1-羟基屈 | 63019-38-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 1-羟基屈
• 中文别名: 1-羟基屈
• 英文名称: 1-hydroxy-chrysene
• 英文别名: 1-hydroxychrysene；chrysene-1-ol；chrysen-1-ol；1-chrysenol；1-Hydroxy-chrysen
• CAS: 63019-38-5
• 化学式: C₁₈H₁₂O
• 分子量: 244.293
• InChiKey: ISHBWEUQYFEVES-UHFFFAOYSA-N

物化性质

• 熔点：
  >160°C (dec.)
• 溶解度：
  可溶于DMSO（轻微）、甲醇（轻微、加热）

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-羟基屈 在 1,4-二氧六环 、 sodium dithionite 、 potassium nitrososulfonate 、 tin(ll) chloride 作用下， 生成 1,4-dimethoxy-chrysene
  参考文献：
  名称：

  Teuber; Lindner, Chemische Berichte, 1959, vol. 92, p. 932,937

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2,3,4-四氢屈-1-酮 在 钯 、 甲基萘 作用下， 生成 1-羟基屈
  参考文献：
  名称：

  76.多环芳烃。XXX部分。甲酚的合成

  摘要：

  DOI：

  10.1039/jr9450000288

文献信息

• PROCESS FOR PRODUCING ESTER COMPOUND
  申请人：Imazeki Shigeaki

  公开号：US20100324314A1

  公开（公告）日：2010-12-23

  PROBLEM To provide an environmentally-friendly method for producing industrially an ester compound. SOLUTION The present invention is a method for producing an ester compound which comprises subjecting a carboxylic acid and an alcohol to dehydration-condensation reaction using an involatile acid catalyst and then removing the residual acid catalyst by bringing a weak basic substance into contact with the residual acid catalyst.

  问题提供一种生产工业酯化合物的环保方法。 解决方案是一种生产酯化合物的方法，包括将羧酸和醇经过脱水缩合反应，使用一种不挥发的酸催化剂，然后通过将弱碱性物质与残留的酸催化剂接触来去除残留的酸催化剂。
• Novel arylamine compound and organic electroluminescence device
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：US20020137969A1

  公开（公告）日：2002-09-26

  A novel arylamine compound represented by the following general formula (1): 1 wherein R 1 and R 2 each independently represent an alkyl group, an alkoxyl group, an aryl group, an arylalkyl group or an aryloxyl group, Ar 1 to Ar 4 each independently represent an aryl group or a heterocyclic group, with provisos that at least two of Ar 1 to Ar 4 each represent m-biphenyl group or a biphenyl group substituted with aryl groups and the others of Ar 1 to Ar 4 each represent biphenyl group and that, when the biphenyl group substituted with aryl groups is a biphenyl group substituted with two aryl groups, the others of Ar 1 to Ar 4 each represent an aryl group; and an organic electroluminescence device comprising a layer of organic compounds which comprises the novel arylamine compound. The organic electroluminescence device has a high luminance, excellent heat resistance and a long life and emits light; at a high efficiency. The novel arylamine compound provides the advantageous properties to the organic electroluminescence device.

  一种新的芳胺化合物，其通式如下（1）： 其中R1和R2分别独立表示烷基、烷氧基、芳基、芳基烷基或芳氧基，Ar1至Ar4分别独立表示芳基或杂环基，但至少两个Ar1至Ar4中的每一个表示m-联苯基或被芳基取代的联苯基，其余的Ar1至Ar4中的每一个表示联苯基；以及包括该新的芳胺化合物的有机电致发光器件。该有机电致发光器件具有高亮度、优异的耐热性和长寿命，并以高效率发光。该新的芳胺化合物为有机电致发光器件提供了有利的性能。
• [EN] AROMATIC AMINE DERIVATIVES AND ORGANIC LIGHT EMITTING LAYER AND DIODE COMPRISING THE SAME<br/>[FR] DÉRIVÉS D'AMINE AROMATIQUE ET COUCHE ET DIODE ÉLECTROLUMINESCENTES ORGANIQUES LES COMPRENANT
  申请人：DOOSAN CORP

