2,6-二烯丙基-4-甲基苯胺 | 1018853-60-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2,6-二烯丙基-4-甲基苯胺
• 英文名称: 2,6-diallyl-4-methylaniline
• 英文别名: 4-Methyl-2,6-bis(prop-2-enyl)aniline；4-methyl-2,6-bis(prop-2-enyl)aniline
• CAS: 1018853-60-5
• 化学式: C₁₃H₁₇N
• 分子量: 187.285
• InChiKey: OUXXUUOYJBNXEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2,6-二烯丙基-4-甲基苯胺 、 N-α-tert-butoxycarbonyl-4′-hydroxy-3′,5′-diiodo-D-phenylglycine 在 4-(4,6-二甲氧基三嗪-2-基)-4-甲基吗啉盐酸盐 作用下， 以 四氢呋喃 为溶剂， 以40%的产率得到tert-butyl N-[(1R)-1-(4-hydroxy-3,5-diiodophenyl)-2-[4-methyl-2,6-bis(prop-2-enyl)anilino]-2-oxoethyl]carbamate
  参考文献：
  名称：

  Stabilization of higher-order structure of poly(phenyleneethynylene)s by metathesis polymerization at the side chains

  摘要：

  Novel poly(m-phenyleneethynlene-p-phenyleneethynylene)s bearing polymerizable diene or norbornene groups were synthesized by the Sonogashira-Hagihara coupling polymerization of the corresponding D-hydroxyphenylglycine-derived diiodo monomers with p-diethynylbenzene. These polymers exhibited strong Cotton effects derived from a predominantly one-handed helical conformation in CHCl3 and tetrahydrofuran, but exhibited weak or no Cotton effects in N,N-dimethylformamide. The metathesis polymerization of the diene and norbornene moieties was performed at the side chains of the polymers under diluted conditions in the presence of a chain-transfer agent, if necessary. The reaction took place intramolecularly, which was confirmed by size exclusion chromatography (SEC) measurements. The polymers exhibited stronger Cotton effects even in polar media after the intramolecular crosslinking, which indicated stabilization of the predominantly one-handed helical structures. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2012.04.028
• 作为产物：
  描述：

  4-甲基-N,N-二烯丙基苯胺 在 三氟化硼乙醚 作用下， 以 xylene 为溶剂， 反应 0.03h， 以56%的产率得到2,6-二烯丙基-4-甲基苯胺
  参考文献：
  名称：

  Microwave-assisted aza-Cope rearrangement of N-allylanilines

  摘要：

  The aza-Cope rearrangement of N-allylanilines is described. The use of BF3 center dot OEt2 and microwave irradiation allows to run the transformation under mild conditions and in reaction times of minutes. (c) 2008 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2008.01.078

文献信息

• Microwave-assisted aza-Cope rearrangement of N-allylanilines
  作者：Israel González、Iria Bellas、Ana Souto、Ramón Rodríguez、Jacobo Cruces

  DOI：10.1016/j.tetlet.2008.01.078

  日期：2008.3

  The aza-Cope rearrangement of N-allylanilines is described. The use of BF3 center dot OEt2 and microwave irradiation allows to run the transformation under mild conditions and in reaction times of minutes. (c) 2008 Published by Elsevier Ltd.
• Stabilization of higher-order structure of poly(phenyleneethynylene)s by metathesis polymerization at the side chains
  作者：Akinobu Hashimoto、Hiromitsu Sogawa、Masashi Shiotsuki、Fumio Sanda

  DOI：10.1016/j.polymer.2012.04.028

  日期：2012.6

  Novel poly(m-phenyleneethynlene-p-phenyleneethynylene)s bearing polymerizable diene or norbornene groups were synthesized by the Sonogashira-Hagihara coupling polymerization of the corresponding D-hydroxyphenylglycine-derived diiodo monomers with p-diethynylbenzene. These polymers exhibited strong Cotton effects derived from a predominantly one-handed helical conformation in CHCl3 and tetrahydrofuran, but exhibited weak or no Cotton effects in N,N-dimethylformamide. The metathesis polymerization of the diene and norbornene moieties was performed at the side chains of the polymers under diluted conditions in the presence of a chain-transfer agent, if necessary. The reaction took place intramolecularly, which was confirmed by size exclusion chromatography (SEC) measurements. The polymers exhibited stronger Cotton effects even in polar media after the intramolecular crosslinking, which indicated stabilization of the predominantly one-handed helical structures. (c) 2012 Elsevier Ltd. All rights reserved.