2,3-双(4-吡啶基)丁烷 | 655-47-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 2,3-双(4-吡啶基)丁烷
• 英文名称: 2,3-bis(4-pyridyl)butane
• 英文别名: 2,3-di(4-pyridyl) butane；4,4'-(1,2-dimethyl-ethane-1,2-diyl)-bis-pyridine；2,3-di-[4]pyridyl-butane；2,3-Di-[4]pyridyl-butan；2,3-Di-<4>pyridyl-butan；meso-2,3-Bis-(4-pyridyl)butan；2,3-Bis-(4-pyridyl)butane；4-(3-pyridin-4-ylbutan-2-yl)pyridine
• CAS: 655-47-0
• 化学式: C₁₄H₁₆N₂
• 分子量: 212.294
• InChiKey: XGJXWHRUXUVTKK-UHFFFAOYSA-N

物化性质

• 熔点：
  134.4-134.8 °C
• 沸点：
  324.4±22.0 °C(Predicted)
• 密度：
  1.041±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,3-双(4-吡啶基)丁烷 、 乙二醇双(4-羧苯基) 醚 在 copper(II) acetate monohydrate 作用下， 以 甲醇 、 乙腈 为溶剂， 反应 72.0h， 以30%的产率得到
  参考文献：
  名称：

  Theoretical Calculation and Experimental Analysis of Molecular Complementarity in Co-Crystal

  摘要：

  A crystallization technique and theoretical calculation were used in co-crystal L of two compounds with 2,3-bis(4-pyridyl)butane (A) and acceptable guest acid (1,2-bis(4-carboxy-phenoxy)ethane) (B). The study shows the crystallization technique to be viable and practical for co-crystal engineering and demonstrates the theoretical calculation may be importance not only of hydrogen bonding but also of geometric fit in co-crystal formation.

  DOI：

  10.1080/15533174.2012.750350
• 作为产物：
  描述：

  4-乙酰吡啶 在 盐酸 、 硫酸 、 溶剂黄146 、 异丙醇 、 铂 作用下， 生成 2,3-双(4-吡啶基)丁烷
  参考文献：
  名称：

  Amphenone Analogs. III. Pinacol-Pinacolone Type Rearrangement in the Pyridine Series¹

  摘要：

  DOI：

  10.1021/ja01524a050

文献信息

• Two new 1D coordination polymers: syntheses, structures and properties
  作者：J. Wu、F-M. Wang、J-Q. Liu、J-X. Chen、J-M. Wu、K-B. Li、Y. Wei、Q-L. Li

  DOI：10.4314/bcse.v28i3.11

  日期：——

  (bib)(H 2 O) 2 ] n ( 2 ) (bi = 4,4'-bis(2-methylimidazol-1-ylmethyl)biphenyl; L = 4-(2-(4-(methoxycarbonyl)phenoxy)ethoxy)benzoic acid and bib = 2,3-bis(4-pyridyl)butane), are synthesized and characterized. Both of 1 and 2 have 1D covalent chains, which show different conformally chain feature. 2D supremolecular rhombic and rectangle motifs are observed in 1 and 2 , respectively. The O–H···O and C–H···Cl

  两种新的配位聚合物，即[Zn（bi）（Cl）2] n（1）和[Cu（L）2（bib）（H 2 O）2] n（2）（bi = 4,4'-合成双（2-甲基咪唑-1-基甲基）联苯; L = 4-（2-（4-（甲氧基羰基）苯氧基）乙氧基）苯甲酸和bib = 2,3-双（4-吡啶基）丁烷）并合成表征。1和2都具有一维共价链，这些共价链显示出不同的共形链特征。在1和2中分别观察到2D超分子菱形和矩形图案。O–H··O和C–H···Cl氢键相互作用在促进结构模式的多样性方面起着重要作用。关键词：结构，超分子相互作用，发光牛。化学 Soc。埃塞俄比亚。2014，28（3），415-422。DOI：http：//dx.doi.org/10.4314/bcse.v28i3.11
• Different interpenetrated coordination polymers based on flexible dicarboxylate ligands: topological diversity and magnetism
  作者：Jian-Qiang Liu、Jian Wu、Yao-Yu Wang、Jian-Tao Lin、Hiroshi Sakiyama

  DOI：10.1039/c3ce42338g

  日期：——

  This work evidently indicates that the effect of the secondary ligands, molar ratios and geometric preferences of the metal centers are critical on the resulting entangled motifs.

  这项工作明显表明，次要配体的作用、摩尔比和金属中心的几何偏好对于形成纠缠的图案有着至关重要的影响。
• Wibaut; Arens, Recueil des Travaux Chimiques des Pays-Bas, 1941, vol. 60, p. 125,127, 133
  作者：Wibaut、Arens

  DOI：——

  日期：——
• ELEMENTAL SELENIUM REACTIONS WITH 4-ETHYLPYRIDINE
  作者：Edward Gleich、Zygmunt Warnke

  DOI：10.1080/10426509808035728

  日期：1998.9.1

  A reaction of elemental selenium with 4-ethylpyridine has been studied. The process was run in sealed ampuls, within 205 - 240 degreesC, under nitrogen. The reaction products were indentified by GC-MS and H-1 NMR. The following products have been identified: (4-pyridyl)hydroxymethyl ketone, (4-pyridyl)methyl ketone, (4-pyridyl)-hydroselenomethyl ketone, 2,3-di(4-pyridyl)butane, 1,3-di(4-pyridyl)butane, 1-(4-pyridyl)-1-[2-(4-ethyl)pyridyl]-ethane, 1-(4-pyridyl)-1-[2-(4-ethenyl)pyridyl]ethane.
• Two new entangled coordination polymers constructed by flexible coligands: Synthesis, magnetism, and gas absorption
  作者：Jian Wu、Jian-Qiang Liu、Jian-Tao Lin、Tie Wu、Xi-Ren Wu、Cai-Hua Zhou、Xiang-Yang Qin

  DOI：10.1016/j.ica.2013.05.015

  日期：2013.8

  Two isostructural metal organic polymers, namely [M(bce)(bib)]center dot solv}(n) (M = Co(II) and solv = CH3OH center dot H2O for 1; M = Ni(II) and solv = 0.5CH(3)OH center dot 0.25H(2)O for 2) (H(2)bce = 1,2-bis(4-carboxy-phenoxy)ethane and bib = 2,3-bis(4-pyridyl)butane), have been synthesized and characterized. The structures of the two compounds show 2D -> 2D parallel interpenetrated frameworks with polyrotaxane and polycatenane character. The magnetic behaviors of 1 and 2 indicate antiferromagnetic interactions within paddle-wheel units. Furthermore, the compound 1 exhibits relative high N-2 uptake adsorption capacity. (C) 2013 Elsevier B.V. All rights reserved.