5-hydroxymethyl-1,2,3,4,7,7-hexachlorobicyclo<2.2.1>hept-2-ene | 1080-25-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 5-hydroxymethyl-1,2,3,4,7,7-hexachlorobicyclo<2.2.1>hept-2-ene
• 英文别名: 1,4,5,6,7,7-hexachloro-bicyclo{2,2,1}-hept-5-ene-2-yl-methylalcohol；1,2,3,4,7,7-Hexachlor-5-hydroxymethyl-bicyclo<2.2.1>hepten-(2)；1,4,5,6,7,7-Hexachlor-2-hydroxymethyl-bicyclo<2.2.1>hepten-(5)；<1,4,5,6,7,7-Hexachlor-norborn-5-en-2-yl>-methanol；1,4,5,6,7,7-Hexachlor-2-hydroxymethyl-norbornen；(1,4,5,6,7,7-Hexachlorobicyclo[2.2.1]hept-5-en-2-yl)methanol；(1,4,5,6,7,7-hexachloro-2-bicyclo[2.2.1]hept-5-enyl)methanol
• CAS: 1080-25-7
• 化学式: C₈H₆Cl₆O
• 分子量: 330.853
• InChiKey: JFSYHGUBAXUJEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  5-hydroxymethyl-1,2,3,4,7,7-hexachlorobicyclo<2.2.1>hept-2-ene 、 1,2,3,4,7,7-hexachlorobicyclo<2.2.1>hept-2-ene 5-carbonyl chloride 在 三乙胺 作用下， 以 乙醚 为溶剂， 以82%的产率得到1,4,5,6,7,7-Hexachloro-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid 1,4,5,6,7,7-hexachloro-bicyclo[2.2.1]hept-5-en-2-ylmethyl ester
  参考文献：
  名称：

  Deo, M. G.; Bapat, B. V., Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 1987, vol. 26, # 1-12, p. 448 - 452

  摘要：

  DOI：
• 作为产物：
  描述：

  六氯环戊二烯 在 sodium hydroxide 、 双氧水 作用下， 以 乙醇 为溶剂， 生成 5-hydroxymethyl-1,2,3,4,7,7-hexachlorobicyclo<2.2.1>hept-2-ene
  参考文献：
  名称：

  Organoboron compounds, communication 133.

  摘要：

  DOI：

  10.1007/bf00844217

文献信息

• Process for the preparation of polyisocyanurate dispersions modified with halogenated alcohols and compositions prepared therefrom
  申请人：BASF WYANDOTTE CORPORATION

  公开号：EP0056582A1

  公开（公告）日：1982-07-28

  Polyisocyanurate polymers are prepared by polymerization of polyisocyanates in organic solvents employing trimerization catalysts. The polyisocyanates are reacted with halogenated alcohols subsequent to polymerization. These polymers may be dispersed in polyols for the preparation of cellular and non-cellular polyurethane products having improved flame retardant physical properties.

  多异氰酸酯聚合物是通过使用三聚催化剂在有机溶剂中聚合多异氰酸酯制备而成。聚合后，多异氰酸酯会与卤化醇发生反应。这些聚合物可分散在多元醇中，用于制备具有更佳阻燃物理特性的蜂窝状和非蜂窝状聚氨酯产品。
• VINYLIDENE SUBSTITUTED AROMATIC MONOMER AND CYCLIC (METH)ACRYLATE ESTER POLYMERS
  申请人：Trinseo Europe GmbH

  公开号：EP3632938A1

  公开（公告）日：2020-04-08

  Compositions comprising at least one copolymers comprising: a) from 20 to 90 percent by weight of one or more vinylidene substituted aromatic compounds; b) from 10 to 80 percent by weight of one or more cyclic (meth)acrylate esters; c) from 0 to 40 percent by weight of one or more unsaturated nitriles; and, d) from 0 to 60 percent by weight of an alkyl (meth)acrylate; wherein based on the weight of the copolymer and the copolymer has a weight average molecular weight of 120,000 Kg/Mole or greater and a glass transition temperature of 100 °C or greater. Disclosed are articles prepared from the compositions which may be fabricated in any known manner. The copolymers, compositions and articles disclosed contain reduced levels of the one or more free/residual/unreacted monomers, such as unsaturated nitriles; may be transparent or opaque; or have a biobased monomer content of 5 percent by weight or greater.

