2,2'-(1,3-Phenylene)bis(4-methyl-4,5-dihydro-1,3-oxazole) | 91786-36-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2'-(1,3-Phenylene)bis(4-methyl-4,5-dihydro-1,3-oxazole)
• 英文别名: 4-methyl-2-[3-(4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole
• CAS: 91786-36-6
• 化学式: C₁₄H₁₆N₂O₂
• 分子量: 244.29
• InChiKey: RSCVPGQKACSLBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  43.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  间苯二甲酸 、 DL-氨基丙醇 在 羟胺 、 sodium hydroxide 、 3-N-(1-hydroxypropan-2-yl)benzene-1,3-dicarboxamide 、 丙酮 、 乙醚 、 4-Methyl-2-[3-(4-methyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]-4,5-dihydro-1,3-oxazole;hydrochloride 作用下， 反应 19.0h， 以to give 4,4'-dimethyl-2,2'-(1,3-phenylene)bis(oxazoline)的产率得到2,2'-(1,3-Phenylene)bis(4-methyl-4,5-dihydro-1,3-oxazole)
  参考文献：
  名称：

  High strength thermoset copolymers incorporating modified bisoxazoline

  摘要：

  本发明提供了一种新型的热固性共聚物及其制备方法，具有高性能、高温度应用所需的强度和热氧化稳定性。该共聚物包括（a）具有未反应酚酸羟基的热塑性树脂，和（b）经过改性的双噁唑单体，其在噁唑环上至少有一个取代基，所选取代基来自于包括甲基基团、具有至少一个能够发生加成聚合的取代基团和能够发生环开聚合的环状基团的群组。

  公开号：

  US05644006A1

文献信息

• PEARLESCENT PIGMENT
  申请人：Kitamura Takeaki

  公开号：US20100249304A1

  公开（公告）日：2010-09-30

  A pearlescent pigment ( 100 ) includes: a flaky substrate ( 10 ); a titanium dioxide layer ( 20 ) that is formed on the flaky substrate ( 10 ); and an oxazoline compound layer ( 40 ) that is formed on the titanium dioxide layer ( 20 ) with the titanium dioxide layer ( 20 ) being interposed between the flaky substrate ( 10 ) and the oxazoline compound layer ( 40 ), and serves as a top surface of the pearlescent pigment ( 100 ).

  一种珠光色颜料（100），包括：一片状基底（10）；在片状基底（10）上形成的二氧化钛层（20）；以及在二氧化钛层（20）上形成的噁唑啉化合物层（40），其中二氧化钛层（20）被夹在片状基底（10）和噁唑啉化合物层（40）之间，作为珠光色颜料（100）的顶部表面。
• BINDER COMPOSITION FOR NON-AQUEOUS SECONDARY BATTERY ELECTRODE
  申请人：Kinoshita Sachiko

  公开号：US20120095131A1

  公开（公告）日：2012-04-19

  Disclosed is a binder composition for a non-aqueous secondary battery electrode, which enables the production of a non-aqueous secondary battery that has excellent adhesion to a current collector or an electrode and can retain a high electric discharge capacity even when charge and discharge are repeated or under a high-temperature environment produced as a result of the generation of heat. Specifically disclosed is a binder composition for a non-aqueous secondary battery electrode, which comprises functional group-containing crosslinked resin microparticles produced by polymerizing the following components (A) to (C): (A) at least one monomer selected from the group consisting of (a) a monomer having one ethylenically unsaturated group per molecule and also having a monofunctional or polyfunctional epoxy group, (b) a monomer having one ethylenically unsaturated group per molecule and also having a monofunctional or polyfunctional amide group, and (c) a monomer having one ethylenically unsaturated group per molecule and also having a monofunctional or polyfunctional hydroxy group; (B) at least one monomer selected from the group consisting of (d) a monomer having one ethylenically unsaturated group per molecule and also having an alkoxysilyl group and (e) a monomer having at least two ethylenically unsaturated groups per molecule; and (C) (k) a monomer which has an ethylenically unsaturated group and is different from the monomers (a) to (e).

