iron(II) maleate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: iron(II) maleate
• 英文别名: (Z)-but-2-enedioate; iron(2+)；(Z)-but-2-enedioate;iron(2+)
• 化学式: C₄H₂O₄*Fe
• 分子量: 169.904
• InChiKey: PMVSDNDAUGGCCE-ODZAUARKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.96
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  iron(II) maleate 生成 棕土
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  二铵富马酸盐 生成 iron(II) maleate
  参考文献：
  名称：

  NOVROCIK, JAN;PECHA, JAROSLAV;NOVROCIKOVA, MARTA

  摘要：

  DOI：

文献信息

• Anionic vinyl/dicarboxylic acid polymers and uses thereof
  申请人：——

  公开号：US20020077436A1

  公开（公告）日：2002-06-20

  Biodegradable anionic polymers are disclosed which include recurring polymeric subunits preferably made up of vinylic and dicarboxylic monomers such as vinyl acetate or vinyl alcohol and maleic anhydride, itaconic anhydride or citraconic anhydride, or combinations thereof. Free radical polymerization is used in the synthesis of the polymers, which are then hydrolyzed to replace ester groups with alcohol groups. The polymers may be complexed with ions and/or mixed with fertilizers or seed to yield agriculturally useful compositions. The preferred products of the invention may be applied foliarly, to seeds, to fertilizer, or to the earth adjacent growing plants in order to enhance nutrient uptake by the plants.

  本发明揭示了可生物降解的阴离子聚合物，其中包括重复的聚合亚单位，优选由乙烯基单体和二羧酸单体组成，例如乙酸乙烯酯或乙醇乙烯酮和马来酸酐、伊曲酸酐或顺-柠檬酸酐或其组合。在聚合物的合成中使用自由基聚合，然后通过水解将酯基替换为醇基。聚合物可以与离子复合物和/或混合肥料或种子，以产生农业有用的组合物。本发明的优选产品可以叶面施用，用于种子、肥料或靠近生长植物的土壤，以增强植物的营养吸收。
• Transition-metal bimaleates and their solid solutions: Synthesis, structural, and thermoanalytical study
  作者：L. I. Yudanova、V. A. Logvinenko、L. A. Sheludyakova、N. F. Yudanov、G. N. Chekhova、N. I. Alferova、V. I. Alekseev、P. P. Semyannikov、V. I. Lisoivan

  DOI：10.1134/s0036023608090180

  日期：2008.9

  Transition-metal hydrogen maleates of composition M(C4H3O4)(2) center dot 4H(2)O, where M = Mn, Fe, Co, and Ni, and their solid solutions were synthesized and characterized by X-ray crystallography, IR spectroscopy, mass spectrometry, and thermal analysis. X-ray crystallography and IR spectroscopy showed that both intramolecular and intermolecular H-bonds exist in these compounds. The generation of continuous substitutional solid solutions with cation substitution in these compounds was studied. The thermolysis mechanism was studied for both transition-metal hydrogen maleates and their solid solutions. The composite produced by thermolysis is stable up to 1200 degrees C in flowing helium.
• ——
  作者：DYER P. N.、 NORDQUIST A. F.、 PIERANTOZZI R.

  DOI：——

  日期：——

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