1-[(E)-2-丙基硫基乙烯基]巯基丙烷 | 1120-17-8

• 物质功能分类: 化学试剂 - 有机试剂 - 烯烃（环状与无环状）
• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 1-[(E)-2-丙基硫基乙烯基]巯基丙烷
• 中文别名: (E)-1,1'-[乙炔二(硫)]-双丙烷
• 英文名称: trans-1,2-Bis-(propylmercapto)-aethen
• 英文别名: trans-1,2-bis-propylsulfanyl-ethene；Propane, 1,1'-((1E)-1,2-ethenediylbis(thio))bis-；1-[(E)-2-propylsulfanylethenyl]sulfanylpropane
• CAS: 1120-17-8
• 化学式: C₈H₁₆S₂
• 分子量: 176.347
• InChiKey: WERZWRCQQURDDW-BQYQJAHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2930909090

文献信息

• Process for the preparation of copolymers of carbon monoxide and ethylenically unsaturated compounds
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0614928A2

  公开（公告）日：1994-09-14

  A process for the preparation of co-polymers by reacting carbon monoxide and one or more ethylenically unsaturated compounds under polymerizable conditions in the substantial absence of a liquid non-polymerizable diluent and in the presence of a catalyst system based on (a) a source of cations of one or more noble metals of Group VIII of the Periodic Table; (b) a source of anions of acids having a pKa of less than 4; (c) a source of cations of one of more metals selected from the group consisting of nickel, cobalt, manganese, lead, zinc, magnesium, iron (II), copper (II), lanthanum and neodymium and (d) a source of bidentate ligands.

  一种用于制备共聚物的工艺，该工艺是在基本不存在液态不可聚合稀释剂的情况下，在可聚合的条件下，使一氧化碳和一种或多种乙烯基不饱和化合物发生反应，该催化剂体系的基础是 (a) 元素周期表第八族的一种或多种贵金属阳离子源； (b) pKa 小于 4 的酸阴离子源； (c) 从镍、钴、锰、铅、锌、镁、铁(II)、铜(II)、镧和钕组成的组中选出的一种或 多种金属的阳离子源；以及 (d) 双齿配体源。
• Gas phase process for the copolymerization of carbon monoxide and ethylenically unsaturated compounds
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0702045A2

  公开（公告）日：1996-03-20

  A gas phase process for the preparation of co-polymers comprising reacting carbon monoxide and an ethylenically unsaturated compound in the presence of a catalyst system based on (a) a source of cations of a metal of Group VIII of the Periodic Table; (b) a source of anions which comprise a plurality of boron atoms or a source of organic boron containing anions or an aluminoxane; and (c) a source of ligands.

  一种制备共聚物的气相工艺，包括一氧化碳和乙烯基不饱和化合物在催化剂系统存在下发生反应，催化剂系统的基础是 (a) 元素周期表第八族金属的阳离子源； (b) 由多个硼原子组成的阴离子源或有机含硼阴离子源或铝氧烷；以及 (c) 配体源。
• Process for the copolymerization of carbon monoxide with an olefinically unsaturated compound
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0733660A1

  公开（公告）日：1996-09-25

  A process for the copolymerization of carbon monoxide with an olefinically unsaturated compound comprising suspending a solid particulate material in a liquid diluent in which the polymer to be produced forms a suspension, and contacting the monomers in the liquid diluent containing the suspended solid particulate material with a catalyst composition which is based on a source of a Group VIII metal and a boron hydrocarbyl compound.

  一种一氧化碳与烯烃不饱和化合物共聚的工艺，包括将固体颗粒材料悬浮在液体稀释剂中，待生产的聚合物在液体稀释剂中形成悬浮液，并将含有悬浮固体颗粒材料的液体稀释剂中的单体与催化剂组合物接触，催化剂组合物基于第八族金属和硼烃基化合物。
• A process for the preparation of a copolymer of carbon monoxide
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0794210A1

  公开（公告）日：1997-09-10

  A process for the copolymerization of carbon monoxide with ethene and optionally another olefinically unsaturated compound in which process the monomers are copolymerized in the presence of a liquid diluent and a catalyst composition which is based on (a) a Group VIII metal compound, (b) an anion of an acid which is obtainable by combining a Brønsted acid with a Lewis acid, and (c) an organic oxidant in a quantity of less than 30 moles per mole of Group VIII metal.

  一种一氧化碳与乙烯和另一种烯烃不饱和化合物共聚的工艺，在该工艺中，单体在一种液体稀释剂和一种催化剂组合物的存在下共聚，该催化剂组合物的基础是 (a) 第 VIII 族金属化合物、 (b) 一种酸的阴离子，该酸可通过将一种布氏酸与一种路易斯酸结合而获得，以及 (c) 一种有机氧化剂，每摩尔 VIII 族金属的含量小于 30 摩尔。
• A PROCESS FOR THE PREPARATION OF CO-POLYMERS OF CARBON MONOXIDE AND ETHYLENICALLY UNSATURATED COMPOUNDS
  申请人：SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.

  公开号：EP0642545A1

  公开（公告）日：1995-03-15