2,6-dimesityl-4-iodobenzene | 225783-19-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,6-dimesityl-4-iodobenzene
• 英文别名: 4-iodo-N,N-bis(4-methoxyphenyl)-3,5-bis(2,4,6-trimethylphenyl)aniline
• CAS: 225783-19-7
• 化学式: C₃₈H₃₈INO₂
• 分子量: 667.63
• InChiKey: FACSZWONFBPNGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.2
• 重原子数：
  42
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,6-dimesityl-4-iodobenzene 在 正丁基锂 、 三氯化磷 作用下， 生成 4-dichlorophosphanyl-N,N-bis(4-methoxyphenyl)-3,5-bis(2,4,6-trimethylphenyl)aniline
  参考文献：
  名称：

  Synthesis and redox properties of a diphosphene carrying a redox-active sterically protecting group

  摘要：

  The 2,6-dimesityl-4-[bis(4-methoxyphenyl)amino]phenyl group was developed as a steric ally protecting group carrying a reversible redox site at the 4-position and was applied to the construction of a novel redox system composed of the diphosphene and triarylamine units. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00466-9
• 作为产物：
  描述：

  2,4,6-溴碘苯 在 copper(l) iodide 、 18-冠醚-6 、 碘 、 铜 、 potassium carbonate 、 potassium iodide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 生成 2,6-dimesityl-4-iodobenzene
  参考文献：
  名称：

  Synthesis and redox properties of a diphosphene carrying a redox-active sterically protecting group

  摘要：

  The 2,6-dimesityl-4-[bis(4-methoxyphenyl)amino]phenyl group was developed as a steric ally protecting group carrying a reversible redox site at the 4-position and was applied to the construction of a novel redox system composed of the diphosphene and triarylamine units. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00466-9
• 作为试剂：
  描述：

  2,4,6-tri-t-butylphenylphosphonous dichloride 在 magnesium 、 2,6-dimesityl-4-iodobenzene 作用下， 以 四氢呋喃 为溶剂， 以9%的产率得到N,N-bis(4-methoxyphenyl)-4-(2,4,6-tritert-butylphenyl)phosphanylidenephosphanyl-3,5-bis(2,4,6-trimethylphenyl)aniline
  参考文献：
  名称：

  Synthesis and redox properties of a diphosphene carrying a redox-active sterically protecting group

  摘要：

  The 2,6-dimesityl-4-[bis(4-methoxyphenyl)amino]phenyl group was developed as a steric ally protecting group carrying a reversible redox site at the 4-position and was applied to the construction of a novel redox system composed of the diphosphene and triarylamine units. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00466-9

文献信息

• Synthesis and redox properties of a diphosphene carrying a redox-active sterically protecting group
  作者：Kyoko Tsuji、Shigeru Sasaki、Masaaki Yoshifuji

  DOI：10.1016/s0040-4039(99)00466-9

  日期：1999.4

  The 2,6-dimesityl-4-[bis(4-methoxyphenyl)amino]phenyl group was developed as a steric ally protecting group carrying a reversible redox site at the 4-position and was applied to the construction of a novel redox system composed of the diphosphene and triarylamine units. (C) 1999 Elsevier Science Ltd. All rights reserved.