  公开号：WO2009091095A1

  公开（公告）日：2009-07-23

  Disclosed are aromatic amine derivatives that can significantly improve material lifetime and luminous efficiency by introducing substituted or unsubstituted, saturated or unsaturated, hexagonal or more polygonal hydrocarbon rings into positions 2, 3, 6 and 7 of anthracene to thereby preventing the crystallization of anthracene, and an organic light emitting layer and an organic light emitting diode comprising the same.

  揭示了一种芳香胺衍生物，通过将取代或未取代的饱和或不饱和的六边形或更多边形的碳氢环引入蒽的2、3、6和7位，从而防止蒽的结晶，可以显著提高材料的寿命和发光效率，以及包括该衍生物的有机发光层和有机发光二极管。
• Directed <i>ortho</i>-Metalation and Anionic <i>ortho</i>-Fries Rearrangement of Polycyclic Aromatic <i>O</i>-Carbamates: Regioselective Synthesis of Substituted Chrysenes
  作者：Sindhu Kancherla、Marianne Lorentzen、Victor Snieckus、Kåre B. Jørgensen

  DOI：10.1021/acs.joc.7b03210

  日期：2018.4.6

  A general method for the regioselective synthesis of a series of ortho-substituted chrysenyl N,N-diethyl-O-carbamates by the directed ortho-metalation (DoM) strategy is reported. The starting O-carbamates were prepared from the corresponding chrysenols, available by oxidative photochemical cyclization or directed remote metalation tactics. Chrysen-1-yl and chrysene-3-yl ring site selectivity of directed

  报道了通过定向邻位金属化（D o M）策略区域选择性合成一系列邻位取代的N，N-二乙基-O-氨基甲酸酯的一般方法。起始的O-氨基甲酸酯是由相应的酚类化合物制备的，可以通过氧化光化学环化或直接的远程金属化策略获得。屈（chrysene）哌啶-1-基和苯并菲-3-基环部位选择性定向邻-metalation（d Ò M）和阴离子邻-Fries重排（A ö F）协议，与小号观察到-BuLi / TMEDA，随后使用选择的亲电试剂进行亲电淬灭，产生了新的Chrysenyl衍生物。5屈基N，N-二乙基ø -氨基甲酸酯后行瞬间甲ö ˚F即使在-100℃至配料屈重排Ò羟基甲酰胺。进行了反复的D o M反应，以了解区域选择性因素。
• ASYMMETRIC STYRYL DERIVATIVES AND ORGANIC LIGHT EMITTING DIODE PREPARED USING THE SAME
  申请人：Kim Tae-Hyung

  公开号：US20100081846A1

  公开（公告）日：2010-04-01

  Disclosed are asymmetric styryl derivatives and an organic light emitting diode prepared using the same. More particularly, there are provided asymmetric styryl derivatives that can provide a blue organic light emitting diode with superior thermal stability, as well as improved luminous efficiency, improved brightness, and extended lifetime, by synthesizing a novel thermally stable compound with a styryl structure represented by Formula 1, and using the compound as a dopant in an organic light emitting layer (EML) of a multilayered organic light emitting diode, and an organic light emitting diode prepared by the same.

  本发明涉及不对称的苯乙烯基衍生物及其制备的有机发光二极管。更具体地，本发明提供了一种不对称的苯乙烯基衍生物，通过合成具有式1所表示的苯乙烯结构的新型热稳定化合物，并将该化合物用作多层有机发光二极管的有机发光层（EML）中的掺杂剂，可以提供具有优越热稳定性、改善的发光效率、改善的亮度和延长寿命的蓝色有机发光二极管。同时本发明还提供了制备该有机发光二极管的方法。