Tert-butyl 2-oxobicyclo[3.1.0]hexane-1-carboxylate | 928302-01-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Tert-butyl 2-oxobicyclo[3.1.0]hexane-1-carboxylate
• CAS: 928302-01-6
• 化学式: C₁₁H₁₆O₃
• 分子量: 196.246
• InChiKey: SEYQLQGOVJGKEL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  tert-butyl 2-diazo-3-oxo-hept-6-enoate 、 甲醇 在 2,2',4,4'-四甲氧基二苯甲酮 作用下， 反应 5.0h， 生成 tert-butyl 2-methyl-5-oxocyclopent-1-enecarboxylate 、 Tert-butyl 2-oxobicyclo[3.1.0]hexane-1-carboxylate 、 Tert-butyl 2-methoxy-3-oxohept-6-enoate
  参考文献：
  名称：

  Photocatalysis within Hyperbranched Polyethers with a Benzophenone Core

  摘要：

  Quenching and product studies have been performed to demonstrate the suitability of hyperbranched polyethers with a tetrafunctionalized benzophenone core as photocatalysts. The triplet photosensitized transformation of an unsaturated diazo compound has been used as the model reaction. The polymer with highest molecular weight led to a similar product distribution even after several catalytic cycles, which evidences its excellent photostability under prolonged irradiation time. We attribute this to the stabilizing effect of the hyperbranched polymer shell.

  DOI：

  10.1021/jo800254f

文献信息

• Photocatalysis within Hyperbranched Polyethers with a Benzophenone Core
  作者：Lourdes Pastor-Pérez、Emilie Barriau、Holger Frey、Julia Pérez-Prieto、Salah-Eddine Stiriba

  DOI：10.1021/jo800254f

  日期：2008.6.1

  Quenching and product studies have been performed to demonstrate the suitability of hyperbranched polyethers with a tetrafunctionalized benzophenone core as photocatalysts. The triplet photosensitized transformation of an unsaturated diazo compound has been used as the model reaction. The polymer with highest molecular weight led to a similar product distribution even after several catalytic cycles, which evidences its excellent photostability under prolonged irradiation time. We attribute this to the stabilizing effect of the hyperbranched polymer shell.