2,2'-(2-甲基丙亚基)二[6-叔丁基-4-甲基-苯酚 | 93803-56-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,2'-(2-甲基丙亚基)二[6-叔丁基-4-甲基-苯酚
• 英文名称: 6,6'-di-tert-butyl-4,4'-dimethyl-2,2'-isobutylidene-di-phenol
• 英文别名: 2-Methyl-1,1-bis-(6-hydroxy-3-methyl-5-tert.-butyl-phenyl)-propan；6,6'-Di-tert-butyl-4,4'-dimethyl-2,2'-isobutyliden-di-phenol；2,2'-(2-methylpropylidene)bis[6-(1,1-dimethylethyl)-p-cresol]；2,2'-(2-Methylpropylidene)bis(6-(1,1-dimethylethyl)-p-cresol)；2-tert-butyl-6-[1-(3-tert-butyl-2-hydroxy-5-methylphenyl)-2-methylpropyl]-4-methylphenol
• CAS: 93803-56-6
• 化学式: C₂₆H₃₈O₂
• 分子量: 382.587
• InChiKey: YRVBJWCQIAOZEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2907299090

反应信息

• 作为产物：
  描述：

  叔-丁基对甲酚 、 异丁醛 在 盐酸 、 溶剂黄146 作用下， 生成 2,2'-(2-甲基丙亚基)二[6-叔丁基-4-甲基-苯酚
  参考文献：
  名称：

  Bis (hydroxyphenyl) alkanes

  摘要：

  公开号：

  US02515907A1

文献信息

• Process for producing phosphite
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20040225145A1

  公开（公告）日：2004-11-11

  There is provided a process for producing a phosphite of the formula (I): 1 wherein R 1 , R 2 , R 4 and R 5 each independently represent a hydrogen atom, a C1-8 alkyl group, a C5-8 cycloalkyl group, a C6-12 alkylcycloalkyl group, a C7-12 aralkyl group or a phenyl group or a phenyl group substituted with an alkyl or an alkoxy group; R 3 represents a hydrogen atom or a C1-8 alkyl group; A represents a C2-8 alkylene group or a *—C(═O)— or *—C(═O)—R 7 — group in which R 7 represents a C1-8 alkylene group, and the bond marked with* is the bond connected with the oxygen atom; and one of Y and Z represents a hydroxyl group, a C1-8 alkoxy group or a C7-12 aralkyloxy group and the other one represents a hydrogen atom or a C1-8 alkyl group.

  提供了一种制备式(I)磷酸酯的方法，其中R1、R2、R4和R5各自独立地表示氢原子、C1-8烷基、C5-8环烷基、C6-12烷基环烷基、C7-12芳基烷基或苯基或被烷基或烷氧基取代的苯基；R3表示氢原子或C1-8烷基；A表示C2-8烷基或*—C(═O)—或*—C(═O)—R7—，其中R7表示C1-8烷基，标记为*的键连接着氧原子；Y和Z中的一个表示羟基、C1-8烷氧基或C7-12芳基烷氧基，另一个表示氢原子或C1-8烷基。
• Phosphites, process for producing the same and their use
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0823435A2

  公开（公告）日：1998-02-11

  A phosphite of formula (I): wherein R1, R2, R4 and R5 represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkylcycloalkyl group, an aralkyl group or a phenyl group; R3 represents hydrogen atom or an alkyl group; X represents a direct bond, sulfur atom, or a -CHR6- group in which R6 represents hydrogen atom, an alkyl group or a cycloalkyl group; A represents an alkylene group having 2 to 8 carbon atoms or a *-COR7-group in which R7 represents a direct bond or an alkylene group, and * indicates the bond to the oxygen; and one of Y and Z represents a hydroxyl group, an alkoxy group or an aralkyloxy group and the other one represents hydrogen atom or an alkyl group, is suitably used as a stabilizer for an organic material.

