2,3,5-三氯-4-丙基磺酰基吡啶 | 38827-35-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 2,3,5-三氯-4-丙基磺酰基吡啶
• 英文名称: 2,3,5-Trichloro-4-(n-propylsulfonyl)-pyridine
• 英文别名: 2,3,5-Trichloro-4-(propylsulfonyl)pyridine；2,3,5-trichloro-4-propylsulfonylpyridine
• CAS: 38827-35-9
• 化学式: C₈H₈Cl₃NO₂S
• 分子量: 288.582
• InChiKey: HKOMCMOYGRBTIP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  55.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  aqueous hypochlorite 、 3,5,6-三氯-4-(丙硫基)-2-吡啶酮腙 生成 2,3,5-三氯-4-丙基磺酰基吡啶
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• A molded antimicrobial article and a process for its production
  申请人：TORAY INDUSTRIES, INC.

  公开号：EP0952248A2

  公开（公告）日：1999-10-27

  A molded antimicrobial article comprises an infiltrated antimicrobial agent which forms independent phases of 0.01 µm or more in shorter diameter in the molded article. It is preferable that the antimicrobial agent is a pyridine based antimicrobial agent with a molecular weight of 200 to 700 and an inorganic property/organic property value of 0.3 to 1, and that 50% or more of the antimicrobial agent is infiltrated in a depth range of 0.5, preferably, 1 µm or more from the surface of the molded article, or that 30% or more of the antimicrobial agent is infiltrated in a depth range of 2 µm or more from the surface of the molded article. It is also preferable that the molded article is fibers, that the surface area used per 1 g of fibers is 0.1 m2 or more, and that the synthetic fibers are a colored antimicrobial fibrous product. The molded antimicrobial article of the present invention can be obtained, for example, by immersing a fibrous product in a dyeing liquid containing a pyridine based antimicrobial agent with a molecular weight of 200 to 700, an inorganic property/organic property value of 0.3 to 1.4 and an average particle size of 2 µm or less, and treating simultaneously with dyeing under pressurization, or by applying a liquid containing a pyridine based antimicrobial agent with a molecular weight of 200 to 700, an inorganic property/organic property value of 0.3 to 1.4 and an average particle size of 2 µm or less to a fibrous product by padding or spraying, and heat-treating it at 160 to 200°C in dry or wet state.

  一种模塑抗菌制品包括一种浸润抗菌剂，该抗菌剂在模塑制品中形成短直径为 0.01 微米或以上的独立相。抗菌剂最好是基于吡啶的抗菌剂，分子量在 200 到 700 之间，无机性质/有机性质值在 0.3 到 1 之间，50%或更多的抗菌剂浸润在距离模塑制品表面 0.5 微米（最好是 1 微米）或更大的深度范围内，或者 30%或更多的抗菌剂浸润在距离模塑制品表面 2 微米或更大的深度范围内。此外，成型品最好是纤维，每 1 克纤维使用的表面积为 0.1 平方米或以上，合成纤维最好是有色抗菌纤维制品。 本发明的模塑抗菌制品可通过将纤维制品浸入含有吡啶类抗菌剂的染色液中获得，吡啶类抗菌剂的分子量为 200 至 700，无机性质/有机性质值为 0.3 至 1.4 和平均粒径为 2 微米或更小的吡啶基抗菌剂的染色液中，并在加压下与染色同时进行处理，或通过轧制或喷涂将含有分子量为 200 至 700、无机物特性/有机物特性值为 0.3 至 1.4 和平均粒径为 2 微米或更小的吡啶基抗菌剂的液体涂抹到纤维制品上，并在 160 至 200°C 的干燥或湿润状态下进行热处理。
• ANTIBACTERIAL COMPOSITION, ANTIBACTERIAL MOLDING, SOLUTION CONTAINING ANTIBACTERIAL COMPOSITION, DETERGENT, SURFACE OF TATAMI MAT AND TATAMI MAT
  申请人：Idemitsu Technofine Co. Ltd

  公开号：EP1779727A1

  公开（公告）日：2007-05-02

  An antibacterial composition containing an organic antibacterial agent and an inorganic antibacterial agent is provided. Zirconium phosphate having supported thereon silver or copper or a salt thereof may be used as the inorganic antibacterial agent, and 2-mercaptopyridine-N-oxide sodium, carbendazim (methyl 1H-2-benzimidazole carbamate), or thiabendazole (2-(4-thiazolyl)-1H-benzimidazole) may be used as the organic antibacterial agent. Those components contain no halogen, so the antibacterial composition can be made halogen-free. The antibacterial composition may be applied to form an antibacterial molding, for example, by molding it together with a resin material or applying it together with a coating agent on a resin molding.

  提供了一种含有有机抗菌剂和无机抗菌剂的抗菌组合物。无机抗菌剂可使用磷化锆，磷化锆上支持银或铜或其盐，有机抗菌剂可使用 2-巯基吡啶-N-氧化钠、多菌灵（1H-2-苯并咪唑氨基甲酸甲酯）或噻菌灵（2-(4-噻唑基)-1H-苯并咪唑）。这些成分不含卤素，因此可以制成无卤抗菌组合物。抗菌组合物可用于形成抗菌模塑件，例如与树脂材料一起模塑或与涂层剂一起涂抹在树脂模塑件上。
• AGENT FOR IMPARTING ANTI-BACTERIAL/ANTI-FUNGAL PROPERTIES, FIBER PROCESSING AGENT, AND PRODUCTION METHOD FOR ANTI-BACTERIAL/ANTI-FUNGAL FIBER
  申请人：Osaka Kasei Co., Ltd.

