2,4,6-三[4-(4-苯基苯基)苯基]-1,3,5-三嗪 | 754980-61-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,4,6-三[4-(4-苯基苯基)苯基]-1,3,5-三嗪
• 英文名称: 2,4,6-Tris-1,1',4',1''-terphenyl-4-yl-1,3,5-triazine
• 英文别名: 2,4,6-Tris[4-(4-phenylphenyl)phenyl]-1,3,5-triazine
• CAS: 754980-61-5
• 化学式: C₅₇H₃₉N₃
• 分子量: 765.957
• InChiKey: IOSKNGFAHYYCNX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.7
• 重原子数：
  60
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-联苯硼酸 、 2,4,6-三-(4-溴苯基)-[1,3,5]三嗪 在 palladium(II) catalyst (WO₉₉/47474) caesium carbonate 作用下， 以 水 、 甲苯 为溶剂， 反应 3.0h， 生成 2,4,6-三[4-(4-苯基苯基)苯基]-1,3,5-三嗪
  参考文献：
  名称：

  Electroluminescent device

  摘要：

  本文揭示了包含三嗪化合物的有机层的电致发光器件。这些三嗪化合物是适合用作蓝光发射、耐久且有机电致发光层的组成部分。这些电致发光器件可用于全彩显示面板，例如移动电话、电视和个人电脑屏幕中。

  公开号：

  US20060135766A1

文献信息

• TRIAZINES AS REACTION ACCELERATORS
  申请人：Scheurich Rene Peter

  公开号：US20130058879A1

  公开（公告）日：2013-03-07

  The invention relates to the use of at least one specific triazine or melamine and/or salt thereof as accelerator for a photoinduced reaction of 3-(4-tert-butylphenyl)-3-hydroxy-1-(4-methoxyphenyl)-propan-1-one, 1-(4-tert-butylphenyl)-3-hydroxy-3-(4-methoxyphenyl)-propan-1-one or a mixture of these compounds to give avobenzone. The invention furthermore relates to a composition comprising at least one specific triazine or melamine and to a method for the stabilisation of the UV absorption capacity of a composition by means of a mixture of at least one specific triazine or melamine together with 3-(4-tert-butylphenyl)-3-hydroxy-1-(4-methoxyphenyl)propan-1-one, 1-(4-tert-butylphenyl)-3-hydroxy-3-(4-methoxyphenyl)propan-1-one or a mixture of these compounds, particularly preferably together with 3-(4-tert-butylphenyl)-3-hydroxy-1-(4-methoxyphenyl)propan-1-one.

  本发明涉及使用至少一种特定的三嗪或三聚氰胺及/或其盐作为光致反应加速剂，用于将3-(4-叔丁基苯基)-3-羟基-1-(4-甲氧基苯基)-丙酮酸酯，1-(4-叔丁基苯基)-3-羟基-3-(4-甲氧基苯基)-丙酮酸酯或这些化合物的混合物转化为阿伏苯宗。本发明还涉及包含至少一种特定三嗪或三聚氰胺的组合物，以及通过将至少一种特定三嗪或三聚氰胺与3-(4-叔丁基苯基)-3-羟基-1-(4-甲氧基苯基)丙酮酸酯，1-(4-叔丁基苯基)-3-羟基-3-(4-甲氧基苯基)丙酮酸酯或这些化合物的混合物混合，特别是与3-(4-叔丁基苯基)-3-羟基-1-(4-甲氧基苯基)丙酮酸酯一起，稳定组合物的UV吸收能力的方法。
• UV ABSORBER FORMULATIONS
  申请人：Acker Stephanie

