2,5-dimethyl-4-aminoacetanilide | 23410-20-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,5-dimethyl-4-aminoacetanilide
• 英文别名: acetic acid-(4-amino-2,5-dimethyl-anilide)；2.5-Dimethyl-N-acetyl-p-phenylendiamin；Essigsaeure-(4-amino-2,5-dimethyl-anilid)；5-Acetamido-2-amino-1,4-xylol；N-(4-amino-2,5-dimethylphenyl)acetamide
• CAS: 23410-20-0
• 化学式: C₁₀H₁₄N₂O
• 分子量: 178.234
• InChiKey: ULWRRNFOVYHBIH-UHFFFAOYSA-N

物化性质

• 沸点：
  262.9±35.0 °C(Predicted)
• 密度：
  1.132±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  55.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,5-dimethyl-4-aminoacetanilide 在 sodium perborate tetrahydrate 、 硼酸 、 溶剂黄146 作用下， 反应 5.5h， 以33%的产率得到2,2′,5,5′-tetramethyl-4,4′-azodiacetanilide
  参考文献：
  名称：

  Variable Noninnocence of Substituted Azobis(phenylcyanamido)diruthenium Complexes

  摘要：

  The synthetic chemistry of substituted 4,4'-azobis(phenylcyanamide) ligands was investigated, and the complexes [{Ru(tpy)(bpy)}(2)(mu-L)][PF6](2), where L = 2,2':5,5'-tetramethyl-4,4'-azobis(phenylcyanamido) (Me4adpc(2)), 2,2'-dimethyl-4,4'-azobis(phenylcyanamido) (Me(2)adpc(2)), unsubstituted (adpc2), 3,3'-dichloro-4,4'-azobis(phenylcyanamido) (Cl(2)adpc(2)), and 2,2':5,5'-tetrachloro-4,4'-azobis(phenylcyanamido) (Cl(4)adpc(2)), were prepared and characterized by cyclic voltammetry and visnear-IR (NIR) and IR spectroelectrochemistry. The room temperature electron paramagnetic resonance spectrum of [{Ru(tpy)(bpy)}(2)(mu-Me(4)adpc)](3+) showed an organic radical signal and is consistent with an oxidation-state description [Ru-II, Me(4)adpc, Ru-II](3+), while that of [{Ru(tpy)(bpy)}(2)(mu-Cl(2)adpc)](3+) at 10 K showed a low-symmetry Ru-III signal, which is consistent with the description [Ru-III, Cl(2)adpc(2), Ru-II](3+). IR spectroelectrochemistry data suggest that [{Ru(tpy)(bpy)}(2)(mu-adpc)](3+) is delocalized and [{Ru(tpy)(bpy)}(2)(mu-Cl(2)adpc)](3+) and [{Ru(tpy)(bpy)}(2)(mu-Cl(4)adpc)](3+) are valence-trapped mixed-valence systems. A NIR absorption band that is unique to all [{Ru(tpy)(bpy)}(2)(mu-L)](3+) complexes is observed; however, its energy and intensity vary depending on the nature of the bridging ligand and, hence, the complexes oxidation-state description.

  DOI：

  10.1021/ic502487x
• 作为产物：
  描述：

  2,5-二甲基乙酰苯胺 在 硫酸 、 硝酸 、 铁粉 、 溶剂黄146 作用下， 生成 2,5-dimethyl-4-aminoacetanilide
  参考文献：
  名称：

  Sulphide dyes and process of making

  摘要：

  公开号：

  US01779508A1

文献信息

• N2-phenylamidine derivatives
  申请人：Charles Mark David

  公开号：US06893650B1

  公开（公告）日：2005-05-17

  The invention provides fungicidal compounds of formula (I) and salts thereof wherein: R 1 is alkyl, alkenyl, alkynyl, carbocyclyl or heterocyclyl, each of which may be substituted, or hydrogen; R 2 and R 3 , which may be the same or different, are any group defined for R 1 ; cyano; acyl; —OR a or —SR a , where R a is alkyl, alkenyl, alkynyl, carbocyclyl or heterocyclyl, each of which may be substituted; or R 2 and R 3 , or R 2 and R 1 , together with their interconnecting atoms may form a ring, which may be substituted; R 4 is alkyl, alkenyl, alkynyl, carbocyclyl or heterocyclyl, each of which may be substituted; hydroxy; mercapto; azido; nitro; halogen; cyano; acyl; optionally substituted amino; cyanato; thiocyanato; —SF 5 ; —OR a ; —SR a or —Si(R a ) 3 ; m is 0 to 3; when present R 5 , which may be the same or different to any other R 5 , is any group defined for R 4 ; R 6 is optionally substituted carbo- or heterocylclyl; and A is a defined linking group, or —A—R 6 and R 5 together with benzene ring M form an optionally substituted fused ring system.

  该发明提供了式（I）及其盐的杀真菌化合物，其中：R1为烷基，烯基，炔基，环烷基或杂环烷基，每个基团都可以被取代，或氢；R2和R3，可以相同或不同，是为R1定义的任何基团；氰基；酰基；-ORa或-SRa，其中Ra为烷基，烯基，炔基，环烷基或杂环烷基，每个基团都可以被取代；或R2和R3，或R2和R1，与它们相互连接的原子一起可以形成一个环，该环可以被取代；R4为烷基，烯基，炔基，环烷基或杂环烷基，每个基团都可以被取代；羟基；巯基；叠氮基；硝基；卤素；氰基；酰基；可选择取代的氨基；氰酸根基；硫氰酸根基；-SF5；-ORa；-SRa或-Si（Ra）3；m为0至3；当存在R5时，它可以与任何其他R5相同或不同，是为R4定义的任何基团；R6为可选择取代的碳基或杂环基；而A是一个定义的连接基团，或-A-R6和R5与苯环M一起形成一个可选择取代的融合环系统。
• N2-PHENYLAMIDINE DERIVATIVES
  申请人：Bayer CropScience GmbH

  公开号：EP1150944B1

  公开（公告）日：2003-08-20
• DE555609
  申请人：——

  公开号：——

  公开（公告）日：——
• US4062838A
  申请人：——

  公开号：US4062838A

  公开（公告）日：1977-12-13
• US4220586A
  申请人：——

  公开号：US4220586A

  公开（公告）日：1980-09-02