1-甲基丁基甲基丙烯酸酯 | 94159-12-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1-甲基丁基甲基丙烯酸酯
• 中文别名: 磷酸氢3-氨丙基(二甲基)铵
• 英文名称: methacrylic acid-(1-methyl-butyl ester)
• 英文别名: Methacrylsaeure-(1-methyl-butylester)；1-methylbutyl methacrylate；methyl-butyl methacrylate；pentan-2-yl 2-methylprop-2-enoate
• CAS: 94159-12-3
• 化学式: C₉H₁₆O₂
• 分子量: 156.225
• InChiKey: QSYOAKOOQMVVTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2916140000

反应信息

• 作为产物：
  描述：

  (S)-(+)-2-戊醇 、 甲基丙烯酸甲酯 生成 1-甲基丁基甲基丙烯酸酯
  参考文献：
  名称：

  Koton; Florinskii, Zhurnal Obshchei Khimii, 1951, vol. 21, p. 1841; engl. Ausg. S. 2041

  摘要：

  DOI：

文献信息

• Processes for preparing aqueous polymer emulsions
  申请人：——

  公开号：US20020045703A1

  公开（公告）日：2002-04-18

  This invention relates to processes for preparing aqueous polymer emulsions useful as thickening agents in aqueous compositions in which plating and/or grit formation is reduced in said processes. This invention also relates to methods for reducing plating and/or grit formation in processes for preparing aqueous polymer emulsions useful as thickening agents in aqueous compositions. This invention further relates to polymers which are soluble in, or swelled by, an aqueous alkaline medium to provide thickeners for use in aqueous coating compositions, especially latex paints.

  本发明涉及制备水性聚合物乳液的工艺，其在水性配方中作为增稠剂有用，并且在该工艺中减少电镀和/或磨粒形成。本发明还涉及减少制备水性聚合物乳液的工艺中电镀和/或磨粒形成的方法。本发明还涉及可溶于或被水性碱性介质肿胀的聚合物，以提供用于水性涂料配方中的增稠剂，特别是乳胶漆。
• Pigment dispersions containing copolymer pigment dispersants and methods of grinding pigment dispersions
  申请人：HÜLS AMERICA INC. (a Delaware corporation)

  公开号：EP0033213A2

  公开（公告）日：1981-08-05

  Low-molecular weight addition copolymers of (1) (meth) acrylic acid esters of alcohols such as methanol and butanol with (2) (meth) acrylic acid esters of alcohols such as N-(β-hydroxyethyl)oxazolidine, optionally including (3) α,β-ethylenically-unsaturated monomers such as (meth)acrylic acid, (where in each instance "(meth)acrylic" means acrylic or methacrylic or both) are used as dispersants for inorganic and organic pigments and colourants which are insoluble in organic solvents, for lacquers. These pigment dispersants are compatible with practically all types of lacquer resins, such as vinyls, nitrocellulose and alkyds, and also with many other types of lacquer film-forming materials. Usually, when small amounts of unsaturated carboxylic acids, or other polar monomers and combinations thereof, are incorporated in the polymers, they become improved pigment dispersants. Such pigment dispersions, unexpectedly, can be let down with many types of synthetic resins and used by air-drying or baking the coated articles. Lacquers for metals, paints and printing inks are examples of uses for such blends.

  (1)甲醇和丁醇等醇的(甲基)丙烯酸酯与(2)N-(β-羟乙基)恶唑烷等醇的(甲基)丙烯酸酯的低分子量加成共聚物，可选择包括(3)α、β-乙烯基不饱和单体，如(甲基)丙烯酸（这里的"(甲基)丙烯酸 "是指丙烯酸或甲基丙烯酸或两者），可用作不溶于有机溶剂的无机和有机颜料和着色剂的分散剂，如漆。这些颜料分散剂几乎与所有类型的漆树脂兼容，如乙烯基、硝化纤维和醇酸树脂，也与许多其他类型的漆成膜材料兼容。通常情况下，当聚合物中加入少量不饱和羧酸或其他极性单体及其组合时，它们就会成为经过改良的颜料分散剂。出乎意料的是，这种颜料分散剂可以与多种类型的合成树脂混合，并通过风干或烘烤涂覆物品来使用。金属漆、油漆和印刷油墨就是此类混合物的应用实例。
• High solids primer-guidecoats based on t-butyl acrylate and styrene
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0103118A1

  公开（公告）日：1984-03-21

  Coating compositions, especially useful as guide coats are produced from copolymers of t-butyl acrylate and styrene which have been crosslinked, preferably with a polyepoxide or an etherified amine-formaldehyde resin.

  由丙烯酸叔丁酯和苯乙烯的共聚物交联而成的涂层组合物，尤其可用作导向涂层，最好与聚环氧树脂或醚化胺-甲醛树脂交联。
• Highly weatherable coatings
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0103146A1

  公开（公告）日：1984-03-21

  Copolymers which are comprised of from about 10 to about 90 weight percent t-butyl acrylate, and which possess a glass transition temperature of less than about 50°C, are formulated into crosslinked coating compositions which possess unexpectedly superior weathering resistance.

  丙烯酸叔丁酯重量百分比从 10%到 90%不等的共聚物，其玻璃化温度低于 50°C，配制成的交联涂料组合物具有出乎意料的优异耐候性。
• Block polymers of methacrylates and derivatives thereof
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0298667A2

  公开（公告）日：1989-01-11

  Block polymers comprise in polymeric form, at least one block selected from hydrolyzable C2-C5 alkyl methacrylates, methacrylic acid and ionomers thereof and at least one other block of an an ionically copolymerizable monomer other than methylmethacrylate. Preferably, the other block comprises, in polymerized form,a conjugated diene, hydrogenated conjugated diene or a C6-C20 nonhydrolyzable methacrylate ester. It is especially preferred that the diene is butadiene or isoprene, the nonhydrolyzable methacrylate is 2-ethylhex- ymethacrylate and that the hydrolyzable methacrylate is t-butyl methacrylate.

  嵌段聚合物的聚合形式包括至少一个选自可水解的 C2-C5 烷基甲基丙烯酸酯、甲基丙烯酸及其离子聚合物的嵌段和至少另一个选自甲基丙烯酸甲酯以外的可离子共聚单体的嵌段。另一个嵌段最好是聚合形式的共轭二烯、氢化共轭二烯或 C6-C20 非水解甲基丙烯酸酯。特别优选的是，二烯是丁二烯或异戊二烯，不可水解的甲基丙烯酸酯是甲基丙烯酸 2-乙基己酯，可水解的甲基丙烯酸酯是甲基丙烯酸叔丁酯。