  式(I)的亚磷酸酯： 其中 R1、R2、R4 和 R5 代表氢原子、烷基、环烷基、烷基环烷基、芳基或苯基；R3 代表氢原子或烷基；X 代表直接键、硫原子或-CHR6-基团，其中 R6 代表氢原子、烷基或环烷基；A 代表具有 2 至 8 个碳原子的亚烷基或 *-COR7- 基团，其中 R7 代表直接键或亚烷基，* 表示与氧的键合；Y 和 Z 中的一个代表羟基、烷氧基或芳氧基，另一个代表氢原子或烷基。
• Intrusion resistant safety glazings and solar cell modules
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1938964A1

  公开（公告）日：2008-07-02

  Described certain plasticized poly(vinyl butyral) (PVB) interlayer sheets that may be used to produce safety glass and solar cell laminates having enhanced penetration resistance and adequate adhesion levels. In particular, the stress value of these interlayer sheets at an elongation of 120% is preferably in the range of from about 8 to about 15 N/mm2.

  描述了某些塑化聚乙烯醇缩丁醛（PVB）中间膜片，可用于生产安全玻璃和太阳能电池层压板，具有更强的抗穿透性和足够的粘合力。特别是，这些中间膜在伸长率为 120% 时的应力值最好在约 8 到约 15 牛/平方毫米的范围内。
• ORGANIC SEMICONDUCTOR COMPOSITION, ORGANIC THIN FILM TRANSISTOR, ELECTRONIC PAPER, AND DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：EP3203540A1

  公开（公告）日：2017-08-09

  The present invention provides an organic semiconductor composition which makes it possible to prepare an organic thin film transistor having excellent insulation reliability while inhibiting the deterioration of mobility, and to provide an organic thin film transistor prepared using the composition. Furthermore, the present invention provides electronic paper and a display device which contain the organic thin film transistor. The organic semiconductor composition according to the present invention contains an organic semiconductor material and at least one kind of migration inhibitor selected from a compound represented by the following Formula (I), a compound represented by the following Formula (II), and a compound represented by the following Formula (III).

  本发明提供了一种有机半导体组合物，该组合物可制备出绝缘可靠性极佳的有机薄膜晶体管，同时可抑制迁移率劣化，本发明还提供了使用该组合物制备的有机薄膜晶体管。此外，本发明还提供了含有该有机薄膜晶体管的电子纸和显示装置。根据本发明的有机半导体组合物含有一种有机半导体材料和至少一种从下式（I）代表的化合物、下式（II）代表的化合物和下式（III）代表的化合物中选出的迁移抑制剂。
• Phosphorous ester compound, process for producing the same, and use thereof
  申请人：Higo Mutsuko

  公开号：US20050247913A1

  公开（公告）日：2005-11-10

  A phosphorous ester compound of formula (I): wherein R 1 and R 2 independently represent hydrogen, C 1-8 alkyl, C 5-8 cycloalkyl, C 6-12 alkylcycloalkyl, C 7-12 aralkyl or phenyl, R 3 represents hydrogen or C 1-8 alkyl, R 4 , R 5 , R 6 and R 7 independently represent hydrogen, C 1-8 alkyl, C 5-8 cycloalkyl, C 6-12 alkylcycloalkyl, C 7-12 aralkyl, phenyl, C 1-8 alkoxy, or halogen, provided that four R 1 groups are the same or different, four R 2 groups are the same or different, two R 4 groups are the same or different, two R 5 groups are the same or different, two R 6 groups are the same or different, and two R 7 groups are the same or different, X represents a single bond, sulfur, or —CHR 8 —, wherein R 8 represents hydrogen, C 1-8 alkyl, or C 5-8 cycloalkyl, A represents a single bond, oxygen, etc.

  式(I)的磷酯化合物： 其中 R 1 和 R 2 分别代表氢、C 1-8 烷基 5-8 环烷基 6-12 烷基环烷基，C 7-12 芳基或苯基、 R 3 代表氢或 C 1-8 烷基、 R 4 , R 5 , R 6 和 R 7 分别代表氢、C 1-8 烷基 5-8 环烷基 6-12 烷基环烷基，C 7-12 芳基、苯基、C 1-8 烷氧基或卤素、 条件是四个 R 1 基团相同或不同，四个 R 2 基团相同或不同，两个 R 4 基团相同或不同，两个 R 5 基团相同或不同，两个 R 6 基团相同或不同，两个 R 7 基团相同或不同、 X 代表单键、硫或 -CHR 8 -，其中 R 8 代表氢、C 1-8 烷基，或 C 5-8 环烷基，A 代表单键、氧等。