  公开号：US20100111884A1

  公开（公告）日：2010-05-06

  Disclosed is a UV filter composition comprising (a) an organic UV absorber of formula (1), wherein R 1 and R 2 , independently of one another, are C 3 -C 18 alkyl; C 2 -C 18 alkenyl; a radical of the formula —CH 2 —CH(OH)—CH 2 —O-T 1 ; or R 1 and R 2 are a radical of the formula (4a); R 7 is a direct bond; a straight-chain or branched C 1 -C 4 alkylene radical or a radical of the formula (I) or (II); R 8 , R 9 and R 10 , independently of one another, are C 1 -C 18 alkyl; C 1 -C 18 alkoxy or a radical of the formula (III); R 11 is C 1 -C 5 alkyl; m 1 is a number from 1 to 4; p 1 is 0; or a number from 1 to 5; A 1 is a radical of the formula (1b), (1c) or (1d); R 3 is hydrogen; C 1 -C 10 alkyl; —(CH 2 CHR 5 —O)n 1 -T 2 ; or —CH 2 —CH(—OH)—CH 2 —O-T 2 ; R 4 is hydrogen; M; C 1 -C 5 alkyl; or —(CH 2 )m 2 —O-T 3 ; R 5 is hydrogen; or methyl; T 1 , T 2 and T 3 independently from each other are hydrogen; or C 1 -C 18 alkyl; Q 1 is C 1 -C 18 alkyl, M is a metal cation; m 2 is 1 to 4; and n 1 is 1-16, (b) dimethyl capramide, (c) a cosmetically acceptable carrier; and water.

  本发明公开了一种紫外线过滤组合物，包括（a）式（1）的有机紫外线吸收剂，其中R1和R2独立地是C3-C18烷基；C2-C18烯基；式—CH2—CH（OH）—CH2—O-T1的基团；或者R1和R2是式（4a）的基团；R7是直链或支链C1-C4烷基、式（I）或（II）的基团；R8、R9和R10独立地是C1-C18烷基、C1-C18烷氧基或式（III）的基团；R11是C1-C5烷基；m1是1至4的数字；p1是0或1至5的数字；A1是式（1b）、（1c）或（1d）的基团；R3是氢、C1-C10烷基、式—（CH2CHR5—O）n1-T2或式—CH2—CH（—OH）—CH2—O-T2；R4是氢、M、C1-C5烷基或式—（CH2）m2—O-T3；R5是氢或甲基；T1、T2和T3互相独立地是氢或C1-C18烷基；Q1是C1-C18烷基，M是金属阳离子；m2是1至4的数字；n1是1-16，（b）二甲基辛酰胺，（c）化妆品可接受载体；和水。
• Ultraviolet ray absorbing composite powder
  申请人：Iwase Cosfa Co., Ltd.

  公开号：EP1782792A1

  公开（公告）日：2007-05-09

  An ultraviolet-absorbing composite powder comprising a plurality of composite powder particles, wherein the composite powder particle consists of an inorganic or organic core particle having an average particle diameter of 0.5-100µm, and a compound of formula (1): which is adsorbed to the surface of the core particle which is provided. The composite powder of the invention exhibits an excellent UV ray protecting property as well as smooth and comfortable texture, and is useful for manufacturing cosmetic products.

  一种紫外线吸收复合粉末，由多个复合粉末颗粒组成，其中复合粉末颗粒由平均颗粒直径为 0.5-100µm 的无机或有机核心颗粒和式 (1) 化合物组成： 它被吸附在所提供的核心颗粒表面。本发明的复合粉末具有优异的防紫外线性能和光滑舒适的质地，可用于制造化妆品。
• STABILIZATION OF COSMETIC COMPOSITIONS AGAINST PHOTODEGRADATION
  申请人：BASF SE

  公开号：EP3492144A1

  公开（公告）日：2019-06-05

  Disclosed is the use of UV absorbers selected from (a2) hydroxyphenyl triazines of formula in which R1, R2 and R3 independently of one another, are C1-C18alkyl; and (a3) benzotriazole derivatives of formula wherein R4 is a random statistical mixture of at least three isomeric branched secondary alkyl groups each having 8 to 30 carbon atoms and having the formula E1 is a straight-chain C1-C14alkyl; E2 is a straight-chain C4-C15alkyl; wherein the total number of carbon atoms in E1 plus E2 is from 7 to 29; and R5 is C1-C5alkyl; for stabilizing cosmetic compositions against photodegradation comprising (b)symmetrical triazine derivatives of formula wherein A is a radical of formula R6 and R10 independently from each other are hydrogen; C1-C18alkyl; or C6-C12aryl; R7, R8 and R9 independently from each other are hydrogen; or a radical of formula wherein, in formula (3a), at least one of the radicals R7, R8 and R9 are a radical of formula (3c); R11, R12, R13 and R14 independently from each other are hydrogen; hydroxy; halogen; C1-C18alkyl; C1-C18alkoxy; C6-C12aryl; biphenylyl; C6-C12aryloxy; C1-C18alkylthio; carboxy; -COOM; C1-C18-alkylcarboxyl; aminocarbonyl; mono- or di-C1-C18alkylamino; C1-C10acylamino; or -COOH; M is an alkali metal ion; x is 1 or 2; and y is a number from 2 to 10; and a UV-absorber selected from (c1) cinnamic acid derivatives; and (c2) dibenzoylmethane derivatives.