  公开号：EP2769620A1

  公开（公告）日：2014-08-27

  An object of the present invention is to make it possible that a pyridine antibacterial/antifungal agent is dispersed stably in a liquid for appropriate impartation of the pyridine antibacterial/antifungal agent to fibers, and that when fibers are processed with the agent which is mixed with various other treating agents such as dyes and softeners, there is no negative influences on the process of the fibers for imparting antibacterial/antifungal properties. An antibacterial/antifungal properties-imparting agent contains a pyridine antibacterial/antifungal agent; a modified polysaccharide having reduced hydroxyl groups; and a wetting agent; but does not contain a surfactant. After applying the antibacterial/antifungal properties-imparting agent to fibers, the fibers undergo a heating process.

  本发明的目的是使吡啶抗菌/抗真菌剂能稳定地分散在液体中，以适当地将吡啶抗菌/抗真菌剂赋予纤维，并且当纤维与混合了各种其他处理剂（如染料和柔软剂）的药剂一起加工时，不会对纤维赋予抗菌/抗真菌特性的过程产生负面影响。一种抗菌/抗真菌剂含有吡啶抗菌/抗真菌剂、具有还原羟基的改性多糖和润湿剂，但不含表面活性剂。在纤维上涂抹抗菌/抗真菌性能诱导剂后，对纤维进行加热处理。
• STAINPROOF FIBER STRUCTURE
  申请人：Toray Industries, Inc.

  公开号：EP3321418A1

  公开（公告）日：2018-05-16

  A soil resistant fiber structure, including a fiber and a soil resistant resin fixed to at least a part of a surface of the fiber, wherein the resin has, in at least a part inside the resin, one or more regions dyed with osmium oxide as observed with a transmission electron microscope, at least one of the regions is circular, the regions have a maximum diameter of 100 nm or more and 500 nm or less, and the soil resistant fiber structure has a mass concentration ratio of oxygen atoms to fluorine atoms (O/F) of 3 or more as obtained by measuring the surface of the fiber with an energy dispersive X-ray analyzer. The present invention provides a fiber structure having high anti-adhesion property against aqueous soils and oily soils as well as soil release property by washing.

  一种耐土纤维结构，包括纤维和固定在纤维表面至少一部分的耐土树脂，其中树脂内部至少一部分有一个或多个用透射电子显微镜观察到的氧化锇染色的区域，其中至少一个区域是圆形的、这些区域的最大直径大于或等于 100 纳米，小于或等于 500 纳米，通过使用能量色散 X 射线分析仪测量纤维的表面，耐土纤维结构的氧原子与氟原子的质量浓度比（O/F）大于或等于 3。本发明提供的纤维结构对水性土壤和油性土壤具有较高的抗粘附性，并具有通过水洗释放土壤的特性。
• MOLDED ANTIMICROBIAL ARTICLE AND A PRODUCTION PROCESS THEREOF
  申请人：——

  公开号：US20020018794A1

  公开（公告）日：2002-02-14

  The invention relates to a molded antimicrobial article including an infiltrated antimicrobial agent which forms independent phases of 0.01 &mgr;m or more in short diameter in the molded article. The antimicrobial agent is a pyridine based antimicrobial agent with a molecular weight of 200 to 700 and an inorganic property/organic property value of 0.3 to 1, and 50% or more of the antimicrobial agent is infiltrated in a depth range of 0.5 &mgr;m or more from the surface of the molded article, or that 30% or more of the antimicrobial agent is infiltrated in a depth range of 2 &mgr;m or more from the surface of the molded article. The molded antimicrobial article of the invention can be obtained by immersing a fibrous product in a dyeing liquid containing the pyridine based antimicrobial agent, and treating simultaneously with dye under pressurization, or by applying a liquid containing a pyridine based antimicrobial agent to a fibrous product by padding or spraying, and heat-treating it at 160 to 200° C. in a dry or wet state.

  本发明涉及一种模塑抗菌制品，包括一种渗入的抗菌剂，该抗菌剂在模塑制品中形成短直径为 0.01 &mgr;m 或更大的独立相。抗菌剂是一种吡啶类抗菌剂，其分子量为 200 至 700，无机性质/有机性质值为 0.3 至 1，50% 或更多的抗菌剂在距离模塑制品表面 0.5 &mgr;m 或更大的深度范围内浸润，或 30% 或更多的抗菌剂在距离模塑制品表面 2 &mgr;m 或更大的深度范围内浸润。将纤维制品浸入含有吡啶类抗菌剂的染色液中，同时在加压条件下进行染色处理，或将含有吡啶类抗菌剂的液体以轧制或喷涂的方式涂抹到纤维制品上，然后在 160 至 200 摄氏度的干燥或潮湿状态下进行热处理，即可获得本发明的模塑抗菌制品。