aluminium monobromoacetate | 98611-11-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: aluminium monobromoacetate
• 英文别名: aluminium (CH2Br-acetate)3；Aluminum;2-bromoacetate
• CAS: 98611-11-1
• 化学式: C₆H₆AlBr₃O₆
• 分子量: 440.804
• InChiKey: WQBANUQNTDBLSR-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  0.79
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  78.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  aluminium monobromoacetate 、 三乙胺 以 苯 为溶剂， 以68%的产率得到aluminium monobromoacetate*Et3N
  参考文献：
  名称：

  SYNTHESES AND CHARACTERIZATION OF ALUMINIUM(III), IRON(III), AND COPPER(II) MONOBROMOACETATES AND THEIR COMPLEXES WITH ORGANIC BASES

  摘要：

  Bromoacetates of the compositions AI(OOCCH2Br)(3), AlBr(OOCCH2Br)(2), FeCl(OOCCH2Br)(2), FeCl2(OOCCH2Br) and Cu(OOCCH2Br)(2) and M(OOCCH2Br)(3).B, M(OOCCH2Br)(2).2B, MBr(OOCCH2Br)(2).B, MCl(OOCCH2Br)(2).2B, MCl2(OOCCH2Br).B. (M=Al(III), Fe(III), Cu(II) and B = C5H5N, (C2H5)(2)NH, (C2H5)(3)N and NH2C6H4F have been synthesized and characterized on the basis of elemental analyses, infrared, reflectance, NMR spectral and magnetic susceptibility studies.

  DOI：

  10.1081/sim-100105262
• 作为产物：
  描述：

  溴代乙酸酐 、 aluminum oxide 以 四氯化碳 为溶剂， 以86%的产率得到aluminium monobromoacetate
  参考文献：
  名称：

  SYNTHESES AND CHARACTERIZATION OF ALUMINIUM(III), IRON(III), AND COPPER(II) MONOBROMOACETATES AND THEIR COMPLEXES WITH ORGANIC BASES

  摘要：

  Bromoacetates of the compositions AI(OOCCH2Br)(3), AlBr(OOCCH2Br)(2), FeCl(OOCCH2Br)(2), FeCl2(OOCCH2Br) and Cu(OOCCH2Br)(2) and M(OOCCH2Br)(3).B, M(OOCCH2Br)(2).2B, MBr(OOCCH2Br)(2).B, MCl(OOCCH2Br)(2).2B, MCl2(OOCCH2Br).B. (M=Al(III), Fe(III), Cu(II) and B = C5H5N, (C2H5)(2)NH, (C2H5)(3)N and NH2C6H4F have been synthesized and characterized on the basis of elemental analyses, infrared, reflectance, NMR spectral and magnetic susceptibility studies.

  DOI：

  10.1081/sim-100105262

文献信息

• Talele, G. G.; Bhattacharya, P. K.; Misra, S. N., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1989, vol. 28, # 9, p. 779 - 782
  作者：Talele, G. G.、Bhattacharya, P. K.、Misra, S. N.

  DOI：——

  日期：——
• TALELE, G. G.;BHATTACHARYA, P. K.;MISRA, S. N., INDIAN J. CHEM. A, 28,(1989) N, C. 779-782
  作者：TALELE, G. G.、BHATTACHARYA, P. K.、MISRA, S. N.

  DOI：——

  日期：——
• PURI, J. K.;VATS, V. K.;MANDAL, H.;MILLER, J. M., INORG. CHIM. ACTA, 1985, 97, N 2, 205-208
  作者：PURI, J. K.、VATS, V. K.、MANDAL, H.、MILLER, J. M.

  DOI：——

  日期：——
• SYNTHESES AND CHARACTERIZATION OF ALUMINIUM(III), IRON(III), AND COPPER(II) MONOBROMOACETATES AND THEIR COMPLEXES WITH ORGANIC BASES
  作者：J. K. Puri、V. K. Vats、Ashu Miglani

  DOI：10.1081/sim-100105262

  日期：2001.6.30

  Bromoacetates of the compositions AI(OOCCH2Br)(3), AlBr(OOCCH2Br)(2), FeCl(OOCCH2Br)(2), FeCl2(OOCCH2Br) and Cu(OOCCH2Br)(2) and M(OOCCH2Br)(3).B, M(OOCCH2Br)(2).2B, MBr(OOCCH2Br)(2).B, MCl(OOCCH2Br)(2).2B, MCl2(OOCCH2Br).B. (M=Al(III), Fe(III), Cu(II) and B = C5H5N, (C2H5)(2)NH, (C2H5)(3)N and NH2C6H4F have been synthesized and characterized on the basis of elemental analyses, infrared, reflectance, NMR spectral and magnetic susceptibility studies.