2-(2-环己基苯氧基)乙醇 | 54852-66-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 2-(2-环己基苯氧基)乙醇
• 英文名称: 2-(2-cyclohexyl-phenoxy)-ethanol
• 英文别名: (2-Hydroxy-aethyl)-(2-cyclohexyl-phenyl)-aether；2-Hydroxy-1-(2-cyclohexyl-phenoxy)-aethan；2-(2-Cyclohexyl-phenoxy)-aethanol；2-(2-Cyclohexylphenoxy)ethanol
• CAS: 54852-66-3
• 化学式: C₁₄H₂₀O₂
• 分子量: 220.312
• InChiKey: ZOICHFKQGRWPTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 海关编码：
  2909499000

反应信息

• 作为反应物：
  描述：

  肉桂酸 、 2-(2-环己基苯氧基)乙醇 在 苯磺酸 、 苯 作用下， 生成 2-(2-cyclohexyl-phenoxy)-1-trans-cinnamoyloxy-ethane
  参考文献：
  名称：

  Aryloxy alkyl esters of cinnamic acid

  摘要：

  公开号：

  US02246974A1
• 作为产物：
  描述：

  环己酚 、 2-氯乙醇 在 sodium hydroxide 作用下， 生成 2-(2-环己基苯氧基)乙醇
  参考文献：
  名称：

  Hydroxy alkyl ethers of hydrogenated hydroxy diphenyl compounds

  摘要：

  公开号：

  US02130525A1

文献信息

• METHOD FOR PRODUCING FLUORENE DERIVATIVE
  申请人：Fujii Katsuhiro

  公开号：US20120029244A1

  公开（公告）日：2012-02-02

  A method for producing a fluorene derivative by reacting fluorenone with a phenol or a phenoxyalcohol in the presence of an acid catalyst includes: adding an alkali to an obtained reaction liquid containing a fluorene derivative; and concentrating a resultant mixture liquid without removing the alkali thus added and a reaction product of the alkali, thereby separating an unreacted phenol or unreacted phenoxyalcohol.

  一种制备芴衍生物的方法，通过在酸催化剂存在下将芴酮与苯酚或苯氧乙醇反应，包括以下步骤：向含有芴衍生物的反应液中加入碱；在不去除已添加的碱和碱的反应产物的情况下浓缩混合液，从而分离未反应的苯酚或未反应的苯氧乙醇。
• Process for the preparation of cyclohexanol
  申请人：——

  公开号：US20030018223A1

  公开（公告）日：2003-01-23

  A method for producing cyclohexanol by subjecting cyclohexene to a hydration reaction in the presence of water using a solid acid as a catalyst in which as a reaction solvent, there is used an organic solvent having a solubility in water at 25° C. of not higher than 5% by weight, a boiling point which is at least 20° C. higher than that of the cyclohexanol produced, a conversion rate of not more than 3% under the hydration reaction conditions, and a solvent effect index of not less than 1.5 which indicates the effect of making the distribution of cyclohexene into the aqueous phase predominate.

  一种生产环己醇的方法，通过在水存在下使用固体酸作为催化剂将环己烯进行水合反应，其中作为反应溶剂使用具有以下特征的有机溶剂：在25℃下其在水中的溶解度不超过5%重量，其沸点比所生产的环己醇高至少20℃，在水合反应条件下的转化率不超过3%，且溶剂效应指数不少于1.5，表明使环己烯分布到水相中的效果占优势。
• Process for producing aryloxyacetic acids
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1067108A2

  公开（公告）日：2001-01-10

  A process for producing an aryloxyacetic acid of formula (2): wherein m represents an integer of 1 or 2, n represents an integer from 0 to 4, Ar represents an aromatic hydrocarbon ring, and each R independently represents an alkyl group, a cycloalkyl group, an aryl group, an alkoxy group, a cycloalkoxy group, an aryloxy group, a halogen atom, an alkylcarbonyl group, an arylcarbonyl group, a carboxyl group or a nitro group, comprising the reaction of an oxygen-containing gas with an aryloxyethanol of formula (1):         (R)n-Ar(̵O-CH2-CH2-OH)m     (1) wherein m, n, Ar, and R are as defined above; using a catalyst comprising palladium and an indium compound and/or a copper compound, in an aqueous medium and in the presence of 0.5m or more equivalents of alkali per mole of the aryloxyethanol of formula (1); or using a platinum catalyst, in an aqueous medium and in the absence of alkali or in the presence of less than 0.5m equivalents of alkali per mole of the aryloxyethanol of formula (1).

