9-(9,10-diphenylanthracen-6-yl)-9H-carbazole | 1190079-62-9

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 9-(9,10-diphenylanthracen-6-yl)-9H-carbazole
• 英文别名: 2CzPA；9-(9,10-diphenyl-2-anthryl)-9H-carbazole；9-(9,10-diphenylanthracen-2-yl)carbazole
• CAS: 1190079-62-9
• 化学式: C₃₈H₂₅N
• 分子量: 495.623
• InChiKey: OGWNONZKAOBEIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.7
• 重原子数：
  39
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-溴-9,10-二苯基蒽 、 咔唑 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 5.0h， 以93%的产率得到9-(9,10-diphenylanthracen-6-yl)-9H-carbazole
  参考文献：
  名称：

  Anthracene Derivative, Light-Emitting Material, Material for Light-Emitting Element, Composition for Coating, Light-Emitting Element, Light-Emitting Device, and Electronic Appliance

  摘要：

  提供了一种具有大能隙的新型蒽衍生物。提供了一种由下列通式（G1）表示的蒽衍生物。在该式中，Ar1和Ar2分别独立表示具有6到13个碳原子的环中芳基基团，R1和R2独立表示氢、具有1到4个碳原子的烷基基团或具有6到13个碳原子的环中芳基基团，且Ar1、Ar2、R1和R2中的每一个都可以具有取代基，两个取代基可以连接在一起形成环。

  公开号：

  US20090253916A1

文献信息

• Composition, Method for Manufacturing Thin Film, and Method for Manufacturing Light-Emitting Element
  申请人：Shitagaki Satoko

  公开号：US20090317539A1

  公开（公告）日：2009-12-24

  It is an object to provide a composition in which an anthracene derivative is dissolved and a technique in which a thin film that has a favorable film quality is formed by a wet process using the composition. In addition, it is another object to manufacture a highly reliable light-emitting element using the composition at low cost with high productivity. A composition having a solvent and an anthracene derivative having one anthracene structure and one carbazolyl group which is bonded to the anthracene structure directly or through a phenyl group is formed. A thin film with a favorable film quality can be formed by a wet process using the composition. Accordingly, a highly reliable light-emitting element can be manufactured using such a thin film.

  本发明的目的是提供一种含有蒽衍生物溶解的组合物和一种利用该组合物通过湿法工艺形成具有良好薄膜质量的薄膜的技术。此外，另一个目的是使用该组合物以低成本和高生产率制造高可靠性的发光元件。所述组合物包含溶剂和具有一个蒽结构和一个咔唑基固定于蒽结构上，直接或通过苯基结构连接的蒽衍生物。使用该组合物可以通过湿法工艺形成具有良好薄膜质量的薄膜。因此，可以使用这样的薄膜制造高可靠性的发光元件。
• Composition, method for manufacturing thin film, and method for manufacturing light-emitting element
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US08231942B2

  公开（公告）日：2012-07-31

  It is an object to provide a composition in which an anthracene derivative is dissolved and a technique in which a thin film that has a favorable film quality is formed by a wet process using the composition. In addition, it is another object to manufacture a highly reliable light-emitting element using the composition at low cost with high productivity. A composition having a solvent and an anthracene derivative having one anthracene structure and one carbazolyl group which is bonded to the anthracene structure directly or through a phenyl group is formed. A thin film with a favorable film quality can be formed by a wet process using the composition. Accordingly, a highly reliable light-emitting element can be manufactured using such a thin film.

  本发明的目的是提供一种含有蒽衍生物的溶液组合物以及一种利用该组合物通过湿法工艺形成具有良好薄膜质量的薄膜的技术。此外，另一个目的是以低成本和高生产率使用该组合物制造高可靠性的发光元件。该组合物包含溶剂和一种蒽衍生物，该蒽衍生物具有一个蒽结构和一个咔唑基团，该咔唑基团通过直接或通过苯基与蒽结构结合。使用该组合物可以通过湿法工艺形成具有良好薄膜质量的薄膜。因此，可以使用这样的薄膜制造高可靠性的发光元件。
• Anthracene derivative, light-emitting material, material for light-emitting element, composition for coating, light-emitting element, light-emitting device, and electronic appliance
  申请人：SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

  公开号：EP2107096A2

  公开（公告）日：2009-10-07

  A novel anthracene derivative with a large energy gap is provided. An anthracene derivative represented by General Formula (G1) below is provided. In the formula, Ar1 and Ar2 independently represent an aryl group with 6 to 13 carbon atoms in a ring, R1 and R2 independently represent any of hydrogen, an alkyl group with 1 to 4 carbon atoms, or an aryl group with 6 to 13 carbon atoms in a ring, and each of Ar1, Ar2, R1, and R2 may have a substituent and the two substituents may be bonded to each other to form a ring.

  本发明提供了一种具有较大能隙的新型蒽衍生物。本发明提供了一种由下式（G1）表示的蒽衍生物。式中，Ar1 和 Ar2 独立地代表一个环上有 6 至 13 个碳原子的芳基，R1 和 R2 独立地代表氢、一个环上有 1 至 4 个碳原子的烷基或一个环上有 6 至 13 个碳原子的芳基中的任一个，Ar1、Ar2、R1 和 R2 中的每一个都可以有一个取代基，两个取代基可以相互键合形成一个环。
• 9,10-Diphenylanthracene derivative substituted with indole moiety for blue organic light-emitting diodes
  作者：Dong Young Kim、Young Seok Kim、Song Eun Lee、Young Kwan Kim、Seung Soo Yoon

  DOI：10.1080/15421406.2016.1277486

  日期：2017.2.11

  In order to develop blue emitters in organic light-emitting diodes (OLEDs), we synthesized two materials, 9-(9,10-diphenylanthracen6-yl)-9H-carbazole and 1-(9,10-diphenylanthracen-6-yl)-1H-indole by Buchwald-Hartwig reactions. To investigate their electroluminescent performances, multilayer devices were fabricated by following structure: indium-tin-oxide (ITO) (180 nm) / N,N'-di(1- naphthyl)-N, N'diphenyl-(1,1'-biphenyl)-4,4'-diamine (NPB) (50 nm) / blue emitters (30 nm) / 4,7-diphenyl- 1,10-phenanthroline (Bphen) (30 nm) / lithium quinolate (Liq): Al (100 nm). A device using 1-(9,10-diphenylanthracen-6yl)-1H-indole exhibited an efficient blue emission with luminous, power, and external quantum efficiency of 3.11 cd/A, 1.60 im/W, and 2.82% at 20 mA/cm(2), respectively and CIE (x,y) coordinates of (0.15, 0.13) at 6.0 V.
• US8231942B2
  申请人：——

  公开号：US8231942B2

  公开（公告）日：2012-07-31