2-(异丁酰基氨基)乙基丙烯酸酯 | 172351-66-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 2-(异丁酰基氨基)乙基丙烯酸酯
• 英文名称: 2-(2-Methylpropanamido)ethyl prop-2-enoate
• 英文别名: 2-(2-methylpropanoylamino)ethyl prop-2-enoate
• CAS: 172351-66-5
• 化学式: C₉H₁₅NO₃
• 分子量: 185.22
• InChiKey: VOHGKWWKLYEEJF-UHFFFAOYSA-N

物化性质

• 沸点：
  340.8±25.0 °C(Predicted)
• 密度：
  1.017±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  55.4
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• DISPERSION COMPOSITION, AND CURABLE COMPOSITION, TRANSPARENT FILM, MICROLENS AND SOLID-STATE IMAGING ELEMENT USING SAME
  申请人：FUJIFILM Corporation

  公开号：EP3135733A1

  公开（公告）日：2017-03-01

  Provided is a dispersion composition which has a high refractive index and has a high dispersion stability, a curable composition using the same, a transparent film, a microlens, and a solid-state imaging device. The dispersion composition comprises: colourless, white or transparent metal oxide particles (A) having a primary particle diameter of 1 nm to 100 nm and a refractive index of from 1.75 to 2.70, a polymer compound (B) having an acid value of 120 mgKOH/g or more, which is represented by the following Formula (1), and a solvent (C): wherein: R1 represents a (m+n)-valent linking group represented by any one of the following Formulae: wherein: L3 represents a trivalent group; T3 represents a single bond or a divalent linking group; and the three T3's may be same or different; L4 represents a tetravalent group; T4 represents a single bond or a divalent linking group, and the four T4's may be the same or different; L5 represents a pentavalent group; T5 represents a single bond or a divalent linking group, and the five T5's may be the same or different; L6 represents a hexavalent group; T6 represents a single bond or a divalent linking group, and the six T6's may be the same or different, R2 represents a single bond or a divalent linking group, A1 represents a monovalent substituent having at least one group selected from the group consisting of an acid group, a urea group, a urethane group, a group having a coordinating oxygen atom, a group having a basic nitrogen atom, a phenol group, an alkyl group, an aryl group, a group having an alkyleneoxy chain, an imide group, an alkyloxycarbonyl group, an alkyl amino carbonyl group, a carboxylate group, a sulfonamide group, a heterocyclic group, an alkoxysilyl group, an epoxy group, an isocyanate group, and a hydroxyl group, n A1's and n R2's may be the same or different, m represents a positive number of 8 or less, n represents 1 to 9, and m+n satisfies 3 to 10, and P1 represents a polymer chain, and m P1,s may be the same or different.

  本文提供了一种具有高折射率和高分散稳定性的分散组合物、一种使用该分散组合物的固化组合物、一种透明薄膜、一种微透镜和一种固态成像装置。 分散组合物包括 无色、白色或透明的金属氧化物颗粒（A），其主颗粒直径为 1 纳米至 100 纳米，折射率为 1.75 至 2.70、 酸值大于或等于 120 mgKOH/g 的聚合物化合物 (B)，如下式 (1) 所示，以及 溶剂 (C)： 其中 R1 代表(m+n)价连接基团，由下式中的任一种表示： 其中 L3 代表三价基团；T3 代表单键或二价连接基团，三个 T3 可以相同或不同； L4 代表四价基团；T4 代表单键或二价连接基团，四个 T4 可以相同或不同；L5 代表五价基团；T5 代表单键或二价连接基团，五个 T5 可以相同或不同； L6 代表六价基团；T6 代表单键或二价连接基团，六个 T6 可以相同或不同、 R2 代表单键或二价连接基团、 A1 代表单价取代基，该取代基至少有一个基团选自以下组别：酸基、脲基、氨基甲酸乙酯基、具有配位氧原子的基团、具有碱性氮原子的基团、酚基、烷基、芳基、醚基、醚烷基、醚醚烷基、醚醚烷基、醚醚烷基、醚醚烷基、醚醚烷基酰亚胺基、烷氧基羰基、烷基氨基羰基、羧酸基、磺酰胺基、杂环基、烷氧基硅基、环氧基、异氰酸酯基和羟基、 n 个 A1 和 n 个 R2 可以相同或不同、 m 代表 8 或以下的正数，n 代表 1 至 9，m+n 满足 3 至 10，以及 P1 代表聚合物链，m P1,s 可以相同或不同。
• End-functionalized polymers
  申请人：Kou Huiguang

