3.3'-Dimethyl-diphenylsulfon | 5097-13-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3.3'-Dimethyl-diphenylsulfon
• 英文别名: 3,3'-sulfonylbis(methylbenzene)；Di(3-methyl phenyl)sulfone；1-methyl-3-(3-methylphenyl)sulfonylbenzene
• CAS: 5097-13-2
• 化学式: C₁₄H₁₄O₂S
• 分子量: 246.33
• InChiKey: NZOSGGNRVDMIHW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3.3'-Dimethyl-diphenylsulfon 、 二氯磷酸乙酯 生成 10-ethoxy-3,7-dimethyl-10H-phenothiaphosphine 5,5,10-trioxide
  参考文献：
  名称：

  Acharekar,A.R. et al., Indian Journal of Chemistry, 1972, vol. 10, p. 129 - 132

  摘要：

  DOI：
• 作为产物：
  描述：

  bis-(2-amino-5-methyl-phenyl)-sulfide 在 permanganate(VII) ion 、 溶剂黄146 作用下， 生成 3.3'-Dimethyl-diphenylsulfon
  参考文献：
  名称：

  THE ACTION OF SULFUR UPON PARA-TOLUIDINE IN THE PRESENCE OF LITHARGE. THIO-PARA-TOLUIDINE, ITS CONSTITUTION AND SOME NEW DERIVATIVES

  摘要：

  DOI：

  10.1021/ja01665a034

文献信息

• BASE GENERATOR
  申请人：Eternal Chemical Co., Ltd.

  公开号：US20130172569A1

  公开（公告）日：2013-07-04

  The present invention provides a base generator having the structure of formula (1): wherein R 1 , R 2 , R 3 , R 4 , R 5 , and Y circle around (−)} are defined as in the specification. The base generator of the present invention can be used for imidization of a polyimide precursor, promoting crosslinking of epoxy monomers, or crosslinking of polyurethane or polyurea.

  本发明提供了一种具有公式（1）结构的碱发生器： 其中R1、R2、R3、R4、R5和Ycircle around (−)}如说明书中所定义。本发明的碱发生器可用于聚酰亚胺前体的酰亚胺化，促进环氧单体交联，或聚氨酯或聚脲的交联。
• Synthesis of Symmetrical Diaryl Sulfone by Homocoupling of Sodium Arylsulfinate
  作者：Yao Peng

  DOI：10.3184/174751914x13946336636551

  日期：2014.5

  An efficient practical homocoupling reaction of sodium arylsulfinate promoted by Cu(II) is reported whereby symmetrical diaryl sulfone derivatives are obtained with high selectivity and reactivity by intermolecular cross-coupling. This homocoupling reaction is tolerant to many functional groups and proceeds under mild conditions.

  报道了一种由 Cu(II) 促进的芳基亚磺酸钠的有效实际均偶联反应，通过分子间交叉偶联以高选择性和反应性获得对称的二芳基砜衍生物。这种同偶联反应对许多官能团具有耐受性，并且在温和的条件下进行。
• Deuterated Polyimides and Derivatives Thereof
  申请人：Muto Kazushige

