1,2,3-tris-allyloxy-benzene | 127952-61-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,2,3-tris-allyloxy-benzene
• 英文别名: Tri-O-allyl-pyrogallol；1,2,3-Tris-allyloxy-benzol；1.2.3-Triallyloxy-benzol；1,2,3-Tris(prop-2-enoxy)benzene
• CAS: 127952-61-8
• 化学式: C₁₅H₁₈O₃
• 分子量: 246.306
• InChiKey: NDUNEKJMZTYBCO-UHFFFAOYSA-N

物化性质

• 沸点：
  339.7±37.0 °C(Predicted)
• 密度：
  1.002±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-溴丙烯 、 邻苯三酚 在 potassium carbonate 、 丙酮 作用下， 生成 1,2,3-tris-allyloxy-benzene 、 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Hurd; Parrish, Journal of the American Chemical Society, 1935, vol. 57, p. 1732

  摘要：

  DOI：

文献信息

• Process for preparation of polyhydric alcohols
  申请人：——

  公开号：US20020157939A1

  公开（公告）日：2002-10-31

  A process for preparing a polyhydric alcohol according to the invention comprises subjecting a polyhydric alcohol compound having protected hydroxy group(s) to microwave irradiation in the presence of basic compound(s) or acid(s) having an acid dissociation exponent (pKa) of −8 to 3 at 25° C. to remove the protecting groups of the hydroxy group of the polyhydric alcohol compound. The invention can provide an industrially advantageous process for preparing polyhydric alcohols by readily removing protecting group(s) from protected hydroxy group(s) of polyhydric alcohol compounds.

  根据该发明，制备多羟基醇的方法包括将具有受保护羟基的多羟基醇化合物置于存在具有25°C下酸解离指数（pKa）为-8至3的碱性化合物或酸性化合物的微波辐射中，以去除多羟基醇化合物的羟基的保护基。该发明可以通过轻松去除多羟基醇化合物中受保护羟基的保护基，提供一个工业上有利的制备多羟基醇的方法。
• Acyl Germanium Photoinitiators And Process For The Preparation Thereof
  申请人：Ivoclar Vivadent AG

  公开号：US20180265527A1

  公开（公告）日：2018-09-20

  Acyl germanium compound according to general formula [R m Ar—(C═O)—] 4 —Ge and process for the preparation thereof. The compound is suitable as initiator for radical polymerization.

  通式为[RmAr—(C═O)—]4—Ge的酰基锗化合物及其制备方法。该化合物适用作为自由基聚合的引发剂。
• POLYMERIZABLE COMPOSITIONS WITH INITIATORS CONTAINING SEVERAL GE ATOMS
  申请人：MOSZNER Norbert

  公开号：US20090239967A1

  公开（公告）日：2009-09-24

  Composition with at least one polymerizable binder and one polymerization initiator, which contains at least one acylgermanium compound according to general Formula (I), and the use of acylgermanes of Formula (I) as initiators for radical polymerization or for the preparation of dental restorations.

  至少含有一种可聚合粘合剂和一种聚合引发剂的组合物，其中包含至少一种按通式（I）的酰基锗化合物，以及将通式（I）的酰基锗化合物用作自由基聚合引发剂或用于制备牙科修复材料的用途。
• Composition for film formation and material for insulating film formation
  申请人：JSR CORPORATION

  公开号：US20020172652A1

  公开（公告）日：2002-11-21

  A composition for film formation capable of forming a coating film excellent in low dielectric constant characteristics, cracking resistance, modulus of elasticity, and adhesion to substrates and useful as an interlayer insulating film material in semiconductor devices, etc. The composition for film formation contains (A) at least one member selected from an aromatic polyarylene and an aromatic poly (arylene ether), (B) a polyvinylsiloxane, and (C) an organic solvent.

  一种用于制备薄膜的组合物，能够形成具有低介电常数特性、抗开裂性、弹性模量和对基底的附着力优异的涂层膜，并可用作半导体器件中的层间绝缘膜材料等。该制膜组合物包含（A）至少一种选自芳香族聚芳烃和芳香族聚（芳烃醚）的成员，（B）聚乙烯基硅氧烷和（C）有机溶剂。
• Polymerizable compositions with acylgermanes as initiatiors
  申请人：Moszner Norbert

  公开号：US20080076847A1

  公开（公告）日：2008-03-27

  Composition with at least one polymerizable binder and a polymerization initiator, which contains at least one acylgermane according to general Formula (I), in which R 0 is a substituted or unsubstituted C 1-18 -alkyl radical or an acyl group; R 1 and R 2 are H, an acyl group or have one of the meanings given for R 3 ; R 3 is a branched or linear C 1-18 -alkyl radical which can be unsubstituted or substituted one or more times by —O—, —NH—, —NR—, —S— or interrupted by other groups, trimethylsilyl, hal-(CH 3 ) 2 Si—[OSi(CH 3 ) 2 ] r − , (CH 3 ) 3 Si—[OSi(CH 3 ) 2 ] r —, —COOH, —COO—R 10 , —CO—NR 11 R 12 , —CO-vinyl, —CO-phenyl, phenyl-C 1-4 -alkyl, phenyl, naphthyl or biphenyl, C 5-12 cycloalkyl, a 5 or 6-membered O, S or N-containing heterocyclic ring, halogen, OH, an aromatic C 6-30 radical which can be substituted or unsubstituted and/or interrupted by O, S or —NR—, or a branched, cyclic or linear C 1-20 alkyl, -alkenyl, -alkoxy or -alkenoxy radical; m is 1, 2 or 3; n is 0 or 1 and p is 0 or 1; and the use of acyl germanes of Formula (I) for example as initiator for radical polymerization.

  至少含有一种可聚合粘合剂和一种聚合引发剂的组合物，其中聚合引发剂至少包含一种符合通式（I）的酰基锗烷，其中R0是取代或未取代的C1-18烷基基团或酰基基团；R1和R2是氢、酰基基团或具有R3所述含义之一的基团；R3是支链或直链的C1-18烷基基团，可以未取代或被—O—、—NH—、—NR—、—S—或其他基团、三甲基硅基、卤代-(CH3)2Si—[OSi( )2]r−、( )3Si—[OSi( )2]r—、—COOH、—COO—R10、—CO—NR11R12、—CO-乙烯基、—CO-苯基、苯基-C1-4-烷基、苯基、萘基或联苯基、C5-12环烷基、5或6元杂环含氧、硫或氮的环、卤素、OH、可以被取代或未取代和/或被O、S或—NR—中断的芳香族C6-30基团，或支链、环状或直链的C1-20烷基、烯基、烷氧基或烯氧基基团；m为1、2或3；n为0或1；p为0或1。酰基锗烷的通式（I）可用作自由基聚合的引发剂。