  公开号：US10316114B2

  公开（公告）日：2019-06-11

  This invention relates to end-functionalized living polymers or copolymers having a structure represented by the general formula 1 or 2, wherein R1 is a hydrogen atom, a methyl group, or a radically non-polymerizable organic group containing 1 to 20 carbon atoms. R2 is a functional end group of a vinyl hetero monomer selected from the group consisting of hydroxy, epoxy, silyl, NH2, NH(C1-C6alkyl), N(C1-C6alkyl)2, —CH═CH2, —C≡CH, —C(CH3)═CH2, —O—CH═CH2, (—O—CH2—CH2)1-10—OH, —OR20, —COOR20, —CONHR20, —OCONHR20, —OCOR20 and —NH—CO—R20, wherein R20 is linear or branched C1-C20 alkyl or linear or branched C1-C20 alkyl substituted with hydroxy, epoxy, silyl, NH2 or N(C1-C6alkyl)2; or R20 is phenyl, benzyl, —CH═CH2, —C≡CH or —C(CH3)═CH2, or R2 is a residue of an acrylic acid (CH2═CH—COO—*), methacrylic acid, (CH2═C(CH3)—COO—*) or CH(CH3)═CH—COO—* or R2 is a residue of a dicarboxylic acid HOOC—Rc—COO—* or C1-C6alkyl-OOC—Rc—COO—* wherein Rc is C1-C20 alkylene, C1-C20alkenylene or phenylene; or R2 is a residue derived from the reaction of an isocyanate Ra—NCO with the hydroxy group or with the amine group of the vinyl hetero monomer, said residue being Ra—NHCOO—* or Ra—NHCO—NH—* wherein Ra is unsubstituted C1-C20alkyl, C1-C20cycloalkyl or C1-C20alkyl substituted with hydroxy, epoxy, silyl, NH2, NH(C1-C6alkyl) or N(C1-C6alkyl)2; or R2 is a residue derived from the reaction of a diisocyanate residue OCN—Rb—NCO with the hydroxy group or with the amine group of the vinyl hetero monomer, said residue being *—OOC—NH—Rb—NCO or *—HNOC—NH—Rb—NCO or *—OOC—NH—Rb—NHCOR30 wherein Rb is C1-C20 alkylene or C1-C20cycloalkylene or phenylene and R30 is a residue of hydroxyethylacrylate (CH2═CH—COO—(CH2)2—O*), hydroxyethylmethacrylate (CH2═C(CH3)—COO—(CH2)2—O*), hydroxybutylacrylate (CH2═CH—COO—(CH2)4—O*) or hydroxybutylmethacrylate (CH2═C(CH3)—COO—(CH2)4—O*), A is the hetero atom of the vinyl hetero monomer selected from the group consisting of oxygen, nitrogen, sulfur and silicon; and if R2 is silyl and M is a direct bond, A is a direct bond; M is a bond or a divalent group linking the heteroatom of the vinyl hetero monomer and the functional end group of the vinyl hetero monomer said M being selected from the group consisting of C1-50 alkylene, C1-50 (hetero)alkylene, arylene and heteroarylene; X is a halogen atom, a nitroxide group or a sulphide group, Zn is a polymer or copolymer segment of random-, gradient- or block-type structure, which is built up from vinylic monomers selected from the group consisting of isoprene, 1,3-butadiene, α-C5-18alkene, 4-vinyl-pyridine, 2-vinyl-pyridine, vinyl-imidazole, N-vinylpyrrolidone, dimethylacrylamide, 3-dimethylamino-propylmethacrylamide, styrene, substituted styrene and a compound of formula CH2═C(R3)—C(═R4)—R5, wherein R3 is a hydrogen atom or a methyl group, R4 is oxygen atom or sulfur atom; R5 is NH2, hydroxy, unsubstituted C1-18 alkoxy, C2-100alkoxy interrupted by at least one N and/or O atom, hydroxy-substituted C1-18alkoxy, unsubstituted C1-18alkylamino, di(C1-18alkyl)amino, hydroxy-substituted C1-18alkylamino, hydroxy-substituted di(C1-18alkyl)amino or —O—CH2—CH2—N(CH3)2; Y is the chain terminus of the polymer/copolymer Zn and Y represents the fragment of a polymerization initiator capable of initiating polymerization; Y1 represents a di-, tri- or polyvalent fragment of a di-, tri-, or polyfunctional NMP initiator; m is 2, 3 or 4, preferably 2; n is the number of monomer units Z and is between 10 and 5000.