  公开号：US20080045724A1

  公开（公告）日：2008-02-21

  The object of the present invention is to provide a polyimide compound useful as a raw material of a polymer for an optical waveguide that has excellent transparency and heat resistance, low moisture absorption, a small optical transmission loss, a high refractive index and good adhesion to a base material or a substrate. The present invention is inventions of a method for producing a deuterated polyamic acid compound represented by the general formula [2]: wherein R 1 indicates a tetravalent alicyclic hydrocarbon group or a tetravalent aromatic hydrocarbon group, which may have a heavy hydrogen atom; R 2 indicates a divalent aromatic hydrocarbon group having a heavy hydrogen atom; and m indicates an integer not less than 1, which comprises reacting an acid anhydride represented by the general formula [3]: wherein R 1 has the same meaning as above, with a deuterated diamine compound represented by the general formula [4]: H 2 N—R 2 —NH 2 [4] wherein R 2 has the same meaning as above; a method for producing a deuterated polyimide compound represented by the general formula [1]: wherein R 1 indicates a tetravalent alicyclic hydrocarbon group or a tetravalent aromatic hydrocarbon group, which may have a heavy hydrogen atom; R 2 indicates a divalent aromatic hydrocarbon group having a heavy hydrogen atom; and n indicates an integer not less than 1, which comprises subjecting thus obtained deuterated polyamic acid compound to a ring closure reaction; a method for producing a deuterated polyimide compound represented by the general formula [1] which comprises reacting an acid anhydride represented by the above general formula [3] with a deuterated diamine compound represented by the above general formula [4] and then subjecting the reaction product to a ring closure reaction; use of a deuterated polyimide compound obtained by the above production methods as a raw material polymer for an optical waveguide; a film for an optical waveguide containing said deuterated polyimide compound; a deuterated polyimide compound; and a deuterated polyamic acid compound.

  本发明的目的是提供一种聚酰亚胺化合物，作为光波导聚合物的原材料，具有优异的透明度和耐热性，低吸湿性，光传输损失小，高折射率，并且与基材或基板具有良好的粘附性。本发明涉及一种制备由通用式[2]表示的氘代聚酰亚胺酸化合物的方法：其中R1表示四价脂环烃基或四价芳香烃基，可能有重氢原子；R2表示带有重氢原子的二价芳香烃基；m表示不小于1的整数，包括将通用式[3]表示的酸酐与通用式[4]表示的氘代二胺化合物反应得到的氘代聚酰亚胺酸化合物；一种制备由通用式[1]表示的氘代聚酰亚胺化合物的方法：其中R1表示四价脂环烃基或四价芳香烃基，可能有重氢原子；R2表示带有重氢原子的二价芳香烃基；n表示不小于1的整数，包括将得到的氘代聚酰亚胺酸化合物进行环合反应；一种制备由上述通用式[3]表示的酸酐与上述通用式[4]表示的氘代二胺化合物反应，然后将反应产物进行环合反应的氘代聚酰亚胺化合物的方法；将上述制备方法得到的氘代聚酰亚胺化合物用作光波导的原材料聚合物；包含上述氘代聚酰亚胺化合物的光波导膜；氘代聚酰亚胺化合物；以及氘代聚酰亚胺酸化合物。
• Palladium-catalyzed One-step Synthesis of Symmetrical Diaryl Sulfones from Aryl Halides and a Sulfur Dioxide Surrogate
  作者：Hiromichi Tanaka、Hideyuki Konishi、Kei Manabe

  DOI：10.1246/cl.190300

  日期：2019.8.5

  A convenient method for the one-step synthesis of symmetrical diaryl sulfones from aryl halides has been developed. A keystone of the method is the use of K2S2O5, which can be easily and safely han...

  已经开发了一种从芳基卤化物一步合成对称二芳基砜的简便方法。该方法的一个关键是使用 K2S2O5，它可以轻松安全地处理...
• Palladium-Catalyzed Three-Component Diaryl Sulfone Synthesis Exploiting the Sulfur Dioxide Surrogate DABSO
  作者：Edward J. Emmett、Barry R. Hayter、Michael C. Willis

  DOI：10.1002/anie.201305369

  日期：2013.11.25

  SO(2) efficient: A three‐component palladium‐catalyzed coupling of aryl lithium compounds; sulfur dioxide (provided by the easy‐to‐handle solid surrogate, DABSO); and aryl, heteroaryl, and alkenyl (pseudo)halides yields a diverse library of sulfones. An electron‐poor XantPhos‐type ligand suppresses aryl–aryl exchange and is key to obtaining high yields.

  SO（2）高效：芳基锂化合物的三组分钯催化偶联；二氧化硫（由易于处理的固体替代物 DABSO 提供）；和芳基、杂芳基和烯基（伪）卤化物产生不同的砜库。缺电子 XantPhos 型配体抑制芳基-芳基交换，是获得高产率的关键。