1-(5-氯-2-甲氧基苯基)-吡咯-2,5-二酮 | 39900-81-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯啉
• 中文名称: 1-(5-氯-2-甲氧基苯基)-吡咯-2,5-二酮
• 中文别名: 1-(5-氯-2-甲氧苯基)吡咯-2,5-二酮；1-(5-氯-2-甲氧基-苯基)吡咯-2,5-二酮；1-(5-氯-2-甲氧苯基)-1H-吡咯-2,5-二酮
• 英文名称: N-(5-Chlor-2-methoxy-phenyl)-maleinimid
• 英文别名: 1-(5-chloro-2-methoxyphenyl)-1H-pyrrole-2,5-dione；1-(5-chloro-2-methoxyphenyl)pyrrole-2,5-dione
• CAS: 39900-81-7
• 化学式: C₁₁H₈ClNO₃
• mdl: MFCD00176573
• 分子量: 237.642
• InChiKey: KRYUCWYKHXDVIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  46.6
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险等级：
  IRRITANT
• 海关编码：
  2925190090

反应信息

• 作为反应物：
  描述：

  1-(5-氯-2-甲氧基苯基)-吡咯-2,5-二酮 、 3-氨基-4-苯基-1H-吡唑 以 溶剂黄146 为溶剂， 以78%的产率得到N-(5-chloro-2-methoxyphenyl)-5-oxo-3-phenyl-4,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-7-carboxamide
  参考文献：
  名称：

  Diverse Directions of Heterocyclizations Involving Derivatives of 5-Aminopyrazoles and N-Arylmaleimides

  摘要：

  研究人员对 5-氨基吡唑衍生物和 N-芳基马来酰亚胺之间的异环化反应进行了研究，并确定了几个可能的方向。涉及 1,3- 未取代的 5-氨基吡唑的环化反应产生了两种异构体的混合物，即吡唑并[1,5-a]嘧啶-7-羧酰胺和吡唑并[3,4-b]吡啶-4-羧酰胺。在大多数情况下，4-取代的 5-氨基吡唑在沸腾的乙酸或 N,N-二甲基甲酰胺中反应生成的唯一产物是吡唑并[1,5-a]嘧啶-7-羧酰胺。用马来酰亚胺处理 1-取代的 5-氨基吡唑，只有在 N,N-二甲基甲酰胺中才具有高选择性，生成吡唑并吡啶，而在乙酸中则会与吡咯并吡唑酮形成混合物。对所研究反应的关键中间产物进行了分离和讨论。

  DOI：

  10.1055/s-0030-1258421

文献信息

• Additive for water-base drilling fluid and process
  申请人：ATLANTIC RICHFIELD COMPANY

  公开号：EP0143508A2

  公开（公告）日：1985-06-05

  An additive for water-base drilling fluid compositions used for drilling subterranean wells is disclosed. In one embodiment, the additive is a sulfonated copolymer of recurring units of a maleimide monomer and recurring units of a vinyl monomer. In another embodiment, the additive is a sulfonated terpolymer of recurring units of a maleimide monomer, recurring units of a vinyl monomer, and recurring units of a carboxyl-containing monomer. Water-base drilling fluids compositions which contain the additive and a process for drilling subterranean wells therewith are also disclosed.

  本发明公开了一种用于钻探地下井的水基钻井液组合物的添加剂。 在一个实施例中，该添加剂是马来酰亚胺单体重复单元和乙烯基单体重复单元的磺化共聚物。 在另一个实施例中，该添加剂是马来酰亚胺单体重复单元、乙烯基单体重复单元和含羧基单体重复单元的磺化三元共聚物。 本发明还公开了含有该添加剂的水基钻井液组合物以及使用该添加剂钻探地下井的工艺。
• Heat resistant copolymer composition
  申请人：Sumitomo Dow Limited

  公开号：EP0267574A2

  公开（公告）日：1988-05-18

  A heat resistant copolymer composition is provided by blending two kinds of copolymers one of which is obtaina­ble by polymerizing a maleimide monomer (A), an aromatic vinyl monomer (B), and unsaturated nitrile monomer (C) and optionally at least one other comonomer copolymerizable therewith (D) in a specific monomer ratio in the presence or absence of an elastomeric polymer and which has an intrinsic viscosity of 0.3 to 1.2 dl/g, and another of which is obtainable by copolymerizing the aromatic vinyl monomer (B), the unsaturated nitrile (C) and optionally at least one other comonomer copolymerizable therewith (D) in a specific monomer ratio in the presence or absence of the elastomeric polymer and which has an intrinsic viscosity of 0.3 to 1.5 dl/g.

  通过混合两种共聚物提供了一种耐热共聚物组合物，其中一种共聚物可通过在有或没有弹性聚合物的情况下，以特定的单体比例聚合马来酰亚胺单体（A）、芳香乙烯基单体（B）和不饱和腈单体（C）以及可与之共聚的至少一种其他共聚单体（D）而获得，其固有粘度为 0.3至1.2分升/克，另一种是在有或没有弹性聚合物的情况下，将芳香乙烯基单体(B)、不饱和腈(C)和至少一种可与之共聚的共聚单体(D)按特定的单体比例共聚而得，其固有粘度为0.3至1.5分升/克。
• Resin Composition
  申请人：Sumitomo Dow Limited

  公开号：EP0303782A2

  公开（公告）日：1989-02-22

  A thermoplastic resin composition comprising: (A) a polymer selected from the group consisting of a conjugated diene rubber-reinforced resin and a non-­conjugated diene rubber-reinforced resin and (B) a graft copolymer which is obtainable by poly­merizing (b-1) at least one monomer selected from the group consisting of aromatic vinyl compounds, cyanated vinyl com­pounds and alkyl unsaturated carboxylates and (b-2) at least one unsaturated epoxy monomer in the presence of an ethylene-α-olefin base rubber, which gives a delustered molded article having improved weather resistance and impact resistance.

  一种热塑性树脂组合物，包括 (A) 选自共轭二烯烃橡胶增强树脂和非共轭二烯烃橡胶增强树脂组成的聚合物， 以及 (B) 接枝共聚物，可通过聚合获得 (b-1) 至少一种选自芳香族乙烯基化合物、氰化乙烯基化合物和烷基不饱和羧酸 酯的单体，以及 (b-2) 至少一种不饱和环氧单体在乙烯-α-烯烃基橡胶的存在下进行聚合，从而得到一种具有更好耐候性和抗冲击性的除尘模塑件。
• Reactions of N-arylmaleimides with 3-amino-1,2,4-triazole and 2-aminobenzimidazole
  作者：Roman V. Rudenko、Sergey A. Komykhov、Vladimir I. Musatov、Irina S. Konovalova、Oleg V. Shishkin、Sergey M. Desenko

  DOI：10.1002/jhet.660

  日期：2011.7

  AbstractThe reaction of 3‐amino‐1,2,4‐triazole (1) with N‐arylmaleimides leads to azolopyrimidines 4 and 5. The 2‐aminobenzimidazole (2) in the reaction with 3 gives the pyrimidobenzimidazoles 6. In similar conditions, the reaction of amine 2 with maleic anhydride (7) leads to formation of 2‐oxo‐1,2,3,4‐tetrahydropyrimido[1,2‐a]benzimidazole‐4‐carboxylic acid (8). The structures of 4, 5, 6, and 8 were proved by X‐Ray and NOE NMR measurements. J. Heterocyclic Chem., (2011)
• Elektronenstrahlvernetzbare Resistlacke
  申请人：BAYER AG

  公开号：EP0001997B1

  公开（公告）日：1981-02-11