  由至少一种共聚物组成的组合物，该共聚物包括a) 20-90%（重量）的一种或多种亚乙烯基取代的芳香族化合物； b) 10-80%（重量）的一种或多种环状（甲基）丙烯酸酯； c) 0-40%（重量）的一种或多种不饱和腈；以及 d) 0-60%（重量）的烷基（甲基）丙烯酸酯；其中基于共聚物的重量，共聚物的重量平均分子量为 120,000 公斤/摩尔或更大，玻璃转化温度为 100℃或更大。本发明还公开了由组合物制备的物品，这些物品可以任何已知的方式制造。所公开的共聚物、组合物和物品含有较少的一种或多种游离/残留/未反应单体，如不饱和腈类；可以是透明或不透明的；或生物基单体含量大于或等于 5%（重量百分比）。
• IMPACT MODIFIED COPOLYMERS OF (METH)ACRYLATE ESTERS AND/OR FREE RADICALLY POLYMERIZABLE MONOMERS CONTAINING NUCLEOPHILIC GROUPS
  申请人：Trinseo Europe GmbH

  公开号：EP3805312A1

  公开（公告）日：2021-04-14

  A composition comprising: a) one or more copolymers of i) one or more of one or more vinylidene aromatic monomers and/or one or more (meth)acrylates; with ii) one or more unsaturated compounds containing one or more nucleophilic groups wherein the copolymer contains on average about 0.01 to about 5.0 percent by weight of nucleophilic groups based on the weight of the copolymer; b) one or more thermoplastic elastomer based polymers containing one or more nucleophilic groups; and c) one or more polymers having electrophilic groups; wherein the electrophilic groups are reactive with the nucleophilic groups. A composition comprising: a) one or more copolymers of i) one or more of one or more vinylidene aromatic monomers and/or (meth)acrylates; with ii) one or more unsaturated compounds containing one or more nucleophilic groups wherein the copolymer contains on average about 0.01 to about 5.0 percent by weight of nucleophilic groups based on the weight of the copolymer; b) one or more thermoplastic elastomer based polymers containing one or more nucleophilic groups; and c) one or more polymers having electrophilic groups; wherein the electrophilic groups have reacted with the nucleophilic groups and at least a portion of the one or more copolymers containing nucleophilic groups are bonded to at least a portion of the one or more thermoplastic elastomers containing one or more nucleophilic groups by at least a portion of the one or more polymers having electrophilic groups.

  一种组合物，包括： a) i) 一种或多种亚乙烯基芳香族单体和/或一种或多种（甲基）丙烯酸酯；与 ii) 一种或多种含有一种或多种亲核基团的不饱和化合物的一种或多种共聚物，其中共聚物平均含有基于共聚物重量约 0.01 至约 5.0% (重量百分比) 的亲核基团； b) 一种或多种含有一个或多个亲核基团的热塑性弹性体基聚合物；以及 c) 一种或多种具有亲电基团的聚合物；其中亲电基团与亲核基团反应。一种组合物，包括： a) i) 一种或多种亚乙烯基芳香族单体和/或（甲基）丙烯酸酯的一种或多种共聚物； ii) 一种或多种含有一个或多个亲核基团的不饱和化合物，其中共聚物平均含有约 0.01 至约 5.0% (以共聚物重量计)的亲核基团； b) 含有一个或多个亲核基团的一种或多种热塑性弹性体基聚合物；以及 c) 具有亲电基团的一种或多种聚合物；其中亲电基团与亲核基团反应，且至少一部分含有亲核基团的一种或多种共聚物通过至少一部分具有亲电基团的一种或多种聚合物键合到至少一部分含有一种或多种亲核基团的一种或多种热塑性弹性体上。
• Copolymers and uses thereof
  申请人：Akzo Nobel Chemicals International, B.V.

  公开号：US10472442B2

  公开（公告）日：2019-11-12

  The invention relates to a specific copolymer obtainable by co-polymerizing at least the following monomers: —more than 80 wt % of at least one bicyclic (meth)acrylate ester, —0.05 to 15% w/w styrene, and —optionally other ethylenically unsaturated monomers, as well as to the way to synthesize them and the use of such polymers to modify the rheology of a liquid in which they are soluble.

  本发明涉及一种特殊的共聚物，这种共聚物可通过共聚至少以下单体而获得：-80 wt % 以上的至少一种双环（甲基）丙烯酸酯，-0.05 至 15% w/w 苯乙烯，以及-可选的其他乙烯基不饱和单体，本发明还涉及合成这种共聚物的方法，以及使用这种聚合物来改变其可溶于其中的液体的流变性。
• Copolymers of bicyclic (meth)acrylates and alkyl (meth)acrylates and their use as rheology modifiers in fuels
  申请人：NOURYON CHEMICALS INTERNATIONAL B.V.

  公开号：US10793656B2

  公开（公告）日：2020-10-06

  The invention relates to a specific copolymer obtainable by co-polymerizing at least the following monomers: —at least one bicyclic (meth)acrylate ester —at least one C8-C24-alkyl (meth)acrylate —optionally, and preferably, at least one aromatic vinyl monomer; and —optionally other ethylenically unsaturated monomers, whereby the copolymer has a weight averaged molecular weight from 400,000 to 50,000,000 Dalton, as well as to the way to synthesize them and the use of such polymers to modify the rheology of a liquid in which they are soluble.

  本发明涉及一种特殊的共聚物，可通过共聚至少以下单体而获得：至少一种双环（甲基）丙烯酸酯--至少一种 C8-C24 烷基（甲基）丙烯酸酯--可选的，最好是至少一种芳香族乙烯基单体；以及--可选的其他乙烯基不饱和单体，由此共聚物的重量平均分子量为 400,000 至 50,000,000 道尔顿。