4-sec-butyl-2-tert-butyl-6-methylphenol | 51067-63-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-sec-butyl-2-tert-butyl-6-methylphenol
• 英文别名: 4-sec-Butyl-2-t-butyl-6-methylphenol；4-(Butan-2-yl)-2-tert-butyl-6-methylphenol；4-butan-2-yl-2-tert-butyl-6-methylphenol
• CAS: 51067-63-1
• 化学式: C₁₅H₂₄O
• 分子量: 220.355
• InChiKey: PWUFHLOVNSPLCI-UHFFFAOYSA-N

物化性质

• 沸点：
  277.5±9.0 °C(Predicted)
• 密度：
  0.928±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-sec-butyl-2-tert-butyl-6-methylphenol 在 cesium hydroxide 、 氧气 、 亚磷酸三乙酯 作用下， 以 二甲基亚砜 为溶剂， 25.0 ℃ 、101.33 kPa 条件下， 反应 12.0h， 以90%的产率得到C₁₅H₂₄O₂
  参考文献：
  名称：

  CsOH催化的好氧氧化合成苯酚。 p温和条件下由多烷基苯酚制得的-喹啉

  摘要：

  对苯二酚是各种天然产物和药物化合物的普遍结构基序，是合成化学中的通用构建基块。报道的合成对-喹诺酚的方法需要化学计量的氧化剂。分子氧由于其天然，廉价和环境友好的特性而被认为是理想的氧化剂。在正在进行的CH键羟基化研究中，我们发现多烷基酚可以在温和的条件下与分子氧反应。在这里，我们描述了多烷基酚对p的有效氧化脱芳香化作用-喹诺醇。使用1atm的分子氧作为氧化剂。许多多烷基酚可以在室温下平稳反应。还进行了同位素标记实验，结果证明生成的羟基中的氧原子来自分子氧。

  DOI：

  10.1007/s11426-015-5363-4
• 作为产物：
  描述：

  2-叔丁基-6-甲基苯酚 在 magnesium 作用下， 以 乙醚 、 氯仿 为溶剂， 生成 4-sec-butyl-2-tert-butyl-6-methylphenol
  参考文献：
  名称：

  Reactions of cyclohexadienones. 37. Attack of Grignard and lithium reagents at carbonyl oxygens of o-quinol acetates

  摘要：

  DOI：

  10.1021/jo00428a030

文献信息

• Lemiere, G. L.; Dommisse, R. A.; Alderweireldt, F. C., Bulletin des Societes Chimiques Belges, 1983, vol. 92, # 2, p. 195 - 196
  作者：Lemiere, G. L.、Dommisse, R. A.、Alderweireldt, F. C.

  DOI：——

  日期：——
• DISPERSION COMPOSITION, POLYMERIZABLE COMPOSITION, LIGHT-SHIELDING COLOR FILTER, SOLID-STATE IMAGE PICK-UP ELEMENT, LIQUID CRYSTAL DISPLAY DEVICE, WAFER LEVEL LENS, AND IMAGE PICK-UP UNIT
  申请人：Nagata Yuzo

  公开号：US20110124824A1

  公开（公告）日：2011-05-26

  A dispersion composition is provided in which the dispersibility of titanium black is high, the sedimentation of titanium black over time is suppressed, and overall dispersibility and storage stability are high. Further, a polymerizable composition is provided in which favorable coating property on a substrate and even film thickness can be obtained, generation of residue in an unexposed region when a pattern is formed can be suppressed, and favorable pattern shape having any steps after exposure/development can be obtained. The dispersion composition contains (A) titanium black, (B) a graft copolymer and (C) a solvent.
• DISPERSION COMPOSITION, PHOTOSENSITIVE RESIN COMPOSITION, AND SOLID-STATE IMAGE PICK-UP ELEMENT
  申请人：Maruyama Yoichi

  公开号：US20120257283A1

  公开（公告）日：2012-10-11

  A photosensitive resin composition which can form a pattern attaining high resolution and having a high refractive index and a high transmittance is provided. The photosensitive resin composition includes a dispersion composition including (A) titanium dioxide particles having an average primary particle diameter of from 1 nm to 100 nm, (B) a graft copolymer that has a graft chain having a number of atoms other than hydrogen atoms in a range of from 40 to 10,000 and (C) a solvent, and (D) a polymerizable compound, and (E) a polymerization initiator.
• COLORING COMPOSITION, AND CURED FILM, COLOR FILTER, PATTERN FORMING METHOD, METHOD FOR MANUFACTURING COLOR FILTER, SOLID-STATE IMAGING DEVICE, IMAGE DISPLAY DEVICE, AND DYE MULTIMER, EACH USING THE COLORING COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：US20160327859A1

  公开（公告）日：2016-11-10

  A coloring composition having good light fastness and exposure sensitivity in the case of preparing a cured film; and a cured film, a color filter, a pattern forming method, a method for manufacturing a color filter, a solid-state imaging device, an image display device, and a dye multimer, each using the coloring composition, are provided. The coloring composition contains a dye multimer having a colorant structure and at least one structure selected from structures of Formulas (1) to (5) in the same molecule (Formula (1) is shown below), and a curable compound:
• COLORING COMPOSITION, CURED FILM, COLOR FILTER, METHOD FOR MANUFACTURING COLOR FILTER, SOLID-STATE IMAGING DEVICE, AND IMAGE DISPLAY DEVICE
  申请人：FUJIFILM Corporation

  公开号：US20160327858A1

  公开（公告）日：2016-11-10

  Provided are a coloring composition which makes it possible to providing a color filter having surface unevenness relieved; and a cured film, a color filter, a method for manufacturing the color filter, a solid-state imaging device, and an image display device, each of which uses the coloring composition. The coloring composition includes a colorant compound represented by General Formula (1), a curable compound, and a solvent, in which one of Ar 1 and Ar 2 is a group represented by General Formula (2), and the other of Ar 1 and Ar 2 is a hydrogen atom, a group represented by the following General Formula (2), or the like, R 5 and R 6 each independently represent a hydrogen atom or the like, R 7 represents a monovalent substituent, R 8 represents a halogen atom or the like, and p represents an integer of 0 to 4, R 1 and R 2 each independently represent an alkyl group having 3 or more carbon atoms, or the like, and X 1 to X 3 each independently represent a hydrogen atom or the like. The colorant compound represented by General Formula (1) has a counter anion inside and/or outside the molecule.