diethyl (phenylsulfonyl)phosphoramidate | 1467-28-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diethyl (phenylsulfonyl)phosphoramidate
• 英文别名: diethyl N-benzenesulfonylamidophosphate；o,o-diethyl phenylsulfonylamidophosphate；Benzolsulfonyl--amin；benzenesulfonyl-amidophosphoric acid diethyl ester；Benzolsulfonyl-amidophosphorsaeure-diaethylester；N-diethoxyphosphorylbenzenesulfonamide
• CAS: 1467-28-3
• 化学式: C₁₀H₁₆NO₅PS
• 分子量: 293.28
• InChiKey: YSHIBADQIXYIEC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  18
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  90.1
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  diethyl (phenylsulfonyl)phosphoramidate 在 potassium tert-butylate 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 反应 48.0h， 生成
  参考文献：
  名称：

  Organophosphorus ligands with XPNSO skeleton (X = O, S) and their Pd(II) complexes. Crystal and molecular structure of [{XP(OEt)2}(O2SR)]NH (X = O, R = Me, Ph; X = S, R = C6H4Cl-4) and Pd[{SP(OEt)2}(O2SC6H4Cl-4)N]2

  摘要：

  Several organophosphorus acids of type [{XP(OEt)(2))(O2SR)]NH [X= O, R= Me (1), Ph (2), C6H4CH3-4 (3); X = S, R = C6H4Cl-4 (4)] were obtained by a method based on the reaction between (EtO)(2)P(X)NHLi and the corresponding organosulfonyl chloride. They were subsequently deprotonated with KOBut. Salt metathesis reactions between PdCl2 and the corresponding potassium salts K[{XP(OEt)(2))(O2SR)N] [X = O, R = Me (5), Ph (6), C6H4CH3-4 (7); X = S. R = C6H4Cl-4 (8)] in a 1:2 molar ratio resulted in palladium(II) complexes of type Pd[{XP(OEt)(2))(O2SR)N](2) [X = O, R = Me (9), Ph (10), C6H4CH3-4 (11); X = S, R = C6H4Cl-4 (12)]. In a similar way was obtained the palladium(II) complex Pd[(SPPh2)(O2SPh)N](2) (13), using the appropriate reagents. All compounds were characterized by multinuclear NMR (H-1, C-13, P-31) and infrared spectroscopy. The potassium salts and the palladium complexes were investigated also by mass spectrometry. Single-crystal X-ray diffraction studies revealed a layered supramolecular assembly in case of acid 1, a monomeric structure for compound 4, while in case of compound 2 dimeric associations are formed in the solid state by NH center dot center dot center dot OP hydrogen bonding. A trans-S,N-coordination pattern of the organophosphorus ligand was found in the palladium complex 12. Moreover, short Cl center dot center dot center dot H contacts result in a polymeric [Pd[{SP(OEt)(2)}(O2SC6H4Cl-4)N](2)](n) chain. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.01.023
• 作为产物：
  描述：

  氨基磷酸二乙酯 、 苯磺酰氯 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 15.0h， 以92%的产率得到diethyl (phenylsulfonyl)phosphoramidate
  参考文献：
  名称：

  Organophosphorus ligands with XPNSO skeleton (X = O, S) and their Pd(II) complexes. Crystal and molecular structure of [{XP(OEt)2}(O2SR)]NH (X = O, R = Me, Ph; X = S, R = C6H4Cl-4) and Pd[{SP(OEt)2}(O2SC6H4Cl-4)N]2

  摘要：

  Several organophosphorus acids of type [{XP(OEt)(2))(O2SR)]NH [X= O, R= Me (1), Ph (2), C6H4CH3-4 (3); X = S, R = C6H4Cl-4 (4)] were obtained by a method based on the reaction between (EtO)(2)P(X)NHLi and the corresponding organosulfonyl chloride. They were subsequently deprotonated with KOBut. Salt metathesis reactions between PdCl2 and the corresponding potassium salts K[{XP(OEt)(2))(O2SR)N] [X = O, R = Me (5), Ph (6), C6H4CH3-4 (7); X = S. R = C6H4Cl-4 (8)] in a 1:2 molar ratio resulted in palladium(II) complexes of type Pd[{XP(OEt)(2))(O2SR)N](2) [X = O, R = Me (9), Ph (10), C6H4CH3-4 (11); X = S, R = C6H4Cl-4 (12)]. In a similar way was obtained the palladium(II) complex Pd[(SPPh2)(O2SPh)N](2) (13), using the appropriate reagents. All compounds were characterized by multinuclear NMR (H-1, C-13, P-31) and infrared spectroscopy. The potassium salts and the palladium complexes were investigated also by mass spectrometry. Single-crystal X-ray diffraction studies revealed a layered supramolecular assembly in case of acid 1, a monomeric structure for compound 4, while in case of compound 2 dimeric associations are formed in the solid state by NH center dot center dot center dot OP hydrogen bonding. A trans-S,N-coordination pattern of the organophosphorus ligand was found in the palladium complex 12. Moreover, short Cl center dot center dot center dot H contacts result in a polymeric [Pd[{SP(OEt)(2)}(O2SC6H4Cl-4)N](2)](n) chain. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.01.023

文献信息

• Curable composition, lithographic printing plate precursor, method for producing lithographic printing plate, and compound
  申请人：FUJIFILM Corporation

  公开号：US11333977B2

  公开（公告）日：2022-05-17

  A curable composition includes a salt compound having a) an organic anion in which, in Hansen solubility parameter, δd is 16 or more, δp is 16 or more and 32 or less, and δH is 60% or less of δp and b) a counter cation. A lithographic printing plate precursor having an image-recording layer containing the curable composition, a method for producing a lithographic printing plate using the lithographic printing plate precursor, and a compound that is used in the image-recording layer in the lithographic printing plate precursor are also set out.

  一种可固化组合物包括一种盐类化合物，该化合物具有 a) 有机阴离子，在汉森溶解度参数中，δd 为 16 或以上，δp 为 16 或以上和 32 或以下，δH 为δp 的 60% 或以下；以及 b) 反阳离子。此外，还阐述了一种平版印刷板前体，其图像记录层含有可固化组合物；一种使用该平版印刷板前体生产平版印刷板的方法；以及一种用于平版印刷板前体图像记录层的化合物。
• N-Alkyl (aryl) sulfonylphosphoramidate monoesters
  作者：Jorge A. Goldstein

  DOI：10.1021/jo00434a026

  日期：1977.7
• Mizhiritskii, M. D.; Reikhsfel'd, V. O., Journal of general chemistry of the USSR, 1986, vol. 56, p. 1373 - 1382
  作者：Mizhiritskii, M. D.、Reikhsfel'd, V. O.

  DOI：——

  日期：——
• Kirsanow; Schewtschenko, Zhurnal Obshchei Khimii, 1954, vol. 24, p. 474,482,882,883;engl.Ausg.S.483,490,879,880
  作者：Kirsanow、Schewtschenko

  DOI：——

  日期：——
• Pudovik, M.A.; Kibardina, L.K.; Terent'eva, S.A., Journal of general chemistry of the USSR, 1991, vol. 61, # 11.1, p. 2293 - 2297
  作者：Pudovik, M.A.、Kibardina, L.K.、Terent'eva, S.A.、Pudovik, A.N.

  DOI：——

  日期：——