2-(2-甲氧基羰基-6-硝基苯基)-3-硝基苯甲酸甲酯 | 803-54-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 2-(2-甲氧基羰基-6-硝基苯基)-3-硝基苯甲酸甲酯
• 英文名称: 1,1'-biphenyl-6,6'-dinitro-2,2'-dicarboxylic acid dimethyl ester
• 英文别名: dimethyl 2,2'-dinitrobiphenyl-6,6'-dicarboxylate；dimethyl 6,6'-dinitrobiphenyl-2,2'-dicarboxylate；6,6'-dinitro-diphenic acid dimethyl ester；6,6'-Dinitro-diphensaeure-dimethylester；2,2'-Dinitro-6,6'-dimethoxycarbonyl-biphenyl；6.6'-Dinitro-biphensaeure-dimethylester；Dimethyl 6,6'-dinitro[1,1'-biphenyl]-2,2'-dicarboxylate；methyl 2-(2-methoxycarbonyl-6-nitrophenyl)-3-nitrobenzoate
• CAS: 803-54-3；803-55-4；67992-16-9
• 化学式: C₁₆H₁₂N₂O₈
• 分子量: 360.28
• InChiKey: VWKXXMPVBIQLRJ-UHFFFAOYSA-N

物化性质

• 沸点：
  535.1±50.0 °C(Predicted)
• 密度：
  1.417±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  144
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2-(2-甲氧基羰基-6-硝基苯基)-3-硝基苯甲酸甲酯 在 水 、 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 2.0h， 以86%的产率得到6,6'-二硝基联苯-2,2'-二甲酸
  参考文献：
  名称：

  Organic electroluminescent device

  摘要：

  本发明涉及电子器件，特别是有机电致发光器件，包括式(1)的化合物，以及相应的化合物，以及制备这些化合物的方法。

  公开号：

  US09337430B2
• 作为产物：
  描述：

  2-溴-3-硝基苯甲酸甲酯 在 铜 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 以81.5%的产率得到2-(2-甲氧基羰基-6-硝基苯基)-3-硝基苯甲酸甲酯
  参考文献：
  名称：

  Organic electroluminescent device

  摘要：

  本发明涉及电子器件，特别是有机电致发光器件，包括式(1)的化合物，以及相应的化合物，以及制备这些化合物的方法。

  公开号：

  US09337430B2

文献信息

• Preparation of (R)-(-)-6,6'-Bis(3,5-dinitrobenzamido)biphenyl-2,2'-dicarboxylic Acid, a Potential Chiral HPLC Selector
  作者：Miloš Tichý、Jiří Závada

  DOI：10.1135/cccc19952161

  日期：——

  The title optically active diacid I has been prepared as a potential selector for chiral stationary phase in the HPLC separation of enantiomers.

  具有光学活性的二元酸已被制备为HPLC对映体分离中的手性固定相的潜在选择器。

• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：Merck Patent GmbH

  公开号：US20140249308A1

  公开（公告）日：2014-09-04

  The present invention relates to electronic devices, in particular organic electroluminescent devices, comprising compounds of the formula (1), to the corresponding compounds, and to a process for the preparation of these compounds.

  本发明涉及电子设备，特别是有机电致发光器件，包括式（1）的化合物，对应的化合物以及制备这些化合物的方法。
• Kenner; Stubbings, Journal of the Chemical Society, 1921, vol. 119, p. 599
  作者：Kenner、Stubbings

  DOI：——

  日期：——
• Kuhn; Albrecht, Justus Liebigs Annalen der Chemie, 1927, vol. 455, p. 281
  作者：Kuhn、Albrecht

  DOI：——

  日期：——
• Restoration of riparian habitat using experimental flooding
  作者：Matthew D. Sprenger、Loren M. Smith、John P. Taylor

  DOI：10.1672/0277-5212(2002)022[0049:rorhue]2.0.co;2

  日期：2002.3

  We evaluated treatments designed to remove saltcedar (Tamarix ramosissima) monocultures from riparian habitats using root plows (mechanical treatment) and aerial applications of the herbicide imazapyr (chemical treatment) within twelve 4-ha impoundments in the Middle Rio Grande Valley in central New Mexico, USA. Following these treatments, impoundments were flooded and water levels were reduced to stimulate native species re-establishment from seed. Water manipulations within saltcedar-removal areas consisted of stage drawdowns of 5 cm/day and 10 cm/day. Mechanically cleared areas had fewer saltcedar resprouts (26 resprouts/ha) than chemically treated areas (2,500 resprouts/ha). Saltcedar and cottonwood (Populus deltoides subsp. wislizinii) seedling density and cottonwood survival were greater in mechanically treated areas than in chemically treated areas. This effect is attributed to soil disturbance resulting from root plowing. Cottonwood seedling density and survival did not differ between 5 cm/day and 10 cm/day stage drawdowns and decreased throughout summer as a result of excessive moisture stress. The absence of a drawdown treatment effect indicates that both drawdowns were too fast for seedling roots to keep up with declining water tables. Seedlings that survived were using moisture from the unsaturated zone.