  所公开的紫外线吸收剂选自以下物质 (a2) 式中的羟苯基三嗪 其中 R1、R2 和 R3 相互独立地为 C1-C18 烷基；以及 (a3) 式中的苯并三唑衍生物 其中 R4 是至少三个异构支链仲烷基的无规统计混合物，每个烷基具有 8 至 30 个碳原子，其式为 E1 是直链 C1-C14 烷基； E2 是直链 C4-C15 烷基；其中 E1 加 E2 的碳原子总数为 7 至 29；以及 R5 是 C1-C5 烷基； 用于稳定化妆品组合物以防止光降解，包括 (b) 式中的对称三嗪衍生物 其中 A 是式中的基团 R6和R10各自独立地为氢、C1-C18烷基或C6-C12芳基； R7、R8 和 R9 相互独立地为氢；或式中的一个基团 其中，在式 (3a) 中，R7、R8 和 R9 中至少有一个是式 (3c) 的基； R11、R12、R13 和 R14 相互独立地为氢；羟基；卤素；C1-C18 烷基；C1-C18 烷氧基；C6-C12 芳基；联苯；C6-C12 芳氧基；C1-C18 烷硫基；羧基；-COOM；C1-C18-烷基羧基；氨基羰基；单-或二-C1-C18 烷基氨基；C1-C10 乙酰氨基；或 -COOH； M 是碱金属离子 x 是 1 或 2；以及 y 是 2 至 10 的数字； 紫外线吸收剂选自 (c1) 肉桂酸衍生物；和 (c2) 二苯甲酰甲烷衍生物。
• Solubilizing agents for UV filters in cosmetic formulations
  申请人：BASF SE

  公开号：US10219990B2

  公开（公告）日：2019-03-05

  The present invention relates to the use of the compounds (A) corresponding to formula wherein R1 is hydrogen; a linear or branched C1-C30 aliphatic hydrocarbon residue comprising 0, 1, 2 or 3 double bonds; R2 independently from each other are hydrogen; methyl; ethyl; —OH; —COOR4; —CH2—OH; and —CH2—COOR4; R4 is hydrogen; or a linear or branched C1-C30 aliphatic hydrocarbon residue comprising 0, 1, 2 or 3 double bonds; R3 independently from each other are hydrogen; methyl; ethyl; —OH; —COOR5; —CH2—OH; and —CH2—COOR5; R5 is hydrogen; or a linear or branched C1-C30 aliphatic hydrocarbon residue comprising 0, 1, 2 or 3 double bonds; n is at least 0.1 on average; m1 and m2 independently from each other are 0; or 1; with the proviso, that at least one of the radicals R1, R4 or R5 represent a linear or branched C1-C30 aliphatic hydrocarbon residue comprising 0, 1, 2 or 3 double bonds, as solubilizing agent for organic UV filters (B) selected from (B1) benzophenone derivatives; (B2) hydroxyphenyl triazine derivatives; and (B3) trianilino-s-triazine derivatives.

  本发明涉及与式（A）对应的化合物的用途 式中 R1 是氢；线性或支链 C1-C30 脂肪族烃残基，包含 0、1、2 或 3 个双键； R2 相互独立地为氢、甲基、乙基、-OH、-COOR4、-CH2-OH 和 -CH2-COOR4； R4 是氢；或由 0、1、2 或 3 个双键组成的直链或支链 C1-C30 脂肪族烃残基； R3 相互独立地为氢、甲基、乙基、-OH、-COOR5、-CH2-OH 和 -CH2-COOR5； R5 是氢；或由 0、1、2 或 3 个双键组成的直链或支链 C1-C30 脂肪族烃残基； n 平均至少为 0.1； m1 和 m2 相互独立地为 0；或 1； 但 R1、R4 或 R5 中至少有一个代表线性或支链 C1-C30 脂肪族烃残基，该残基包含 0、1、2 或 3 个双键、 作为有机紫外线过滤剂的增溶剂（B），选自 (B1) 二苯甲酮衍生物； (B2) 羟苯基三嗪衍生物；以及 (B3) 三苯胺-s-三嗪衍生物。