1-甲基-3,5,7-三氮杂-1-氮翁金刚烷氯化物 | 76902-90-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪烷类
• 中文名称: 1-甲基-3,5,7-三氮杂-1-氮翁金刚烷氯化物
• 英文名称: N-methylhexamethylenetetramine chloride
• 英文别名: hexamine methochloride；urotropine methyl chloride；methyl-hexamethylenetetraminium; chloride；Methyl-hexamethylentetraminium; Chlorid；1-methyl-3,5,7-triaza-1-azoniatricyclodecane chloride；methyl-3,5,7-triaza-1-azoniaadamantane chloride；1-Methyl-3,5,7-triaza-1-azoniaadamantane chloride；1-methyl-3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane;chloride
• CAS: 76902-90-4
• 化学式: C₇H₁₅N₄*Cl
• 分子量: 190.676
• InChiKey: XUTDJVFRVABGQY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.87
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2933990090

反应信息

• 作为反应物：
  描述：

  1-甲基-3,5,7-三氮杂-1-氮翁金刚烷氯化物 、 mercury dichloride 以 水 为溶剂， 生成 methyl hexamethylentetrammonium tetrachloromercurate(II)
  参考文献：
  名称：

  Cohn, G., Pharmazeutische Zentralhalle für Deutschland, 1919, vol. 60, p. 65 - 69

  摘要：

  DOI：
• 作为产物：
  描述：

  六亚甲基四胺,二硝酸盐 在 水 作用下， 生成 1-甲基-3,5,7-三氮杂-1-氮翁金刚烷氯化物
  参考文献：
  名称：

  Foss et al., Journal of the Chemical Society, 1950, p. 624,626

  摘要：

  DOI：

文献信息

• Hydrogen bonding Part 44. 1-Methyl-1,3,5,7-tetra-aza-adamantan-1-ium (N-methylhexamethylenetetramine cation) halide hydrates: IR and thermodynamic study of planar C2h (H2O·Br−)2 and (H2O·Cl−)2 clusters, a possible C2h (H2 O·I− )2 cluster, and two higher Cl- hydrates
  作者：Kenneth M. Harmon、Patricia K. Keefer

  DOI：10.1016/0022-2860(92)85018-c

  日期：1992.7

  Abstract The IR spectrum of the C 2h (H 2 O·Br − ) 2 cluster in the bromide monohydrate of the N -methylhexamethylenetetramine cation (MHMTA + ) correlates well with that of the C 2h H 2 O·Cl − ) 2 cluster in tetraethylammonium chloride monohydrate. MHMTA + Cl − forms a monohydrate which contains a similar cluster, as well as a dihydrate and trihydrate. Equilibrium dissociation vapor pressure measurements

  摘要 N-甲基六亚甲基四胺阳离子 (MHMTA + ) 的溴化物一水合物中 C 2h (H 2 O·Br - ) 2 簇的红外光谱与 C 2h H 2 O·Cl - ) 2 簇在四乙基氯化铵一水合物。MHMTA + Cl - 形成包含类似簇的一水合物以及二水合物和三水合物。平衡解离蒸气压测量表明，HOHċX - 氢键的最小值在一水合溴化物中约为6.5 kcal mol -1 ，在一水合氯化物中约为7.5 kcal mol -1 。MHMTA + I - 形成短暂的一水合物；有限范围内的解离测量表明 HOH⋯I - 氢键的最小值约为 8 kcal mol -1。
• Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes
  申请人：McDaniel C. Steven

  公开号：US20100210745A1

  公开（公告）日：2010-08-19

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peotide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文公开了一些聚合材料，如涂层、塑料、层压板、复合材料、弹性体、粘合剂或密封剂；一种表面处理，如纺织品涂层或蜡；一种填料，用于这样的聚合材料或表面处理，其中包括一种酶，如酯酶（例如，脂肪水解酶，硫酸酯水解酶，有机磷化合物降解酶），降解细胞壁和/或细胞膜成分的酶（例如，溶菌酶，裂解转糖基酶），生物杀菌或生物静态肽，以及/或肽酶。本文还公开了通过将酶纳入可通过脂肪水解酶、水解酶和/或脲酶的活性交联材料中来改变材料性能，如使用寿命、柔韧性或刚度的方法。
• VISUAL ASSAYS FOR COATINGS INCORPORATING BIOACTIVE ENZYMES FOR CATALYTIC FUNCTIONS
  申请人：Reactive Surface, Ltd.

  公开号：US20140196631A1

  公开（公告）日：2014-07-17

  Disclosed herein are materials such as a coating, comprising a lipolytic enzyme or organophosphrous compound degrading enzyme. Also disclosed herein are methods of visually detecting enzyme activity in a coating by contacting the coating with a substrate of an enzyme and a visual indicator that changes appearance upon production of a product of enzyme activity on a tack-free coating surface.

  本文公开了一种涂层材料，包括脂肪水解酶或有机磷化合物降解酶。本文还公开了一种方法，通过将涂层与酶底物和视觉指示剂接触，以在无粘涂层表面产生酶活性产物时改变外观来检测酶活性。
• Anti-fouling Paints and Coatings
  申请人：Reactive Surfaces LTD

  公开号：US20150191607A1

  公开（公告）日：2015-07-09

  Disclosed herein are polymeric materials such as a coating, a plastic, a laminate, a composite, an elastomer, an adhesive, or a sealant; a surface treatment such as a textile finish or a wax; a filler for such a polymeric material or a surface treatment that includes an enzyme such as an esterase (e.g., a lipolytic enzyme, a sulfuric ester hydrolase, an organophosphorus compound degradation enzyme), an enzyme (e.g., a lysozyme, a lytic transglycosylase) that degrades a cell wall and/or a cell membrane component, a biocidal or biostatic peptide, and/or a peptidase. Also disclosed herein are methods of altering a material's property such as service life, flexability, or rigidity, by incorporation of an enzyme into a material capable of being chemically crosslinked by the activity of a lipolytic enzyme, a hydrolase, and/or a urease.

  本文披露了聚合材料，例如涂层、塑料、层压材料、复合材料、弹性体、粘合剂或密封剂；表面处理，例如纺织品整理或蜡；填充剂，用于这种聚合材料或表面处理，包括酯酶（例如脂肪水解酶、硫酸酯水解酶、有机磷化合物降解酶）的酶，降解细胞壁和/或细胞膜成分的酶（例如溶菌酶、裂解转葡糖苷酶），生物杀菌或生物稳定肽，和/或肽酶。本文还披露了通过将酶并入能够通过脂肪水解酶、水解酶和/或脲酶的活性进行化学交联的材料中，改变材料性能（例如使用寿命、柔韧性或刚度）的方法。
• Antifungal and antibacterial coating compositions
  申请人：McDaniel, Steven C.

  公开号：EP2431429A2

  公开（公告）日：2012-03-21

  Antifungal and antibacterial peptides, polypeptides and proteins as antifungal additives for paint and other coatings are disclosed, along with antifungal compositions, and coated surfaces with antifungal properties. Methods of using the coatings for treating and/or inhibiting growth of mold, mildew and other fungi and bacteria on objects such as building materials that are susceptible to such infestation are also disclosed.

  本发明公开了作为涂料和其他涂层的抗真菌添加剂的抗真菌和抗菌肽、多肽和蛋白质，以及抗真菌组合物和具有抗真菌特性的涂层表面。此外，还公开了使用这些涂料处理和/或抑制易受霉菌、霉菌和其他真菌及细菌侵扰的建筑材料等物体上霉菌、霉菌和其他真菌及细菌生长的方法。