[1,1':4',1'':4",1'''-quaterphenyl]-4-amine | 25660-12-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1,1':4',1'':4",1'''-quaterphenyl]-4-amine
• 英文别名: 4-Amino-p-quaterphenyl；4-amino-1,1':4',1'':4'',1'''-quaterphenyl；4-[4-(4-phenylphenyl)phenyl]aniline
• CAS: 25660-12-2
• 化学式: C₂₄H₁₉N
• 分子量: 321.422
• InChiKey: WVMMWAWDYFKKCC-UHFFFAOYSA-N

物化性质

• 沸点：
  554.0±19.0 °C(Predicted)
• 密度：
  1.117±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [1,1':4',1'':4",1'''-quaterphenyl]-4-amine 、 N-(2-ethylhexyl)-1,7-(3',5'-di-t-butylphenoxy)perylene-3,4-dicarboxyanhydride-9,10-dicarboximide 在 zinc diacetate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 17.0h， 以40.6%的产率得到N,N-(2-ethylhexyl)-(quaterphenyl)-7-(3',5'-di-t-butylphenoxy)perylene-3,4:9,10-bis(dicarboximide)
  参考文献：
  名称：

  Making a Molecular Wire:  Charge and Spin Transport through para-Phenylene Oligomers

  摘要：

  Functional molecular wires are essential for the development of molecular electronics. Charge transport through molecules occurs primarily by means of two mechanisms, coherent superexchange and incoherent charge hopping. Rates of charge transport through molecules in which superexchange dominates decrease approximately exponentially with distance, which precludes using these molecules as effective molecular wires. In contrast, charge transport rates through molecules in which incoherent charge hopping prevails should display nearly distance independent, wirelike behavior. We are now able to determine how each mechanism contributes to the overall charge transport characteristics of a donor-bridge-acceptor (D-B-A) system, where D = phenothiazine (PTZ), B = p-oligophenylene, and A = perylene-3,4:9,10-bis(dicarboximide) (PDI), by measuring the interaction between two unpaired spins within the system's charge separated state via magnetic field effects on the yield of radical pair and triplet recombination product.

  DOI：

  10.1021/ja0398215
• 作为产物：
  描述：

  4-氨基苯硼酸频哪醇酯 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 甲苯 为溶剂， 反应 47.0h， 生成 [1,1':4',1'':4",1'''-quaterphenyl]-4-amine
  参考文献：
  名称：

  Making a Molecular Wire:  Charge and Spin Transport through para-Phenylene Oligomers

  摘要：

  Functional molecular wires are essential for the development of molecular electronics. Charge transport through molecules occurs primarily by means of two mechanisms, coherent superexchange and incoherent charge hopping. Rates of charge transport through molecules in which superexchange dominates decrease approximately exponentially with distance, which precludes using these molecules as effective molecular wires. In contrast, charge transport rates through molecules in which incoherent charge hopping prevails should display nearly distance independent, wirelike behavior. We are now able to determine how each mechanism contributes to the overall charge transport characteristics of a donor-bridge-acceptor (D-B-A) system, where D = phenothiazine (PTZ), B = p-oligophenylene, and A = perylene-3,4:9,10-bis(dicarboximide) (PDI), by measuring the interaction between two unpaired spins within the system's charge separated state via magnetic field effects on the yield of radical pair and triplet recombination product.

  DOI：

  10.1021/ja0398215

文献信息

• Synthesis of Monofunctionalized p-Quaterphenyls
  作者：Arne Lützen、Ivonne Wallmann、Manuela Schiek、Rainer Koch

  DOI：10.1055/s-2008-1067163

  日期：2008.8

  Abstract: p -Oligophenyls have proven to be versatile buildingblocks for the generation of self-assembled nanoaggregates via va-por deposition on solid supports whose optical properties and mor-phologies can be influenced by the introduction of functionalgroups. Nonsymmetrically functionalized p , p ¢-disubstituted deriva-tives could even be demonstrated to form nanoaggregates that canact as frequency

  摘要： 对低聚苯已被证明是一种通用的结构单元，可通过气相沉积在固体载体上产生自组装纳米聚集体，其光学性质和形态会受到官能团的引入的影响。非对称功能化的 p , p ¢-二取代衍生物甚至可以被证明可以形成纳米聚集体，由于它们的非线性光学特性，可以作为倍频器。单功能化衍生物也可以预期类似的性质。因此，我们通过应用可靠的 Suzuki 交叉偶联策略开发了一种合成单官能化 1,1¢:4¢,1¢¢:4¢¢,1¢¢¢ - 四联苯 ( p -quaterphenines) 的通用方法. 关键词: 交叉偶联反应, 对低聚苯, 棒状分子,
• Nitration of p-quaterphenyl
  作者：M. L. Scheinbaum

  DOI：10.1039/c2969001235a

  日期：——

  Nitration of p-quaterphenyl with acetyl nitrate generated in situ affords 4-nitro- and 4,4′-dinitro-quarter-phenyl, no products of ortho- or meta-nitration of inner or outer rings being detected.

  的硝化p与所生成的硝酸乙酰酯-quaterphenyl原位得到4-硝基-和4,4'-二硝基四分之一苯基，无产品邻或-元被检测到内部或外部环的-nitration。
• 新型覆盖层用化合物以及包含上述覆盖层用化合物的有机发光元件
  申请人：东进世美肯株式会社

  公开号：CN113773317A

  公开（公告）日：2021-12-10

  本发明提供一种以下述化学式1表示的覆盖层用化合物以及包含上述覆盖层用化合物的有机发光元件。
• [EN] NITROGENOUS HETEROAROMATIC COMPOUNDS FOR ORGANIC ELECTROLUMINESCENT DEVICES<br/>[FR] COMPOSÉS HÉTÉROAROMATIQUES AZOTÉS POUR DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES<br/>[DE] STICKSTOFFHALTIGE HETEROAROMATEN FÜR ORGANISCHE ELEKTROLUMINESZENZVORRICHTUNGEN
  申请人：[de]MERCK PATENT GMBH

  公开号：WO2022129113A1

  公开（公告）日：2022-06-23

  Die vorliegende Erfindung betrifft stickstoffhaltige Heteroaromaten, die sich für die Verwendung in elektronischen Vorrichtungen eignen, sowie elektronische Vorrichtungen, insbesondere organischen Elektrolumineszenzvorrichtungen, enthaltend diese Verbindungen.
• [EN] INDOLO[3.2.1-JK]CARBAZOLE-6-CARBONITRILE DERIVATIVES AS BLUE FLUORESCENT EMITTERS FOR USE IN OLEDS<br/>[FR] DÉRIVÉS D'INDOLO[3.2.1-JK]CARBAZOLE-6-CARBONITRILE UTILISÉS EN TANT QU'ÉMETTEURS FLUORESCENTS BLEUS DESTINÉS À ÊTRE UTILISÉS DANS DES OLED<br/>[DE] INDOLO[3.2.1-JK]CARBAZOLE-6-CARBONITRIL-DERIVATE ALS BLAU FLUORESZIERENDE EMITTER ZUR VERWENDUNG IN OLEDS
  申请人：[de]MERCK PATENT GMBH

  公开号：WO2022129116A1

  公开（公告）日：2022-06-23

  lndolo[3.2.1-jk]carbazole-6-carbonitril-Derivate der Formel (I) als blau fluoreszierende Emitter in organischen Elektrolumineszenzvorrichtungen, insbesondere OLEDs.