1-甲基乙烯基甲基丙烯酸酯 | 93942-70-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 1-甲基乙烯基甲基丙烯酸酯
• 英文名称: ethylene-methyl methacrylate
• 英文别名: isopropenyl methacrylate；1-methylvinyl methacrylate；isopropenyl (meth)acrylate；Methacrylsaeure-isopropenylester；2-Propenoic acid, 2-methyl-, 1-methylethenyl ester；prop-1-en-2-yl 2-methylprop-2-enoate
• CAS: 93942-70-2
• 化学式: C₇H₁₀O₂
• 分子量: 126.155
• InChiKey: PKFBISBCCISXKA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-甲基乙烯基甲基丙烯酸酯 以90%的产率得到3-羟基-1-金刚烷基甲基丙烯酸酯
  参考文献：
  名称：

  POLYMERIZABLE ADAMANTANE DERIVATIVES AND PROCESS FOR PRODUCING THE SAME

  摘要：

  公开号：

  EP0915077B1

文献信息

• Polymers of 3-butene esters, their preparation and use
  申请人：Eastman Chemical Company

  公开号：US20010051690A1

  公开（公告）日：2001-12-13

  The specification describes various polymers having monomer of formula (I): 1 In formula (I), R1 and R2 are, independently, hydrogen, a C 1 -C 24 alkyl group, an aromatic or heteroaromatic group, a C 3 -C 8 cycloalkyl or C 2 -C 7 heterocycloalkyl group, or a —C(O)R3 group in which R3 is a C 1 -C 24 alkyl group, an aromatic or heteroaromatic group, a C 3 -C 8 cycloalkyl or C 2 -C 7 heterocyclic group; or a —CH 2 —C(O)—R4 group in which R4 is a C 1 -C 6 alkyl group. At least one of R1 and R2 is a —C(O)R3 group. The polymer may be a homopolymer or a copolymer containing other ethylenically unsaturated monomers. The polymer may be used in a variety of coating compositions such as inks, adhesives, paints and films. Unique monomers where both R1 and R2 are acetoacetyl groups and novel monomers where R2 is an acetoacetyl group are also described.

  该规范描述了具有式(I)的单体的各种聚合物： 在式(I)中，R1和R2分别是氢、C1-C24烷基、芳香或杂芳基、C3-C8环烷基或C2-C7杂环烷基、或者—C(O)R3基团，其中R3是C1-C24烷基、芳香或杂芳基、C3-C8环烷基或C2-C7杂环基；或者—CH2—C(O)—R4基团，其中R4是C1-C6烷基。R1和R2中至少有一个是—C(O)R3基团。该聚合物可以是同聚物或含有其他乙烯基不饱和单体的共聚物。该聚合物可用于各种涂料组合物，如油墨、粘合剂、油漆和薄膜。还描述了R1和R2均为乙酰乙酰基团的独特单体以及R2为乙酰乙酰基团的新型单体。
• [EN] PHOTOALIGNING MATERIALS<br/>[FR] MATÉRIAUX DE PHOTOALIGNEMENT
  申请人：ROLIC AG

  公开号：WO2013050121A1

  公开（公告）日：2013-04-11

  The present invention relates to polymer, homo- or copolymer or oligomer for the photoalignment of liquid crystals, especially for the planar orientation of liquid crystals, comprising a main chain and a side chain, wherein the side chain and/or main chain comprises a polar group, compositions thereof, and its use for optical and electro optical devices, especially liquid crystal devices (LCDs).

  本发明涉及用于液晶的光调向的聚合物、同聚物或寡聚物，特别用于液晶的平面取向，包括主链和侧链，其中侧链和/或主链包含极性基团，以及其组合物，以及其在光学和电光设备中的应用，特别是液晶设备（LCD）。
• PHOTOCROSSLINKABLE MATERIALS COMPRISING ALICYCLIC GROUP
  申请人：Eckert Jean-Francois

  公开号：US20100048849A1

  公开（公告）日：2010-02-25

  A diamine compound of formula (I) is proposed as well as polymers, copolymers, polyamic acids, polyamic acid esters, or polyimides based on such compound.

  提出了一种化学式为（I）的二胺化合物，以及基于该化合物的聚合物，共聚物，聚酰胺酸，聚酰胺酸酯或聚酰亚胺。
• Photocrosslinkable Materials
  申请人：Bachels Thomas

  公开号：US20080293888A1

  公开（公告）日：2008-11-27

  A diamine compound of formula (I) is proposed as well as polymers, copolymers, polyamic acids, polyamic acid esters, or polyimides based on such compound.

  提出了一种化学式为(I)的二胺化合物，以及基于该化合物的聚合物、共聚物、聚酰胺酸、聚酰胺酸酯或聚酰亚胺。
• THERMALLY STABLE ALIGNMENT MATERIALS
  申请人：Bury Izabela

  公开号：US20110065859A1

  公开（公告）日：2011-03-17

  A thermally stable diamine compound of formula (I′) is proposed as well as polymers, copolymers, polyamic acids, polyamic acid esters, or polyimides based on such compound.

  提出了一种公式为（I'）的热稳定二胺化合物，以及基于该化合物的聚合物，共聚物，聚酰胺酸，聚酰胺酸酯或聚酰亚胺。