  一种生产式(2)芳氧基乙酸的工艺： 其中 m 代表 1 或 2 的整数，n 代表 0 至 4 的整数，Ar 代表芳香烃环，每个 R 独立地代表烷基、环烷基、芳基、烷氧基、环烷氧基、芳氧基、卤原子、烷基羰基、芳基羰基、羧基或硝基、 包括含氧气体与式 (1) 的芳氧基乙醇反应： (R)n-Ar(̵O-CH2- -OH)m (1) 其中 m、n、Ar 和 R 如上定义； 在水介质中，在每摩尔式 (1) 芳氧基乙醇含有 0.5m 或更多当量碱的情况下，使用由钯和铟化合物和/或铜化合物组成的催化剂；或 在水介质中，在无碱或每摩尔式（1）的芳氧基乙醇存在少于 0.5m 当量碱的情况下，使用铂催化剂。
• PROCESS FOR THE PREPARATION OF CYCLOHEXANOL
  申请人：Asahi Kasei Kabushiki Kaisha

  公开号：EP1243572A1

  公开（公告）日：2002-09-25

  A method for producing cyclohexanol by subjecting cyclohexene to a hydration reaction in the presence of water using a solid acid as a catalyst in which as a reaction solvent, there is used an organic solvent having a solubility in water at 25°C of not higher than 5% by weight, a boiling point which is at least 20°C higher than that of the cyclohexanol produced, a conversion rate of not more than 3% under the hydration reaction conditions, and a solvent effect index of not less than 1.5 which indicates the effect of making the distribution of cyclohexene into the aqueous phase predominate.

  一种生产环己醇的方法，该方法使用固体酸作为催化剂，使环己烯在水的存在下进行水合反应，其中作为反应溶剂，使用的有机溶剂在 25℃时在水中的溶解度不高于 5%（按重量计），沸点至少比所生产的环己醇的沸点高 20℃，在水合反应条件下转化率不超过 3%，溶剂效应指数不低于 1.5（表示使环己烯主要分布在水相中的效应）。5，这表明环己烯主要分布在水相中。
• COMPOUND HAVING FLUORENE SKELETON, AND METHOD FOR MANUFACTURING SAME
  申请人：Teijin Limited

  公开号：EP3747856A1

  公开（公告）日：2020-12-09

  Provided are a novel compound having a fluorene skeleton, and a method for manufacturing the same, the compound having a low palladium content or other content of a specific metal or content of a specific compound in a raw material alcohol, and being excellent in hue or various characteristics (optical characteristics, heat resistance, moldability, and other characteristics) as a raw material or in a resin that uses the raw material. This compound is a mixture of compounds having a fluorene skeleton represented by formula (1) (in formula (1), the rings Z being (same or different) aromatic groups, R1 and R2 each independently representing a hydrogen atom, a halogen atom, or a C1-12 hydrocarbon group which may include an aromatic group, Ar1 and Ar2 representing C6-10 aromatic groups which may have a substituent, L1 and L2 representing alkylene groups, j and k each independently representing an integer of 0 or greater, and m and n each independently representing an integer of 0 to 5), the mixture of compounds having a fluorene skeleton being characterized in that the content of elemental palladium therein satisfies formula (2) ((2): 0 ≤ Pd ≤ 50 ppm), and among the mixture of compounds represented by formula (1), compounds comprising the integers m = 1-5 and n = 0 are included in a range of 0-5%.

  本发明提供了一种具有芴骨架的新型化合物及其制造方法，该化合物在原料酒精中的钯含量或其他特定金属含量或特定化合物含量较低，作为原料或在使用该原料的树脂中的色调或各种特性（光学特性、耐热性、成型性和其他特性）优良。该化合物是具有由式（1）表示的芴骨架的化合物混合物（在式（1）中，环 Z 是（相同或不同的）芳香基团，R1 和 R2 各自独立地代表氢原子、卤素原子或可包括芳香基团的 C1-12 碳氢基团，Ar1 和 Ar2 代表可具有取代基的 C6-10 芳香基团、L1和L2代表亚烷基，j和k各自独立地代表0或更大的整数，m和n各自独立地代表0至5的整数），具有芴骨架的化合物混合物的特征在于其中钯元素的含量满足式(2)（(2)：0≤钯≤50ppm)，在式(1)表示的化合物混合物中，包含整数m＝1-5和n＝0的化合物在0-5％的范围内。