  本发明公开了一种用于非水性二次电池电极的粘合剂组合物，该组合物能够生产出具有优异附着力的非水性二次电池，该电池能够在充放电重复或因产生热而产生高温环境下保持高电放电容量。具体而言，本发明公开了一种用于非水性二次电池电极的粘合剂组合物，该组合物包括通过聚合以下组分（A）至（C）制备的含有功能性基团的交联树脂微粒：（A）选自以下组中的至少一种单体，所述组包括（a）每个分子具有一个乙烯基不饱和基团并且还具有单官能或多官能环氧基团的单体，（b）每个分子具有一个乙烯基不饱和基团并且还具有单官能或多官能酰胺基团的单体，以及（c）每个分子具有一个乙烯基不饱和基团并且还具有单官能或多官能羟基团的单体；（B）选自以下组中的至少一种单体，所述组包括（d）每个分子具有一个乙烯基不饱和基团并且还具有烷氧基基团的单体和（e）每个分子具有至少两个乙烯基不饱和基团的单体；以及（C）（k）一种具有乙烯基不饱和基团且与单体（a）至（e）不同的单体。
• PHOTOSENSITIVE COMPOSITION, CURED FILM AND PRODUCTION PROCESS THEREOF, AND ELECTRONIC PART
  申请人：JSR CORPORATION

  公开号：US20140234777A1

  公开（公告）日：2014-08-21

  It is an object of the present invention to improve the curability of a resin composition and a photosensitive composition suitably employed to form e.g., a surface protecting film and an interlaminar insulating film of e.g., an electronic part, while reducing the internal stress remaining in a substrate when the composition is used to form a cured film on the substrate. The photosensitive composition includes a resin (A) having a phenolic hydroxyl group, a crosslinking agent (B1) having at least two oxazoline groups and a crosslinking agent (B2) having at least two groups represented by —CH 2 OR (wherein R is a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or an acetyl group) and a photosensitive acid-generating agent (C).

  本发明的目的是提高树脂组合物和光敏组合物的可固化性，适用于形成电子部件的表面保护膜和层间绝缘膜等，同时在组合物用于在基板上形成固化膜时减少基板中剩余的内部应力。光敏组合物包括具有酚羟基的树脂(A)，至少具有两个噁唑烷基的交联剂(B1)，至少具有两个由—CH2OR（其中R是氢原子，具有1至10个碳原子的烷基或乙酰基）表示的基团的交联剂(B2)和光敏酸发生剂(C)。
• Process for producing thermoset resin
  申请人：TEIJIN LIMITED

  公开号：EP0273368A2

  公开（公告）日：1988-07-06

  A process for producing a thermoset resin, which comprises reacting (A) an organic compound containing at least two groups selected from the class consisting of alcoholic hydroxyl groups, aromatic amino groups and aromatic aminomethyl groups, and (B) a poly(cyclic imino­ether) in the presence of (C) a compound acting as an acid catalyst, at an elevated temperature.

  一种生产热固性树脂的工艺，包括使(A)含有至少两个选自醇羟基、芳香族氨基和芳香族氨基甲基的基团的有机化合物和(B)聚（环状亚胺醚）在(C)作为酸催化剂的化合物存在下，在高温下反应。
• Reversibly color-changeable materials
  申请人：TEIJIN LIMITED

  公开号：EP0336391A2

  公开（公告）日：1989-10-11

  An electrochromic resin composition comprising (A) 100 parts by weight of a network comprising a cross­linked polymer containing 4,4′-diaminodiphenylmethane units in a form in which the amino groups in the formula are quaternized, and (B) 5 to 150 parts by weight of an electrolytic material uniformly dispersed in the network (A). The crosslinked polymer containing the units with the amino groups therein being the quaternized state is useful as an electrochromic or photochromic material.

  一种电致变色树脂组合物，包括(A)100 重量份的网络，该网络由含有 4,4′-二氨基二苯甲烷单元的交联聚合物组成，其单元中的氨基呈季铵化状态；和(B)5 至 150 重量份的电解材料，该电解材料均匀地分散在网络(A)中。含有其中氨基呈季铵化状态的单元的交联聚合物可用作电致变色或光致变色材料。