2,3,5,6-四氯苯-1,4-二硫醇 | 67341-48-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 中文名称: 2,3,5,6-四氯苯-1,4-二硫醇
• 英文名称: tetrachlorobenzenedithiol
• 英文别名: Tetrachlor-1,4-benzodithiol；2,3,5,6-Tetrachlorobenzene-1,4-dithiol
• CAS: 67341-48-4
• 化学式: C₆H₂Cl₄S₂
• 分子量: 280.026
• InChiKey: WLBKDFVKXREIHQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,3,5,6-四氯苯-1,4-二硫醇 、 1-溴-2-氯乙烷 在 氢氧化钾 作用下， 以 二甲基亚砜 、 甲苯 为溶剂， 反应 18.0h， 以59%的产率得到1,2,4,5-tetrachloro-3,6-bis-(2-chloro-ethylsulfanyl)-benzene
  参考文献：
  名称：

  Low loss high refractive index vinyl sulfide compounds and method of making same

  摘要：

  该发明涉及一般式A(—S—CH═CH2)z的芳香基硫化乙烯化合物，其中z在1-4范围内，A代表高度卤化和高度卤化-氘代的苯、联苯和萘化合物；高度卤化和高度卤化-氘代的联苯醚和硫醚；以及含有碳和来自氮、氧和硫组成的杂原子中至少一个的高度卤化和高度卤化-氘代的不饱和5-和6-成员杂环系统。该发明的芳香基硫化乙烯化合物可用于制备适用于光通信的元件和器件。

  公开号：

  US20040044251A1
• 作为产物：
  描述：

  Dimethyl-thiocarbamic acid S-(2,3,5,6-tetrachloro-4-dimethylcarbamoylsulfanyl-phenyl) ester 、 氢氧化钾 、 盐酸 以72%的产率得到
  参考文献：
  名称：

  RAASCH M. S., J. ORG. CHEM., 1979, 44, NO 15, 2629-2632

  摘要：

  DOI：

文献信息

• Mercaptofunctional high uB EO chromophores and high tg, low optical loss, covalently bonded, high uB EO chromophore containing polymers and methods of synthesizing EO materials
  申请人：Corning Incorporated

  公开号：EP2450355A1

  公开（公告）日：2012-05-09

  The present invention relates generally to mercaptofunctional high µβ EO chromophores and EO polymers, and particularly to mercaptofunctional high µβ EO chromophores and EO polymers useful for making electro-optical devices and systems. Mercaptofunctional high µβ EO chromophores are covalently bonded to poly(imido sulfide) polymers producing high Tg, low optical loss, covalently bonded, high µβ EO chromophore containing polymers. Methods of synthesizing these EO materials using mild polymerization conditions are also described.

  本发明一般涉及巯基官能团高µβ环氧乙烷发色团和环氧乙烷聚合物，特别是用于制造电光器件和系统的巯基官能团高µβ环氧乙烷发色团和环氧乙烷聚合物。巯基官能团高µβ环氧乙烷发色团与聚（亚氨基硫醚）聚合物共价键合，产生高Tg、低光学损耗、共价键合的高µβ环氧乙烷发色团聚合物。此外，还介绍了使用温和聚合条件合成这些环氧乙烷材料的方法。
• PROCESS FOR THE PREPARATION OF AROMATIC SULFUR COMPOUNDS
  申请人：Nippon Finechemical Co., Ltd.

  公开号：EP1044965B1

  公开（公告）日：2003-10-01
• MERCAPTOFUNCTIONAL HIGH "MU-BETA" EO CHROMOPHORES AND HIGH TG, LOW OPTICAL LOSS, COVALENTLY BONDED, POLYMERS CONTAINING SAID CHROMOPHORES AND METHODS OF SYNTHESIZING EO MATERIALS
  申请人：Corning Incorporated

  公开号：EP2021332B1

  公开（公告）日：2012-10-03
• Mercaptofunctional high mubeta EO chromophores and high Tg, low optical loss, covalently bonded, high mubeta EO chromophore containing polymers and methods of synthesizing EO materials
  申请人：He Mingqian

  公开号：US20070257237A1

  公开（公告）日：2007-11-08

  The present invention relates generally to mercaptofunctional high μβ EO chromophores and EO polymers, and particularly to mercaptofunctional high μβ EO chromophores and EO polymers useful for making electro-optical devices and systems. Mercaptofunctional high μβ EO chromophores are covalently bonded to poly(imido sulfide) polymers producing high Tg, low optical loss, covalently bonded, high μβ EO chromophore containing polymers. Methods of synthesizing these EO materials using mild polymerization conditions are also described.
• Aromatic Organosulfur Functionalized 1,4-cis Polybutadiene
  申请人：Kwag Gwang Hoon

  公开号：US20090156751A1

  公开（公告）日：2009-06-18

  The present invention relates to a preparation method of aromatic organosulfur functionalized 1,4-cis polybutadiene comprising: polymerizing 1,3-butadiene or butadiene derivative in the presence of a specific catalyst in a nonpolar solvent to prepare 1,4-cis polybutadiene; and reacting the resultant polybutadiene with an aromatic organosulfur compound. Such prepared aromatic organosulfur functionalized 1,4-cis polybutadiene is without ultrahigh molecular weight region and, thus, has narrow molecular weight distribution.