1-丁基硫烷基-己烷 | 16967-04-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 1-丁基硫烷基-己烷
• 英文名称: butyl hexyl sulfide
• 英文别名: 1-butylsulfanyl-hexane；Butyl-hexyl-sulfid；5-Thiaundecane；1-butylsulfanylhexane
• CAS: 16967-04-7
• 化学式: C₁₀H₂₂S
• 分子量: 174.351
• InChiKey: YZUHMAFUXBPUKH-UHFFFAOYSA-N

物化性质

• 熔点：
  -53.83°C (estimate)
• 沸点：
  215.37°C (estimate)
• 密度：
  0.8410
• 保留指数：
  1278;1278

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  11
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  n-hexyl(vinyl)sulfide 在 ruthenium(IV) oxide 乙醇 、 氢气 、 sodium 作用下， 以 甲醇 为溶剂， 25.0~60.0 ℃ 、810.6 kPa 条件下， 反应 96.0h， 生成 1-丁基硫烷基-己烷
  参考文献：
  名称：

  Low Pressure Hydrogenation of Unsaturated Sulphides with Homogeneous and Heterogeneous Ruthenium Catalysts

  摘要：

  Ru2O . nH(2)O and [Ru3O(AcO)(6)(H2O)(3)](AcO-)-Ac-+ were examined for catalytic activity in the hydrogenation of a series of unsaturated sulphides under heterogeneous and homogeneous conditions, respectively. By the appropriate combination of these two methodologies, a number of saturated sulphides could be synthesized in satisfactory to good yields, thus minimizing side reactions.

  DOI：

  10.1080/00397919608003694

文献信息

• DIBENZORYLENETETRACARBOXIMIDES AS INFRARED ABSORBERS
  申请人：Koenemann Martin

  公开号：US20100048904A1

  公开（公告）日：2010-02-25

  Dibenzorylenetetracarboximides of the general formula I in which the variables are each defined as follows: R′ are identical or different radicals: hydrogen; optionally substituted aryloxy, arylthio, hetaryloxy or hetarylthio; R are identical or different radicals: hydrogen; optionally substituted C 1 -C 30 -alkyl, C 3 -C 8 -cycloalkyl, aryl or hetaryl; m, n are each independently 0 or 1.

  一般式I的二苯并咔唑四羧酰亚胺中，变量定义如下：R′为相同或不同的基团：氢；可选择取代的芳氧基、芳硫基、杂芳氧基或杂芳硫基；R为相同或不同的基团：氢；可选择取代的C1-C30烷基、C3-C8环烷基、芳基或杂芳基；m，n各自独立地为0或1。
• LIQUID CRYSTALLINE RYLENE TETRACARBOXYLIC ACID DERIVATIVES AND USE THEREOF
  申请人：Koenemann Martin

  公开号：US20110042651A1

  公开（公告）日：2011-02-24

  The present invention relates to liquid-crystalline rylenetetracarboxylic acid derivatives, to processes for their preparation and to their use as n-type organic semiconductors for producing organic field-effect transistors and solar cells.

  本发明涉及液晶芳纶四羧酸衍生物，其制备方法以及作为n型有机半导体用于制造有机场效应晶体管和太阳能电池的用途。
• [EN] OLIGOCONDENSED PERYLENE BISIMIDES<br/>[FR] BISIMIDES DE PÉRYLÈNE OLIGOCONDENSÉS
  申请人：BASF SE

  公开号：WO2010111822A1

  公开（公告）日：2010-10-07

  The present invention relates to oligocondensed perylene bisimides, a method for their production and their use.

  本发明涉及寡聚化的苝二酰亚胺，其生产方法及其用途。
• A remarkably efficient initiation by 9-BBN in the radical addition reactions of alkanethiols to alk-1-enes
  作者：Yuzuru Masuda、Masayuki Hoshi、Yutaka Nunokawa、Akira Arase

  DOI：10.1039/c39910001444

  日期：——

  A catalytic amount of 9-borabicyclo[3.3.1]nonane (9-BBN) initiates radical addition reactions of alkanethiols to alkenes under very mild conditions to provide the corresponding dialkyl sulphides almost quantitatively.

  在非常温和的条件下，催化量的 9-硼杂双环[3.3.1]壬烷（9-BBN）可引发烷硫醇与烯烃的自由基加成反应，从而几乎定量地生成相应的二烷基硫化物。
• Amidothiol derivatives
  申请人：NATIONAL RESEARCH DEVELOPMENT CORPORATION

  公开号：EP0021637A1

  公开（公告）日：1981-01-07

  Amidothiol derivatives have the formula wherein: R represents an alkyl, alk-2 to 6 - enyl, phenylalkyl, phenyl or heterocyclic group optionally substituted by one or more functional groups inert to electrochemical oxidation: R1, R2, R3 and R4 independently represent hydrogen or substituent groups, and r5 represents alkyl, phenylalkyl or phenyl. The derivatives are useful in the preparation of pharmaceutically active compounds and dyestuffs and have herbicidal and/or antibacterial activity. The compounds can be prepared by electrochemical oxidation of a corresponding organic disulphide in the presence of the corresponding alkene and the corresponding organic nitrite, and treatment of the reaction product with water.

  酰胺硫醇衍生物的化学式为 其中 R 代表烷基、烷-2-6-烯基、苯基烷基、苯基或杂环基团，可任选被一个或多个电化学氧化惰性官能团取代： R1、R2、R3 和 R4 分别代表氢或取代基，r5 代表烷基、苯基烷基或苯基。这些衍生物可用于制备医药活性化合物和染料，并具有除草和/或抗菌活性。这些化合物的制备方法是：在相应的烯烃和相应的有机亚硝酸盐存在下，对相应的有机二硫化物进行电化学氧化，然后用水处理反应产物。