4-(4-cyanophenyl)-2,5-dimethylbenzene | 949115-08-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(4-cyanophenyl)-2,5-dimethylbenzene
• 英文别名: 2',5'-dimethylbiphenyl-4-carbonitrile；2',5'-dimethyl-[1,1'-biphenyl]-4-carbonitrile；4-(2,5-Dimethylphenyl)benzonitrile
• CAS: 949115-08-6
• 化学式: C₁₅H₁₃N
• 分子量: 207.275
• InChiKey: BGSDDOXYLAFUAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-(4-cyanophenyl)-2,5-dimethylbenzene 在 吡啶 、 sodium azide 、 氯化铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2-[3-(3,7-dimethyloctyloxy)phenyl]-5-[4-(2,5-dimethylphenyl)phenyl]-1,3,4-oxadiazole
  参考文献：
  名称：

  Synthesis and Characterization of a Light-Emitting Poly(p-phenylenevinylene)-Based Copolymer Containing 1,3,4-Oxadiazole Functionality

  摘要：

  A new class of high brightness and luminance efficiency of poly[2-{4-[5-(3-(3, 7-dimethyloctyloxy)phenyl)-1,3,4-oxadiazole-2-yl]phenyl}-1,4-phenylenevinylene] (C(10)PhOxa-PPV) was synthesized by Gilch polymerization. The weight average molecular weight (Mw) and the polydispersity of C(10)PhOxa-PPV were found to be 2.7 x 10(4) and 2.6, respectively. Double-layer light-emitting device with an ITO/ PEDOT/C(10)PhOxa-PPV/Al was fabricated and characterized. The maximum brightness, and luminance efficiency of C(10)PhOxa-PPV showed values of up to 8.3 cd/A and 4,426 cd/m(2), respectively.

  DOI：

  10.1080/15421400601010813
• 作为产物：
  描述：

  甲苄基溴 在 四(三苯基膦)钯 、 正丁基锂 、 碳酸氢钠 作用下， 以 四氢呋喃 、 乙二醇二甲醚 为溶剂， 生成 4-(4-cyanophenyl)-2,5-dimethylbenzene
  参考文献：
  名称：

  Synthesis and Characterization of a Light-Emitting Poly(p-phenylenevinylene)-Based Copolymer Containing 1,3,4-Oxadiazole Functionality

  摘要：

  A new class of high brightness and luminance efficiency of poly[2-{4-[5-(3-(3, 7-dimethyloctyloxy)phenyl)-1,3,4-oxadiazole-2-yl]phenyl}-1,4-phenylenevinylene] (C(10)PhOxa-PPV) was synthesized by Gilch polymerization. The weight average molecular weight (Mw) and the polydispersity of C(10)PhOxa-PPV were found to be 2.7 x 10(4) and 2.6, respectively. Double-layer light-emitting device with an ITO/ PEDOT/C(10)PhOxa-PPV/Al was fabricated and characterized. The maximum brightness, and luminance efficiency of C(10)PhOxa-PPV showed values of up to 8.3 cd/A and 4,426 cd/m(2), respectively.

  DOI：

  10.1080/15421400601010813

文献信息

• Nickel-catalysed Suzuki–Miyaura cross-coupling reactions of aryl halides with arylboronic acids in ionic liquids
  作者：Man Wang、Xiaobin Yuan、Hongyu Li、Limin Ren、Zhizhong Sun、Yanjun Hou、Wenyi Chu

  DOI：10.1016/j.catcom.2014.08.037

  日期：2015.1

  An efficient strategy for the nickel-catalysed synthesis of biaryls and terphenyls has been developed in environmentally-friendly reaction media. In the presence of β-diketone and PPh3 ligands, Ni(TFA)2 acted as an effective catalyst for the Suzuki–Miyaura cross-coupling of aryl halides and arylboronic acids in an ionic liquid solution. Biaryls and terphenyls were obtained in good yields under this

  在环境友好的反应介质中，已经开发了镍催化的联芳基和三联苯合成的有效策略。在存在β-二酮和PPh 3配体的情况下，Ni（TFA）2充当离子液体溶液中芳基卤化物和芳基硼​​酸的Suzuki-Miyaura交叉偶联的有效催化剂。在该催化体系下，以高收率获得了联芳基和三联苯。
• Switching between mono and doubly reduced odd alternant hydrocarbon: designing a redox catalyst
  作者：Jasimuddin Ahmed、Paramita Datta、Arpan Das、Stephy Jomy、Swadhin K. Mandal

  DOI：10.1039/d0sc05972b

  日期：——

  orbital (HMO) calculations in 1950, it has been well known that the odd alternant hydrocarbon (OAH), the phenalenyl (PLY) system, can exist in three redox states: closed shell cation (12π e−), mono-reduced open shell neutral radical (13π e−) and doubly reduced closed shell anion (14π e−). Switching from one redox state of PLY to another leads to a slight structural change owing to its low energy of disproportionation

  由于休克尔早期分子轨道（HMO）在1950年的计算中，已经公知的是奇数交替烃（OAH）时，非那烯基（PLY）系统中，可以在三个氧化还原状态存在：封闭壳体阳离子（12πë - ），单减小开壳中性自由基（13πë - ）和成倍减少封闭壳阴离子（14πë - ）。由于PLY的歧化能低，因此从PLY的一种氧化还原状态切换到另一种状态会导致轻微的结构变化，从而使电子添加或去除过程变得容易。迄今为止，已经广泛研究了单还原的基于PLY的自由基。然而，迄今为止还没有研究双还原的PLY物种的反应性和应用。在这项工作中，我们报告了双还原PLY物种（14πe- ）和其对氧化还原催化的开发应用程序通过与单-还原形式切换（13πë - ）对芳基卤化物的活化和过渡金属的分类的条件下的官能化没有任何外部刺激如热，光或阴极电流供给。
• METALLIC COMPOSITE AND COMPOSITION THEREOF
  申请人：Higashimura Hideyuki

  公开号：US20120032121A1

  公开（公告）日：2012-02-09

  A metallic composite in which a conjugated compound having a molecular weight of 200 or more is adsorbed to a metallic nanostructure having an aspect ratio of 1.5 or more, for example, a metallic composite in which a compound having a group represented by the formula (I) or a repeating unit represented by the formula (II) or both of them is adsorbed to a metallic nanostructure having an aspect ratio of 1.5 or more, is useful for electronic devices such as a light-emitting device, a solar cell and an organic transistor.

  一种金属复合材料，其中分子量为200或更高的共轭化合物被吸附到具有1.5或更高长宽比的金属纳米结构上，例如，一种金属复合材料，其中具有由式(I)表示的基团或由式(II)表示的重复单元或两者都被吸附到具有长宽比为1.5或更高的金属纳米结构上，对于光电器件如发光器件、太阳能电池和有机晶体管等是有用的。
• Palladium-Catalyzed Borylation of Aryl Chlorides: Scope, Applications, and Computational Studies
  作者：Kelvin L. Billingsley、Timothy E. Barder、Stephen L. Buchwald

  DOI：10.1002/anie.200701551

  日期：2007.7.9
• SILVER-(CONJUGATED COMPOUND) COMPOSITE
  申请人：Iijima Takayuki

  公开号：US20120168693A1

  公开（公告）日：2012-07-05

  A silver-(conjugated compound) composite comprising silver particles having a number-average Feret diameter of not more than 1,000 nm, and a conjugated compound having a weight-average molecular weight of not less than 3.0×10 2 adsorbed to the silver particles. The composite exhibits excellent conductivity and charge injection properties, and excellent dispersibility within non-polar solvents.