  本发明涉及具有通式 1 或 2 所代表结构的末端官能化活聚合物或共聚物，其中 R1 是氢原子、甲基或含有 1 至 20 个碳原子的非聚合有机基团。R2 是乙烯基杂单体的官能末端基团，选自羟基、环氧基、硅烷基、NH2、NH(C1-C6 烷基)、N(C1-C6 烷基)2、-CH═CH2、-C≡CH、-C(CH3)═CH2、-O-CH═CH2、(-O-CH2-CH2)1-10-OH-OR20、-COOR20、-CONHR20、-OCONHR20、-OCOR20 和-NH-CO-R20，其中 R20 是直链或支链 C1-C20 烷基或被羟基、环氧基、硅烷基、NH2 或 N（C1-C6 烷基）2 取代的直链或支链 C1-C20 烷基；或 R20 是苯基、苄基、-CH═CH2、-C≡CH 或 -C(CH3)═CH2，或 R2 是丙烯酸 (CH2═CH-COO-*)、甲基丙烯酸的残基、(CH2═C(CH3)-COO-*) 或 CH(CH3)═CH-COO-* 或 R2 是二羧酸 HOOC-Rc-COO-* 或 C1-C6 烷基-OOC-Rc-COO-*的残留物，其中 Rc 是 C1-C20 亚烷基、C1-C20 亚烯基或亚苯基；或 R2 是异氰酸酯 Ra-NCO 与乙烯基杂单体的羟基或胺基反应生成的残留物，所述残留物为 Ra-NHCOO-* 或 Ra-NHCO-NH-*，其中 Ra 是未取代的 C1-C20 烷基、C1-C20 环烷基或被羟基、环氧基、硅烷基、NH2、NH(C1-C6 烷基)或 N(C1-C6烷基)2取代的 C1-C20 烷基；或 R2 是二异氰酸酯残基 OCN-Rb-NCO 与乙烯基杂单体的羟基或胺基反应生成的残基、所述残基为 *-OOC-NH-Rb-NCO 或 *-HNOC-NH-Rb-NCO 或 *-OOC-NH-Rb-NHCOR30，其中 Rb 为 C1-C20 亚烷基或 C1-C20 环亚烷基或亚苯基，R30 为羟乙基丙烯酸酯（CH2═CH-COO-(CH2)2-O*）的残基、羟乙基甲基丙烯酸酯（CH2═C(CH3)-COO-(CH2)2-O*）、羟丁基丙烯酸酯（CH2═CH-COO-(CH2)4-O*）或羟丁基甲基丙烯酸酯（CH2═C(CH3)-COO-(CH2)4-O*）的残基，A 是乙烯基杂单体的杂原子，选自由氧、氮、硫和硅组成的组；如果 R2 是硅烷基且 M 是直接键，则 A 是直接键；M 是连接乙烯基杂单体的杂原子和乙烯基杂单体的官能团的键或二价基团，所述 M 选自 C1-50 亚烷基、C1-50（杂）亚烷基、芳基和杂芳基组成的组；Zn 是无规、梯度或块状结构的聚合物或共聚物片段，由选自异戊二烯、1,3-丁二烯、 α-C5-18烯、4-乙烯基吡啶2-乙烯基吡啶、乙烯基咪唑、N-乙烯基吡咯烷酮、二甲基丙烯酰胺、3-二甲基氨基丙基甲基丙烯酰胺、苯乙烯、取代苯乙烯和式 CH2═C(R3)-C(═R4)-R5 的化合物，其中 R3 是氢原子或甲基，R4 是氧原子或硫原子；R5 是 NH2、羟基、未取代的 C1-18 烷氧基、被至少一个 N 原子和/或 O 原子打断的 C2-100 烷氧基、羟基取代的 C1-18 烷氧基、未取代的 C1-18 烷基氨基、二(C1-18 烷基)氨基、羟基取代的 C1-18 烷基氨基、羟基取代的二(C1-18 烷基)氨基或 -O-CH2-CH2-N(CH3)2；Y 是聚合物/共聚物 Zn 的链终端，Y 代表能引发聚合的聚合引发剂的片段；Y1 代表二价、三价或多价 NMP 引发剂的片段；m 是 2、3 或 4，最好是 2；n 是单体单元 Z 的数目，介于 10 和 5000 之间。
• Antireflection film, polarizing plate, method for producing them, liquid cryatal display element, liquid crystal display device, and image display device
  申请人：Ikeda Akira

  公开号：US20070146887A1

  公开（公告）日：2007-06-28

  To provide an antireflection film which is easily and inexpensively producible and which has an antireflection property, a scratch resistance and a stain resistance in a sufficient level, and a polarizing plate and a liquid crystal display device utilizing the antireflection film of such excellent ability, the antireflection film includs a transparent support and a low-refractive index layer having a lower refractive index than the transparent support, wherein the low-refractive index layer is an outermost layer, and the low-refractive index layer contains a hollow silica particle and a compound that reduces a surface free energy of the outermost layer.
• US8039065B2
  申请人：——

  公开号：US8039065B2

  公开（公告）日：2011-10-18