2-(2-(benzylthio)phenyl)pyridine | 1584673-21-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-(2-(benzylthio)phenyl)pyridine
• 英文别名: 2-(2-Benzylsulfanylphenyl)pyridine
• CAS: 1584673-21-1
• 化学式: C₁₈H₁₅NS
• 分子量: 277.39
• InChiKey: OIPWXWIUUSKWCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  38.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-苯基吡啶 、 二苄基二硫 在 dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 copper diacetate 、 silver trifluoromethanesulfonate 作用下， 以 2-甲基-2-丁醇 为溶剂， 反应 36.0h， 以46%的产率得到2-(2-(benzylthio)phenyl)pyridine
  参考文献：
  名称：

  芳烃的C铑催化定向硫基化？H债券

  摘要：

  首次开发了铑催化芳烃和烷基二硫化物的分子间直接CH硫醇化反应，从而为制备芳基硫醚提供了便利的途径。该策略可与许多不同的导向基团兼容，并具有出色的官能团耐受性。更重要的是，可以选择性地实现单或二硫代化，从而为选择性制备芳基硫醚和二硫醚提供了直接的方法。

  DOI：

  10.1002/chem.201303730

文献信息

• METHOD FOR PRODUCING CYCLOMETALATED IRIDIUM COMPLEX
  申请人：TANAKA KIKINZOKU KOGYO K.K.

  公开号：US20180362565A1

  公开（公告）日：2018-12-20

  The present invention provides a method for producing a cyclometalated iridium complex by use of a non-chlorine iridium raw material. The method for producing a cyclometalated iridium complex includes producing a cyclometalated iridium complex by reacting a raw material including an iridium compound with an aromatic heterocyclic bidentate ligand capable of forming an iridium-carbon bond, the raw material being non-halogenated iridium having a conjugated base of a strong acid as a ligand. Here, the non-halogenated iridium is preferably one containing a conjugated base of a strong acid having a pKa of 3 or less as a ligand.

  本发明提供了一种利用非氯化铱原料生产环金属化铱配合物的方法。生产环金属化铱配合物的方法包括通过将包含铱化合物的原料与能够形成铱-碳键的芳香杂环双齿配体反应来生产环金属化铱配合物，所述原料是非卤化铱，其具有强酸的共轭碱作为配体。在这里，非卤化铱最好是含有pKa值为3或更低的强酸的共轭碱作为配体的铱。
• RAW MATERIAL AND PRODUCTION METHOD FOR CYCLOMETALLIZED IRIDIUM COMPLEX
  申请人：TANAKA KIKINZOKU KOGYO K.K.

  公开号：US20160326198A1

  公开（公告）日：2016-11-10

  The present invention relates to a raw material for a cyclometalated iridium complex, and provides a technique that makes it possible to obtain a cyclometalated iridium complex in higher yield at a lower reaction temperature than using tris(2,4-pentanedionato)iridium(III). The present invention relates to a raw material for a cyclometalated iridium complex, including an organic iridium material for producing a cyclometalated iridium complex, the organic iridium material being a tris(β-diketonato)iridium(III), in which an asymmetric β-diketone is coordinated to iridium.

  本发明涉及一种用于环金属铱配合物的原料，并提供了一种技术，使得能够在比使用三(2,4-戊二酮)铱(III)更低的反应温度下以更高收率获得环金属铱配合物。本发明涉及一种用于环金属铱配合物的原料，包括用于生产环金属铱配合物的有机铱材料，该有机铱材料为三(β-二酮酸盐)铱(III)，其中一个不对称的β-二酮酸盐与铱配位。
• 1,4-BIS(2-THIENYLVINYL)BENZOL DERIVATIVES AND THEIR USE
  申请人：Buesing Arne

  公开号：US20090321686A1

  公开（公告）日：2009-12-31

  The present invention relates to novel 1,4-bis(2-thienylvinyl)benzene derivatives, to conjugated polymers, dendrimers, blends, mixtures and formulations comprising same, and to the use thereof in electronic devices, in particular in polymeric organic light-emitting diodes.

  本发明涉及新颖的1,4-双(2-噻吩基乙烯基)苯衍生物，共轭聚合物，树枝状聚合物，混合物，配方以及在电子设备中的使用，特别是在聚合有机发光二极管中的使用。
• METAL COORDINATION COMPOUND AND LIGHT-EMITTING MATERIAL CONTAINING THE SAME
  申请人：Konno Hideo

  公开号：US20100317858A1

  公开（公告）日：2010-12-16

  To provide a light-emitting device that is capable of red-light-emitting with high luminance and high efficiency and that is excellent in endurance; and a metal coordination compound metal coordination compound having a partial structure represented by formula (1) that can be used in the light-emitting device, and that can also be used in applications, such as organic electroluminescent device materials, electrochemiluminescence (ECL) device materials, emission sensors, photosensitizers, displays, photographic materials, laser dyes, color filter dyes, optical communications, color conversion filters, backlights, illuminations, photosensitizing dyes, various light sources, and the like.

  提供一种具有高亮度和高效率的红光发射能力、并且具有出色耐久性的发光装置；以及具有由公式（1）表示的部分结构的金属配位化合物，可用于发光装置中，并可用于有机电致发光器件材料、电化学发光（ECL）器件材料、发射传感器、光敏剂、显示器、摄影材料、激光染料、彩色滤光片染料、光通信、色彩转换滤光片、背光、照明、光敏染料、各种光源等应用中。
• METAL COMPLEX COMPOSITION AND COMPLEX POLYMER
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2471889A1

  公开（公告）日：2012-07-04

  A metal complex composition comprising a metal complex including a structure represented by the following formula (1) and a charge transport material, wherein in the formula (1), Ra represents an alkyl group having 2 to 30 carbon atoms, and R1, R2, R3 and R4 each independently represent a hydrogen atom, an alkyl group having 1 to 30 carbon atoms that may have a substituent, or the like, provided that adjacent groups among R1, R2, R3 and R4 may be bonded to each other to form a ring structure.

  一种金属络合物组合物，由包括下式（1）所代表结构的金属络合物和电荷传输材料组成、 式（1）中，Ra 代表具有 2 至 30 个碳原子的烷基，R1、R2、R3 和 R4 各自独立地代表氢原子、具有 1 至 30 个碳原子且可能具有取代基的烷基或类似基团，条件是 R1、R2、R3 和 R4 中的相邻基团可以相互键合以形成环状结构。