3-(3-Formyl-2,5-dihydroxyphenyl)-2,5-dihydroxybenzaldehyde | 1224447-26-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(3-Formyl-2,5-dihydroxyphenyl)-2,5-dihydroxybenzaldehyde
• 英文别名: 3-(3-formyl-2,5-dihydroxyphenyl)-2,5-dihydroxybenzaldehyde
• CAS: 1224447-26-0
• 化学式: C₁₄H₁₀O₆
• 分子量: 274.23
• InChiKey: QSQJMJSHJUYNGP-UHFFFAOYSA-N

物化性质

• 沸点：
  516.3±50.0 °C(Predicted)
• 密度：
  1.596±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  115
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2,5-二羟基苯甲醛 在 sodium hypochlorite 、 水 、 sodium hydroxide 作用下， 反应 3.0h， 以56%的产率得到3-(3-Formyl-2,5-dihydroxyphenyl)-2,5-dihydroxybenzaldehyde
  参考文献：
  名称：

  Dimerization of phenols and naphthols using an aqueous sodium hypochlorite

  摘要：

  The observation of an unusual dimerization of phenols and naphthols using a sodium hypochlorite (NaOCl) in an aqueous solution is reported. NaOCl is an environmentally friendly and less expensive reagent than previously used reagents for dimerization. The yield of the dimer is moderate to high at ambient temperature. Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2010.02.173

文献信息

• Dimerization of phenols and naphthols using an aqueous sodium hypochlorite
  作者：Ramesh Neelamegam、Matthew T. Palatnik、James Fraser-Rini、Mark Slifstein、Anissa Abi-Dargham、Balu Easwaramoorthy

  DOI：10.1016/j.tetlet.2010.02.173

  日期：2010.5

  The observation of an unusual dimerization of phenols and naphthols using a sodium hypochlorite (NaOCl) in an aqueous solution is reported. NaOCl is an environmentally friendly and less expensive reagent than previously used reagents for dimerization. The yield of the dimer is moderate to high at ambient temperature. Published by Elsevier Ltd.