butylthioacetyl chloride | 7031-22-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: butylthioacetyl chloride
• 英文别名: butylsulfanyl-acetyl chloride；Me(CH2)3SCH2C(O)Cl；(n-Bu)SCH2C(O)Cl；S-Butyl-thioglykolsaeure-chlorid；Butylmercapto-acetylchlorid；S-Butyl-thioglykoloylchlorid；2-Butylsulfanylacetyl chloride
• CAS: 7031-22-3
• 化学式: C₆H₁₁ClOS
• 分子量: 166.672
• InChiKey: YYYRKPUFCONIOH-UHFFFAOYSA-N

物化性质

• 沸点：
  83-84 °C(Press: 8 Torr)
• 密度：
  1?+-.0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  9
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  42.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  butylthioacetyl chloride 在 potassium permanganate 、 溶剂黄146 作用下， 生成 N-[4-(butane-1-sulfonylmethyl)-thiazol-2-yl]-acetamide
  参考文献：
  名称：

  Yamamoto, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1953, vol. 73, p. 934,937

  摘要：

  DOI：
• 作为产物：
  描述：

  (丁基硫代)乙酸 在 三氯化磷 作用下， 生成 butylthioacetyl chloride
  参考文献：
  名称：

  Synthesis, spectral characterization, electrochemical properties and antimicrobial screening of sulfur containing acylferrocenes

  摘要：

  Several known and eight new sulfur containing acylferrocenes of the general formula FcCO(CH2)(n)SR (where Fc = ferrocenyl, n = 1 or 2 and R = alkyl, 4-bromobenzyl or 2,6-dichlorobenzyl group) were synthesized in order to test their in vitro antimicrobial activity against 11 bacterial and three fungal/yeast strains. It has been shown that only four of the 14 ketones are completely inactive at the tested dose, while the activities of the other ones were noteworthy. All new compounds were well characterized by IR and NMR spectral data, and their electrochemical properties were investigated by cyclic voltammetry. The X-ray crystal structures of two representative ketones are also presented. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.03.002

文献信息

• Immune-stimulating and cancerostatic 1-acyl-2-cyanoaziridines
  申请人：Boehringer Mannheim, GmbH

  公开号：US04267174A1

  公开（公告）日：1981-05-12

  1-Acyl-2-cyanoaziridines of the formula ##STR1## wherein R is an acyl radical of a carboxylic, sulphonic, sulphinic, sulphenic, phosphonic or phosphoric acid, exhibit immune-stimulating and cancerostatic activities.

  公式为##STR1##的1-酰基-2-氰基环氧丙烷，其中R是羧酸、磺酸、亚磺酸、亚硫酸、膦酸或磷酸的酰基基团，具有免疫刺激和抗癌活性。
• Mirskova, A. N.; Seredkina, S. G.; Voronkov, M. G., Journal of Organic Chemistry USSR (English Translation), 1985, vol. 21, # 12, p. 2291 - 2295
  作者：Mirskova, A. N.、Seredkina, S. G.、Voronkov, M. G.

  DOI：——

  日期：——
• Is Information Risk a Determinant of Asset Returns?
  作者：David Easley、Soeren Hvidkjaer、Maureen O'Hara

  DOI：10.1111/1540-6261.00493

  日期：2002.10

  ABSTRACTWe investigate the role of information‐based trading in affecting asset returns. We show in a rational expectation example how private information affects equilibrium asset returns. Using a market microstructure model, we derive a measure of the probability of information‐based trading, and we estimate this measure using data for individual NYSE‐listed stocks for 1983 to 1998. We then incorporate our estimates into a Fama and French (1992) asset‐pricing framework. Our main result is that information does affect asset prices. A difference of 10 percentage points in the probability of information‐based trading between two stocks leads to a difference in their expected returns of 2.5 percent per year.
• Zolotova,M.V.; Konstantinova,T.V., Journal of general chemistry of the USSR, 1970, vol. 40, p. 2113
  作者：Zolotova,M.V.、Konstantinova,T.V.

  DOI：——

  日期：——
• ITOH, TOSHIYUKI;TAKAGI, YUMIKO;NISHIYAMA, SHIGENORI, J. ORG. CHEM., 56,(1991) N, C. 1521-1524
  作者：ITOH, TOSHIYUKI、TAKAGI, YUMIKO、NISHIYAMA, SHIGENORI

  DOI：——

  日期：——