 3 to 20; component (D): a poly(12-hydroxystearic acid) derivative obtained by esterifying a poly(12-hydroxystearic acid) having an average degree of polymerization of 3 to 20 and a polyvalent alcohol having a valence of 5 or more; and, component (E): a dimer dilinoleic acid derivative. According to the present invention, a vaseline-like composition that realizes moisture occlusion comparable to that of vaseline and has superior skin spreadability, superior skin blendability and little stickiness, and a cosmetic incorporating the vaseline-like composition, can be provided.

  本发明涉及一种类血管组合物，该组合物包含一种或两种或多种类型的组分，这些组分选自以下组分(C)、(D)和(E)(重量百分比为5%至20%)、以下组分(A)(重量百分比为40%至90%)和以下组分(B)(重量百分比为5%至50%)，以及含有该类血管组合物的化妆品：组分(A)：选自苹果酸二异硬脂酯和三异硬脂酸二甘油酯的一种或多种酯类化合物；组分(B)平均聚合度为 3 至 20 的聚(12-羟基硬脂酸)；组分(D)：通过酯化平均聚合度为 3 至 20 的聚(12-羟基硬脂酸)和价数为 5 或 5 价以上的多价醇而得到的聚(12-羟基硬脂酸)衍生物；以及组分(E)：二聚二苯乙烯酸衍生物。 根据本发明，可以提供一种类似凡士林的组合物，该组合物可以实现与凡士林相当的湿度闭塞，并且具有优异的皮肤铺展性、优异的皮肤混合性和较小的粘性，还可以提供一种含有该类似凡士林的组合物的化妆品。