S-benzyl O,O-dipropyl thiophosphate | 40599-01-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S-benzyl O,O-dipropyl thiophosphate
• 英文别名: di-n-propyl (benzylthio)phosphonate；o,o-dipropyl-s-benzylthiophosphate；S-(Phenylmethyl) O,O-dipropyl phosphorothioate；dipropoxyphosphorylsulfanylmethylbenzene
• CAS: 40599-01-7
• 化学式: C₁₃H₂₁O₃PS
• 分子量: 288.348
• InChiKey: XCAGMSIYFVSJSZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  18
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  60.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  氯化苄 、 potassium O,O-dipropyl phosphorothioate 以59%的产率得到
  参考文献：
  名称：

  BABAEV, B. N.;ASANOVA, M., UZB. XIM. ZH.,(1988) N 5, S. 17-20

  摘要：

  DOI：

文献信息

• DCDMH-promoted synthesis of thiophosphates by coupling of H-phosphonates with thiols
  作者：Xiaojing Bi、Junchen Li、Fanhua Meng、Hongmei Wang、Junhua Xiao

  DOI：10.1016/j.tet.2015.12.020

  日期：2016.2

  DCDMH-mediated phosphorylation of versatile thiols with H-phosphonates for the preparation of synthetically and biologically important thiophosphates was demonstrated. Without metal catalysts and other additives, phosphorylation occurred to give the desired products with good to excellent yields within 10 min at ambient temperature in the air. (C) 2015 Elsevier Ltd. All rights reserved.
• FUNGICIDAL COMPOSITION COMPRISING AN ACYLAMINOBENZAMIDE (COMPOUND A) AND PROCESS FOR PREPARING COMPOUND A
  申请人：ZENECA LIMITED

  公开号：EP0936864A1

  公开（公告）日：1999-08-25
• BIOCIDAL COMPOUNDS AND THEIR PREPARATION
  申请人：Syngenta Limited

  公开号：EP1465898A1

  公开（公告）日：2004-10-13
• US5827540A
  申请人：——

  公开号：US5827540A

  公开（公告）日：1998-10-27
• [EN] FUNGICIDAL COMPOSITION COMPRISING AN ACYLAMINOBENZAMIDE (COMPOUND A) AND PROCESS FOR PREPARING COMPOUND A<br/>[FR] COMPOSITION FONGICIDE COMPRENANT UN ACYLAMINOBENZAMIDE (COMPOSE A) ET PROCEDE POUR PREPARER LE COMPOSE A
  申请人：ZENECA LIMITED

  公开号：WO1998019539A1

  公开（公告）日：1998-05-14

  (EN) Fungicidal compositions comprising, as a first active ingredient, compound (A) and their use to combating fungal infections of plants. Also claimed is a process for preparing a compound of formula (I) wherein R is halogen or C1-4 alkyl.(FR) L'invention concerne des compositions fongicides comprenant comme premier ingrédient actif, le composé (A), ainsi que leur utilisation pour combattre les infections fongiques des plantes. L'invention concerne, également, un procédé pour préparer un composé de la formule (I) dans laquelle R est un halogène ou un alkyle en C1-4.